查询词典 2-butene

A novel method for determination of benzoyl peroxide with spectrophotometry was developed. Inclusion ratio of β cyclodextrin to dibenzoy peroxide and benzoic acid is obtained with spectrophotometry.The mechanism of the inclusion was studied,too. The results showed that β-CD react with dibenzoyl peroxide to form a 1:1 or 2:1 host-guest complex, with the apparent formation constants of 5.0× 10~2and 2.5× 10~4 , respectively.β-CD reacts with benzoic acid to form a 1:1 host-guest complex with the apparent formation constant of 6.9 × 10~2 after the dibenzoyl peroxide was reduced by hydroxyl ammonium chloride.

建立了用β环糊精测定过氧化苯甲酰的分光光度法，并测定了β环糊精与过氧化苯甲酰和苯甲酸的包结比，随着β-CD浓度的增大，可与BPO分别形成1：1或2：1的包容络合物，包结常数分别为5.0×10~2和2.5×10~4，与苯甲酸形成1：1的包容络合物，包结常数为6.9×10~2；由于包结物的吸光度值比过氧化苯甲酰的吸光度值大大增加，建立了一种当β-CD存在下，在水溶液中测定过氧化苯甲酰的方法。

The results show that the foamable MAA/MAN copolymers were prepared at 40-60℃ by polymerizing the mixture of 50phr MAA, 50phr MAN, 1-5phr magnesium oxide, 2-8phr butanol and tert-butanol, 0.2-0.3 phr dibenzoyl peroxide and tert-butyl perbenzoate and 0.1-0.2phr DMF. Then the resulting copolymers were expanded at 200-220℃ for 2-3h, subsequently treated at 160℃ for 5-6h, generating PMI foams with excellent mechanical properties and heat-resistance.

研究结果表明：将50份MAA、50份MAN、1~5份氧化镁、2~8份正丁醇、叔丁醇的混合物、0.2~0.3份过氧化二苯甲酰和过氧化苯甲酸叔丁酯和0.1~0.2份的甲酰胺，混合均匀后在40~60℃聚合为可发泡的MAA/MAN共聚物，该共聚物在200~220℃下发泡2~3h，在160℃下热处理5~6h，制得PMI泡沫塑料，其力学性能和耐热性能优异。

This is the first example of two-dimensional lanthanide MOFs with one dimensional water chains.2、Coordination polymer[Nd_2_3(H_2O)_2]·bpy·4H_2O(2)(bpdc=2, 2′-bipyridine-3,3′-dicarboxylate,bpy=4,4′-bipyridine)had been synthesized under hydrothermal conditions and its structures were determined by X-ray diffraction,and confirmed by IR and TG analysis.

该结构是在二维骨架的镧系配位聚合物中首次观察到的一维的水链结构。2、以Nd_2O_3，2，2′-联吡啶-3，3′-二羧酸和4，4′-联吡啶为原料，采用水热法合成了一个具有二维骨架结构的配位聚合物[Nd_2_3(H_2O)_2]bpy·4H_2O，通过IR、x射线单晶衍射分析和热重等手段对其结构进行了表征。

Dimethylamino)ethyl methacrylate was polymerized using PS-CH_2Cl as macroinitiator and CuCl/ 2,2 '-Bipyridyl as catalyst in toluene to acquire amphiphilic brush-type copolymers of PS-g-PDMAEMA.

再以氯甲基化的聚苯乙烯(PS-CH_2Cl)为大分子引发剂，在CuCl和2，2′-联吡啶(2，2′-Bipyridyl，bpy)存在下，以甲苯为溶剂，进行甲基丙烯酸N，N-二甲胺基乙酯2-(Dimethylaminoethyl methacrylate，DMAEMA的ATRP聚合，得到两亲性的梳状共聚物PS-g-PDMAEMA。

Firstly,two novel rare earth complexes(CH_2=CHO)Ln~Ⅲ[2,6-_2PhNSiMe _3]_2Li_3Ln=Y(2,Yb(3)containing arylamido and enolate mixed ligands have been synthesized by treatment of 2 equiv of of 2,6-~iPr_2PhNHSiMe_3 with exces n-BuLi at -78℃in THF for 12h,followed by reaction with 1 equiv of LnCl_3at 80℃for 24h in one-pot.All the two compounds were characterized by spectroscopic methods,elemental analyses,and a single-crystal X-ray diffraction study.

