查询词典 AU

Probably, during the formation of spherical Au nanocrystals, PVP or PAM can be selectively adsorb on certain crystal planes of Au nanocrystals by the complexing effect between N or O with Au atom, thus leading to the different growth rates at different crystal planes of spherical Au nanocrystals and resulting in the formation of faceted Au nanocrystals and Au nanoplates.

研究表明，多面体和片状Au纳米晶是由球形Au纳米晶转变而来，这个转变是由于在球形Au纳米晶的形成过程中，PVP和PAM借助于其特有的N原子和O原子吸附到Au纳米晶的Au原子上，造成了晶体不同晶面生长速率的差异而导致的结果。

Using the extended relativistic multi-configuration Dirac-Fock theory and the general-purpose relativistic atomic structure program 2(GRASP2) with quantum electrodynamical effect and breit correction, we have calculated the energy level structures, transition wavelengths, transition probabilities, oscillator strengths, energy level lifetimes, level widths and ionic average lifetimes of As-like Au~(46+), Ge-like Au~(47+) and Fe-like Au~(53+).

根据扩展的全相对论多组态Dirac-Foek理论，采用"多功能相对论原子结构程序GRASP~2(General-Purpose Relativistic Atomic Structure Program 2，1992)"，考虑量子电动力学效应和Breit修正，计算了激光金等离子体中类砷金Au~(46+)，类锗金Au~(47+)和类铁金Au~(53+)的能级结构、跃迁波长、跃迁几率、振子强度、能级寿命、能级宽度和离子平均寿命。

Water-rock interaction demonstrates that, a gold-boring formation , i. e., a set of light metamorphic clastic gritstone, sandy slate, and tuffaceous slate in Wuqiang Runnel Formation, Ban Stream Group, act as the source of gold deposits in South-West Hunan. The gold is originally derived from volcanic eruption materials in Wuling-Xuefeng period; for the typical single gold deposit such as Mobin, which is short of sulphide, chlorine is very important in the metallogenic process; sulphur and chlorine perform as the major negative ions to form complex ions with Au throughout the gold activation and migration movement. The complex ion of chlorine and gold may keep stable in a wide range of temperature; the physical-chemical conditions in typical geothermal fluid system are of deciding significance for gold activation, migration and precipitation.

特定体系的水岩实验证实了漠滨及整个湘西南金矿的成矿元素Au和伴生元素主要源于赋矿围岩-板溪群五强溪组的一套浅变质碎屑砂岩、砂质板岩和凝灰质板岩；首次突破传统认识，证明氯在中低温热液体系中能与Au形成稳定络合物的形式进行运移，因此氯在本区Au成矿过程中起着相当重要的作用；成矿热液流体中Au主要以金硫、金氯络合物形式在溶液中迁移，阴离子∑S、Cl〓对金的活化、迁移及沉淀起主导作用，Au的伴生元素As、Sb在热液体系中与Au形成金锑、金砷络合物有利于金的进一步活化、迁移及沉淀；中低温热液流体成矿过程中，体系的物理化学参数对Au的活化、迁移及沉淀富集起决定性作用。

By using molecular dynamics simulation, the deposition process of cold spraying nano-scale Au particles on Au (001) surface and the morphological changes of the surface layers of the substrate and the particle are described, in which the many-body potential was used to calculate the interatomic force between the atoms.

通过对Au纳米粒子在Au基体上沉积过程的分子动力学模拟，再现了冷喷涂中Au纳米粒子在Au基体上沉积的过程以及粒子和基体表层的形貌变化；在撞击过程中，基体的局部区域有熔化现象，通过计算粒子原子进入基体表面层的数量及粒子与基体间的最终接触面积，探讨了影响喷涂粒子沉积过程的主要因素。

The preparation method is characterized in that:(1) at minus 10 DEG C to 10 DEG C, a chloroauric acid solution with a certain concentration is added into a nano-Pt/C catalyst by ultrasonic or stirring mixture and the atomic ratio of Pt to Au is controlled between 18:1 and 5:1;(2) a small amount of monohydric alcohol or dihydric alcohol or trihydric alcohol of C1-C3 is added and is stirred at minus 10 DEG C to 10 DEG C for 10 min to 5h, so as to prepare the carbon-loading Pt-Au bimetallic nano electro-catalyst;(3) if necessary, the catalyst obtained by the step (2) is treated for 0.5 to 4h at high temperature ranging from 100 DEG C to 700 DEG C in the inert or reducing atmosphere, so as to adjust and control the grain size of the Pt-Au bimetallic nano electro-catalyst.

