查询词典 2-butene

Two potential novel environmentally friendly ashless vegetable oil additives, 2-mercaptobenzothiazole derivatives, di-n-dodecyl-[2-(2-benzothiazolyl)thio]ethylborane and di-n-dodecylthio-[2-(2-benzothiazolyl)thio]ethylborane, were synthesized and their tribological performance as additives in rapeseed oil was evaluated using a four-ball wear tester.

合成了两种新型环境友好型植物油无灰添加剂，即二正十二烷氧基-2-[(2-苯并噻唑基)硫代]乙氧基甲硼烷和二正十二烷硫基-2-[(2-苯并噻唑基)硫代]乙氧基甲硼烷。

Results: The changes following hydrocortisone intervention of rats could be identified by PCA, and the kidney deficiency syndrome rats entered a state of "hyperfunction", involving a series of changes in metabolic pathway and metabolic network. The response integral area of lactic acid (δ 1.37) increased, indicating the accumulation of metabolites of lactic acid. The amount of dimethylamine (δ 2.72) also increased, indicating that the disorder of kidney function was related to kidney-deficiency syndrome. The response of creatinine (δ 3.87), asparaginic acid (δ 2.83), taurine (δ 3.44, 3.28), and hippurate (δ 7.84, 7.56, 7.64, 3.97) all decreased significantly, indicating that the hydrocortisone might cause adrenal cortex excretion injury. The response integral area of succinate (δ 2.41) and citric acid (δ 2.53, 2.68) decreased, which was usually caused by disorder of the mitochondrial function.

结果：PCA方法处理肾虚证和空白对照大鼠尿液数据显示，两组大鼠的数据可以在得分图实现分类，与对照组比较肾虚组大鼠由于氢化可的松诱导，大鼠机体进入一个过消耗后衰弱的状态，相关代谢发生显著变化，乳酸(δ 1.37)代谢发生堆积；二甲胺(δ 2.72)的含量增加，提示肾虚与肾功能异常是密切相关的；天冬氨酸(δ 2.83)，牛磺酸(δ 3.44， 3.25)，马尿酸(δ 7.84， 7.56， 7.64， 3.97)，肌氨酸(δ 3.87)等的相对积分面积明显下降，这预示糖皮质激素可能引起了肾上腺皮质分泌功能的损害；琥珀酸(δ 2.41)和柠檬酸(δ 2.53， 2.68)是三羧酸循环能量代谢及糖酵解的中间产物，其含量的降低，通常是由于线粒体功能紊乱所引起。

More and more attention is focusing on the safty of drinking water suply. In this paper, firstly, chloramine formation and the characteristics and kinetics of monochloramine autodecomposition were studied. Secondly, considering the high concentration of ammonia and the complication of organic matters in Shanghai Huangpu River, formation characteristics and rules of disinfection byproducts were reviewed during the breakpoint chlorination process, and on the basis of grading and clssification of organisms, the control effects of chloramination on DBPs formation were studied. Finally, the formation rules of 2-monochlorophenol, 2,4-dichlorophenol and 2,4,6-trichlorophenol from phenol chlorination were investigated, and related influencing factors and kinetics were analysed.

饮用水的安全供给受到越来越多的重视，本文首先进行了氯胺形态以及一氯胺自降解特性及其动力学研究；然后结合上海黄浦江水源氨氮浓度高、有机物成分复杂的特点，研究折点加氯过程中消毒副产物的生成特性和规律，以及在将有机物分级和分类的基础上，研究氯胺消毒对不同类别有机物生成消毒副产物的控制效果；最后考察了氯化苯酚生成2-一氯酚(2-MCP)、2，4-二氯酚(2，4-DCP)及2，4，6-三氯酚(2，4，6-TCP)的规律，并进行了影响因素和动力学分析。

Two benzothiazole ester compounds containing boron with different alkyl chain, Di-n-hexyl-[2-(2-benzothiazolylthio)] ethyl boric acid ester (BNS-1) and Dicyclohexyl-[2-(2-benzothiazolylthio)] ethyl boric acid ester(BNS-2), were synthesized and their tribological performance as additives in rapeseed oilwas investigated using a four-ball testing machine.