首先，-78℃下，在两当量的2，6-~iPr_2PhNHSiMe_3(1)THF溶液中加入过量的n-BuLi，反应12小时，再加入一当量的LnCl_380℃下，反应24小时，一锅法合成了含胺基、乙烯醇基混合配体的新型稀土金属配合物(CH_2=CHO)Ln~Ⅲ[2，6-_2PhNSiMe_3]_2Li_3Ln=Y(2、Yb(3)，上述化合物结构经单晶X-ray衍射、光谱和元素分析表征，表明我们得到的是一类新型的三价稀土配合物。

Two novel A-it-A' type benzothiazole-based derivatives with benzothiazolyl, phenyl-acetyl or pyridine cation groups as π electron acceptor, diethenylphenyl as π conjugated bridge: 4-(2-benzothiazolyl) ethenylchalcone (1) and 4-{4-[2-(benzothiazole-2-yl) ethenyl] styryl}-N-methylpyridinium iodide (2) were synthesized.

以苯并噻唑、苯乙酰基和吡啶阳离子为电子受体，二乙烯基苯为共扼桥，合成了两个新的A-π-A'型苯并噻唑衍生物：4-（2-苯并噻唑）－乙烯基查尔酮(1)和4-｛4-［2-乙烯基］苯乙烯基｝－N-甲基吡啶碘盐(2)。

Two novel A-π-A′ type benzothiazole-based derivatives with benzothiazolyl,phenyl-acetyl or pyridine cation groups as π electron acceptor,diethenylphenyl as π conjugated bridge: 4-(2-benzothiazolyl)ethenylchalcone(1) and 4-{4-[2-(benzothiazole-2-yl)ethenyl]styryl}-N-methylpyridinium iodide(2) were synthesized.

以苯并噻唑、苯乙酰基和吡啶阳离子为电子受体，二乙烯基苯为共轭桥，合成了两个新的A-π-A′型苯并噻唑衍生物：4-(2-苯并噻唑)-乙烯基查尔酮(1)和4-{4-[2-乙烯基]苯乙烯基}-N-甲基吡啶碘盐(2)。

Then sodium ethoxide was used as base,the nucleophilic substitution of 2-pyrrolidone with the intermediate provided nefiracetam.

以碳酸钠为缚酸剂，摩尔比为1︰1的2，6-二甲基苯胺与氯乙酰氯反应合成了中间体2-氯-N-(2，6-二甲基苯基)乙酰胺；在强碱乙醇钠作用下，2-吡咯烷酮再与2-氯-N-(2，6-二甲基苯基)乙酰胺经亲核取代合成了目标化合物奈非西坦。

Other Psionic and Magic Gear: Dorje of firefall (2nd), dorje of charm person (3rd), crystal capacitor [1] (4th-8th), third eye concentrate (4th), cloak of resistance +1 (5th-19th), dorje of knock (6th-7th), crystal capacitor [3] (7th-11th), dorje of invisibility [9th-level manifester] (8th), crystal mask of mindarmor (9th-12th), 3 powerleech pearls (10th, 18th-20th), dorje of whitefire (10th), amulet of natural armor +1 (11th-16th), third eye aware (11th), psionatrix of Psychoportation (11th), gloves of Dexterity +2 (12th-16th), ring of stabilization (12th), crystal capacitor [5] (13th-16th), torc of free will (13th), bracers of armor +2 (14th-20th), dorje of negate psionics (14th-15th, 18th), ring of fire resistance (16th), amulet of natural armor +2 (17th-20th), skin of striking (17th), crystal capacitor [7] (17th- 18th), gloves of Dexterity +4 (17th-18th), amulet of natural armor +3 (19th-20th), gloves of Dexterity +6 (19th-20th), crystal capacitor [9] (19th), cloak of resistance +3 (20th).