本发明涉及了一种高稳定性碳载Pt-Au双金属纳米电催化剂的制备方法，其特征在于：(1)在-10～10℃中，将一定浓度氯金酸溶液加入到纳米Pt/C催化剂中经超声或搅拌混合，控制Pt∶Au的原子比为18∶1-5∶1；(2)添加少量C 1 -C 3 的一元、二元或三元醇类，在-10～10℃下搅拌10min-5h，制备了碳载铂金双金属纳米电催化剂；(3)视需要，可将步骤(2)得到的催化剂在惰性气氛或还原气氛中经100～700℃高温处理0.5-4h，可调控Pt-Au/C双金属纳米催化剂的粒径。

For the Au/TiO2 catalyst reduced at 673 K with an optimal Au mass fraction of 9.2%, the mean particle size of Au was 2 nm and the initial hydrogenation rate was as high as 13.7×10^(-5) mols^(-1)g^(-1), while the maximum yield of crotyl alcohol was 69.9%.

在673K还原条件下制备Au质量分数为9.2%的Au/TiO2催化剂上，Au粒子的平均粒径为2nm，初始加氢速率达到13.7×10^(-5)mols^(-1)g^(-1)，同时巴豆醇最高收率可达69.9%。

Using liquid-reduction or complex-redution method,four catalysts,i.e,the Au/C,Pd/C,Pd-Au/C-T and Pd-Au/C-H were preparated and which electroanalytic activities and stabilities for the oxidation of formic acid were compares.

合成并比较了碳载Au、碳载Pd、碳载高合金化Pd-Au和碳载非合金化Pd-Au催化剂对甲酸氧化的电催化活性和稳定性。

The oxidant 〓 plays indirect role in dissolving gold, and mainly controls the mix potential of Au in the alkaline thiourea solution. In which the "mix potential"is the decisive factor affecting the dissolution of gold. The reaction driving force is enough to have formamidine disulfide oxidize Au to Au〓 at the potential of about 0.4V. And then thiourea molecular complexes with Au〓 ion soon, which causes the fast dissolution of gold in the alkaline thiourea media. The dissolved weight of gold in 0.25 M thiourea solution with 0.05M Na〓SO〓 and 0.1M 〓 of pH 12. 5 by air at the temperature of 303K is 7. 8mg·cm〓 within 1hr.

在碱性硫脲溶金过程不起直接作用，而是通过S〓O〓来控制二硫甲脒有效形成的金在溶液中的混合电位；&混合电位&是影响碱性硫脲溶液溶金与否的决定性因素，在0.4V左右，有足够的推动力致使二硫甲脒氧化Au成Au〓，随后硫脲与Au〓络合形成稳定的络离子Au〓，从而使金快速溶解；温度为303K、pH为12.5时，在含0.05MNa〓SO〓、0.1M 〓及0.25M硫脲的溶液中，鼓入空气，金的溶解量在1hr内为7.8mg·cm〓；铜只有微量溶解，银、镍、铁则几乎不溶解。

With the dose of 7.04 mC/cm2, ODT/Au will become a more strengthened structure and then form a negative resist in the correlation with cross-linking from alkyl matrix, partial breakdown of S-Au bonding and surface adsorption by air-borne species. Thus, it can obtain a gold pattern via gold-etching process. Besides, as a result of massive breakdown of alkyl matrix and S-Au bonding from ODT/Au under irradiation with doses of 64.06 and 128.13 mC/cm2, ODT SAMs would form a loose-packed structure on the gold substrate. The ODT/Au becomes less resistive for gold-etching and a positive gold pattern would form after gold-etching.

结果发现：以50 eV 低能量电子在照射剂量7.04 mC/cm2微影并曝露於大气后，受到来自於ODT/Au碳链间的交联、部分的S-Au键结破坏以及照射后立即曝露大气所吸附於表面的碳氧化物种的共同影响下，ODT SAMa於Au膜基材上将形成更紧密复杂的结构而作为负型阻剂，经后续湿式蚀刻15分钟后将显影出来Au的负型图案；当提升照射剂量至64.06及128.13 mC/cm2后，由於ODT/Au上碳链及S-Au键结的大量破坏，将使ODT/Au结构不能稳固且紧密地排列於Au膜基材上，显影时Au蚀刻液将容易穿过ODT SAMs抵达S/Au界面而移除Au，而形成正型图案。

This paper deals mainly with (1)partition of Au and Ag in coexisting phases of lower maturity and high sulphur crude oil and aqueous solution;(2)mobilization and transport abilities of Au and Ag during the interaction of water,oil,and rock;(3)enrichment ability of Au by crude oil during oil generation and primary migration within double source system and under the experimental temperature and pressure.

本文实验内容包括Au、Ag元素在低熟高硫原油及其共存的水溶液中的分配特征，水－油－岩反应体系中Au、Ag活化和迁移的能力，以及在共同源岩和温度，压力共同作用的压力机系统中，石油生成和初次运移过程对Au的富集能力等。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。