合成了两种含不同烷基链的含硼苯并噻唑酯类化合物，即二正己氧基-2-[(2-苯并噻唑基)硫代]乙氧基甲硼烷(BNS-1)和二环己氧基-2-[(2-苯并噻唑基)硫代]乙氧基甲硼烷(BNS-2)。

The results showed that loading Ag^＋, Ni^2＋, Cu^2＋ or Zn^2＋ ion on the activated carbon obviously improved its adsorption of benzothiophene, while loading Fe^3＋ or Co^3＋ ion on the activated carbon caused a decrease in its adsorption of benzothiophene in comparison with the original unloaded activated carbon, which was due to the variation of the nature of soft and hard acid on the surface of the activated carbon.

采用密度泛函数理论法计算结果表明，苯并噻吩的电负性χ为2.638，属软碱类物质；由于Ag^＋为软酸，活性炭负载Ag^＋离子，增加了其局部表面的软酸，从而增强了对苯并噻吩硫化物的吸附；由于Ni^2＋、Cu^2＋和Zn^2＋离子属交界酸，负载Ni^2＋、Cu^2＋、Zn^2＋离子增加了活性炭表面的交界酸，也在一定程度上提高了其表面对苯并噻吩硫化物的吸附；当活性炭表面负载了硬酸性Fe^3＋或Co^3＋离子，其局部表面硬酸增大从而降低了其对苯并噻吩的吸附。

Experimental results show that the incorporation of appropriate amounts of Al~2O~3 into SO~4^2^-/ZrO~2, SO~4^2^-/TiO~2 and SO~4^2^-/Fe~2O~3 is helpful for stabilizing the sulfur species and increasing the effective acid sites on the catalyst surfaces, which can improve the strong acidity and catalytic activity in benzoylation.

实验表明，向SO~4^2^-/ZrO~2，SO~4^2^-/TiO~2和SO~4^2^-/Fe~2O~3中引入适量的Al~2O~3，有助于稳定样品表面的含硫物种，增加样品表面的有效酸位，提高样品的强酸性和对甲苯的苯甲酰化的反应活性。

Benzylidene[1,3-bis(2,6-dimethylphenyl)-4,5-dihydroimidazol-2-ylidene]dichloro(2-methylpyridine)ruthenium (62), benzylidene[1,3-bis(2,6-dimethylphenyl)-4,5-dihydroimidazol-2-ylidene] dichloro(2,4-dimethylpyridine)ruthen ium (63) introduce ortho substituted pyridine as dissociating ligand to weaken Ru-N bondand accelerate dissociation of pyridine derivative ligand through steric hindrance.

在钌卡宾配合物[1，3-二-(2，6-二甲苯基)-4，5-二氢咪唑基]-苯亚甲基-(2-甲基吡啶)-二氯合钌(62)，1，3-二-(2，6-二甲苯基)-4，5-二氢咪唑基1-苯亚甲基-(2，4-二甲基吡啶)-二氯合钌(63)中，邻位取代的吡啶作为解离配体，通过邻位基团的空间效应削弱钌-氮配位键，使配体更易解离，提高了催化剂的初活性。

Methyl-2,3,5,6-tetrafluoro-benzene methanol was synthesized by chlorination, acylation, fluorination, esterifica- tion, reduction, bromization, reduction from terephthalic acid. Tefluthrin was obtained from-(1RS,3RS)-3-(2-chloro-3,3,3-trifluoro-1-propenyl)-2,2-dimethyl cycolpropa-necarboxylate acid by reacting with 4-methyl-2,3,5,6-tetrafluoro-benzene methanol.

以对苯二甲酸为原料，经氯化、酰氯化、氟化、酯化、还原、溴化、还原七步反应合成了4-甲基-2，3，5，6-四氟苄醇，甲基苄醇与-(1RS，3RS)-3-(2-氯-3，3，3-三氟丙-1-丙烯基)-2，2-二甲基环丙甲酸一步酯化合成了七氟菊酯。

During ～2.68-2.45 Ma, the vegetation was dominated by arbores, mainly Pinus, Chenopodiaceae and Artemisia, indicating a cold warm climate in the mountain region. During ～2.45-2.11 Ma, herbs increased rapidly and the climate became dry-cold, indicating the characteristic of the bushveld climate. During 2.11-1.49 Ma, the quantity and species of the herbs reached the culmination and the bush increased accordingly, showing that the climate became more and more arid. During 1.49-1.36 Ma, herbs declined slightly but pteridophytes increased relatively greatly, revealing a dry-cold grassland climate.