其他灵能和魔法装备：&落炎术&灵杖(2级)，&魅惑人类&灵杖(3级)，灵容[1](4至8级)，隐匿镶额眼(4级)，+1抗力斗篷(5至19级)，&敲击术&灵杖(6至7级)，灵容[3](7 至11级)，&隐形术&灵杖[显能者等级9](8级)，水晶心防面具(9至12级)，夺能珍珠×3(10级、18至20级)，&苍火&灵杖(10级)，+ 1天生防御护符(11至16级)，知觉镶额眼(11级)，心灵传送灵锥(11级)，+2敏捷手套(12至16级)，稳定戒指(12级)，灵容[5](13至16级)，自由意志项圈(13级)，+2防御护腕(14至20级)，&消解灵能&灵杖(14至15级、18 级)，次级抗火戒指(16级)，+2天生防御护符(17至20级)，反击灵皮(17级)，灵容[7](17至18级)，+4敏捷手套(17至18级)，+3天生防御护符(19至20级)，+6敏捷手套(19至20级)，灵容[9](19级)，+3抗力斗篷(20级)。

By means of GPC,IR,GC-MS,~(13)CNMR,~1HNMR,Methylation analysisetc,structural properties of PST-1 were identified as follows:The Mwof PST-1 was 3.44×10~6 Da and its optical rotation was _D~(20)=+0.110°(c0.1, H_2O); PST-1 constituted 8 simple sugars and the molar ratio was 2,4-Dimethoxy-Mannose:Rhamnose:Ara-binose:Xylose:Galactose:D-Galacturonic acid:Mannose:D-glucuronic acid=2%:5%:24%:9%:3%:1%:46%:10%;The chief bone of PST-1 was 1,3,6-linked-β-D-Man residue and the side chains contained Furanoid and Pyranoid residues.

结合GPC、旋光度测定、IR、GC-MS、~(13)CNMR、~1HNMR、高碘酸氧化法、Smith降解以及甲基化方法等分析测试方法，得到PST-1的单糖组成及结构表征，实验结果如下：红豆杉多糖PST-1是重均分子量为3.44×10~6 Da的支链多糖，旋光度为20D=+0.110~0(c0.1，H_2O)；PST-1单糖组成为：2，4-Dimethoxy-Mannose：Rhamnose：Arabinose：Xylose：Galactose：D-Galacturonic acid：Mannose：D-glucuronic acid=2％：5％：24％：9％：3％：1％：46％：10％；PST-1的骨架结构为：具有1，3，6-连接的β-D-甘露糖残基骨架，侧链分枝包括非还原末端的呋喃型α-L-阿拉伯糖残基、吡喃型α-L-阿拉伯糖残基、β-D-木糖残基、β-D-甘露糖残基、2，4-二氧甲基-β-D-甘露糖残基和α-D-葡萄糖醛酸残基；侧链的糖残基也可能存在2，5-二氧-取代呋喃型α-L-阿拉伯糖基、3-氧-取代的β-D-木糖残基、6-氧-取代的α-D-半乳糖醛酸残基、6-氧-取代的α-D-半乳糖残基、4-氧-取代的α-D-葡萄糖醛酸残基和2-氧-取代的α-L-鼠李糖残基，同时后者也可能穿插在主链上。

With Death guitarist Schuldiner adopting vocal duties, the band made a major impact on the scene.

随着死亡的吉他手Schuldiner接受主唱的职务，乐队在现实中树立了重要的影响。

But he could still end up breakfasting on Swiss-government issue muesli because all six are accused of nicking around 45 million pounds they should have paid to FIFA.

不过他最后仍有可能沦为瑞士政府&议事餐桌&上的一道早餐，因为这所有六个人都被指控把本应支付给国际足联的大约4500万英镑骗了个精光。