约在2.68～2.45Ma期间，植被以乔木为主，主要为松、藜、蒿，属山地寒温气候；约在 2.45～2.11Ma期间，草本植物迅速上升，气候变得干旱寒冷，显示出灌木草原气候特征；在2.11～1.49Ma期间，草本植物数量和种类达到之最，灌木相对增加，也显示气候进一步趋于干旱；在1.49～1.36Ma期间，草本植物有小幅下降，但蕨类植物增加幅度较大，显示了干冷草原气候特征。

On the basis of spectral analysis, these compounds were identified as Kaempferol , Kaempferol-3-O-β-D-glucopyranoside , Kaempferol-3-O-β-D-galactopyranoside, Quercetin , Quercetin-3-O-β-D-arabinopyranoside, Quercetin-3-O-β-D-galactopyranoside, gallic acid, methyl gallate-4-O-β-D- galactopyranoside, caffeicacid, methyl caffeate, 4-cafeoyl-(3"a, 4"a, 5"β)- trihydroxyquinic acid, 3"-cafeoyl-(3"a, 4"P, 5"P )-trihydroxyquinic acid methyl ester, 5"-cafeoyl-galactonic acid , pumiloside, loganic acid , 5R,6S,7E-megastima-3-on-7-en-9-ol 9-O-β-D-glucopyranoside. 2a, 3β-dihydroxy-oleanoic acid , 2a, 3β, 23-trihydroxy-oleanoic acid, 3a, 6a-dihydroxy-oleanoic acid, 3β-hydroxy-ursoic acid, 2a, 3a, 23-trihydroxy-ursoic acid , 2a, 3β, 23-trihydroxy-ursoic acid, 2β, 3β, 19a -trihydroxy-ursoic acid, 2a , 3β, 19a -trihydroxy-ursoic acid-28-O-β-D-glucopyranoside , 2a. 3a, 19a-trihydroxy-ursoic acid-28-O-β-D-glucopyranoside, 2a, 3a, 19a, 23-tetrahydroxy-ursoic acid, 1a, 3a, 19a, 23-tetrahydroxy-ursoic acid-28-O-β-D-glucopyranoside , 3a, 19a, 23-trihydroxy-ursoic acid.

从珙桐中分离鉴定得到了28种化合物，它们分别是：山奈酚，3-O-β-D-吡喃葡萄糖基-山奈酚甙，3-O-β-D-吡喃半乳糖基-山奈酚甙，槲皮素，3-O-β-D-吡喃阿拉伯糖基-槲皮素甙，3-O-β-D-吡喃半乳糖基-槲皮素甙，没食子酸，4-O-β-D-吡喃半乳糖基-没食子酸甲酯，咖啡酸，咖啡酸甲酯，4-咖啡酰基-(3&α，4&α，5&β)-三羟基鸡纳酸，4-咖啡酰基-(3&α，4&β，5&β)-三羟基鸡纳酸甲酯，5'-咖啡酰基-半乳糖酸，pumiloside，loganic acid，5R，6S，7E-megastima-3-on-7-en-9-ol9-O-β-D-glucopyranoside，2α，3β-二羟基齐墩果酸，2α，3β，23-三羟基齐墩果酸，3α，6α-二羟基齐墩果酸，3β-羟基熊果酸，2α，3α，23-三羟基熊果酸，2α，3β，23-三羟基熊果酸，2β，3β，19α-三羟基熊果酸，2β，3β，19α-三羟基熊果酸-28-O-β-D-吡喃葡萄糖甙，2α，3α，19α-三羟基熊果酸-28-O-β-D-吡喃葡萄糖基甙，2α，3α，19α，23-四羟基熊果酸，2α，3α，19α，23-四羟基熊果酸-28-O-β-D-吡喃葡萄糖基甙，3α，19α，23-三羟基熊果酸。

With Death guitarist Schuldiner adopting vocal duties, the band made a major impact on the scene.

随着死亡的吉他手Schuldiner接受主唱的职务，乐队在现实中树立了重要的影响。

But he could still end up breakfasting on Swiss-government issue muesli because all six are accused of nicking around 45 million pounds they should have paid to FIFA.

不过他最后仍有可能沦为瑞士政府&议事餐桌&上的一道早餐，因为这所有六个人都被指控把本应支付给国际足联的大约4500万英镑骗了个精光。