查询词典 2-butene

To be different from the already chloromethylation catalyst, it has a certain amount of moisture wet, which will not produce huge amounts of doughtic cancerogenic chloromethyl methyl ether during and after the reaction.4,4\'-bisbiphenyl, 1,4-bisbenzene, 1,4-bis(chloro- methyl)-2,5-dimethylbenzene, 1,5-bis-2,4-dimethylbenzene, 4-(chlor- omethyl)-1,2-dimethylbenzene, 1,2-bis-4,5-dimethylbenzene, 5,8-bis-1,2,3,4-tetrahydronaphthalene, 3,3\',5-tris-4,4\'-bisbiphenyl and 3,3\', 5,5\'-tetrakis-4,4\'-bisbiphenyl were synth- esized by using this new catalyst. Results indicated that when the reaction temperature was 55～60℃, the reaction time was 12h, the catalyst which consists of the concentration of 80%H_2SO_4, HAc and Lewis acid, the amount of Lewis acid 0.15 mol(nLewis:nbiphenyl=1.5:1), yield of biphenyl chloromethylation product 4,4\'-bis(chrolomethylbiphenyl can reach a maximum 85%.

采用这种催化体系完成了4，4′-二氯甲基联苯、对二氯甲基苯、1，4-二氯甲基-2，5-二甲基苯、1，5-二氯甲基-2，4-二甲基苯、4-氯甲基-1，2-二甲基苯、1，2-二氯甲基-4，5-二甲基苯、5，8-二氯甲基-四氢萘、3，3'，5-三氯甲基-4，4'-二甲基苯和3，3'，5，5'-四氯甲基-4，4'-二甲基苯的合成，结果表明：在反应条件为：反应温度55～60℃，反应时间12h，选择80%H_2SO_4、冰醋酸和Lewis酸为催化剂，反应最佳反应Lewis酸用量是0.15mol(和原料比为1.5：1)，反应效果最好，联苯氯甲基化产物(4，4′-二氯甲基联苯)收率为85%；在反应条件为：反应温度70℃，反应时间8h，80%H_2SO_4、冰醋酸和Lewis酸为催化剂，反应最佳反应Lewis酸用量是0.1mol(和原料比为1：1)时，反应效果最好，苯的氯甲基化产物收(来源：ABd0C论文eded网www.abclunwen.com)率为75%；在反应条件为：在反应条件为：反应温度40℃，反应时间10h，60%H_2SO_4和Lewis酸为催化剂，反应最佳反应Lewis酸用量是0.1mol(和原料比为1：1)时，反应效果最好，对二甲苯氯甲基化产物(1，4-二氯甲基-2，5-二甲基苯)收率为78.5%；在反应条件为：反应温度35℃，反应时间10h，60%H_2SO_4、冰醋酸和Lewis酸为催化剂，反应最佳反应Lewis酸用量是0.1mol(和原料比为1：1)时，反应效果最好，间二甲苯氯甲基化产物(1，5-二氯甲基-2，4-二甲基苯)收率为81.5%。

Photoinduced Electron Transfer [2+2] Cycloaddition Reactions ofBenzannelated Isoquinolin-1-ones with Electron Deficient Alkenes Photoinduced [2+2] cycloaddition reactions of 11H-benzoxazolo[3,2-b]isoquinolin-11-one 8 and 11H-benzothiazolo[3,2-b]isoquinolin-11-one 13 with electron deficient alkenessuch as acrylonitrile, methyl acrylate, dimethyl fumarate and dimethyl maleate afforded a group of polycyclic isoquinoline derivatives bearing cyclobutane moieties ingood to excellent yields and resulted in the Schenck isomerization of the alkenes.

3苯并增环异喹啉-1-酮与缺电子烯烃的光诱导电子转移[2+2]环加成反应 11H-苯并恶唑[3，2-b]异喹啉-11-酮8和11H-苯并噻唑[3，2-b]异喹啉-11-酮13与缺电子烯烃如丙烯腈，丙烯酸甲酯，富马酸二甲酯及马来酸二甲酯的光诱导[2+2]环加成反应以高产率给出一系列含有环丁烷结构单元的多环异喹啉衍生物并导致烯烃的Schenck异构化作用。

This paper presents a study of Eucalyptus dunnii tissue culture, using its seeds as explants. The results reveal that MS medium is a suitable basic medium for its seeds to germinate and grow; that MS+KT1.0 mg/L+2, 4-D2.0 mg/L+Homocysteine30mg/L is a good medium to induce its seeds to dedifferentiate directly into callus; that H+6-BA2.0 mg/L+IAA0.2 mg/L is a good medium to make its bud on the seedling reproduce more buds; that MS+6-BA2.0 mg/L+NAA0.2 mg/L is a better medium to induce its root on the seedling into callus; that B5+6-BA2.0 mg/L+2, 4-D0.2 mg/L can induce its under-hypocotyl to differentiate into buds; and that B5+Ad2.0 mg/L+IAA0.2 mg/L can induce its under-hypocotyl into callus to generate normal buds.

以邓恩桉种子为外植体，探讨用最少种子快速繁殖最多幼苗的方法，结果表明：MS培养基是较适合邓恩桉种子萌芽和生长的基本培养基；诱导种子直接脱分化成愈伤组织的较佳培养基配方为MS+KT1.0 mg/L+2，4-D2.0 mg/L+半胱氨酸30 mg/L；以邓恩桉实生苗的芽来繁芽的较理想培养基配方为H+BA2.0 mg/L+IAA0.2 mg/L；邓恩桉实生苗的根诱导愈伤组织的较佳培养基配方为MS+6-BA2.0 mg/L+NAA0.2 mg/L；诱导邓恩桉下胚轴分化芽较佳培养基配方为B5+6-BA2.0 mg/L+2，4-D0.2 mg/L；诱导邓恩桉下胚轴脱分化为胚性愈伤组织的较佳培养基配方为B5+Ad2.0 mg/L+IAA0.2 mg/L。

Inthis papor,we synthesize and symbolize three sulphide bicarboxylate ligands such as 2.5-bis-1.3,4-thiadiazole;2,2 -(o-phenylenedimethylenethio) diacetic acid(L11); 2,2 -(m-phenylenedimethylenethio) diacetic acid.

本文合成和表征了2，2′-(1，3，4-噻二唑-2，5-二硫基)二乙酸、2，2′-邻苯二甲硫基二乙酸和2，2′-间苯二甲硫基二乙酸三个含硫二元羧酸配体。

EPR study of the thermal products of these montmorillonites shows that g = 2. 14 signal relates with hydrated copper ions existing in the interlayer of montmorillonites and g = 2. 07 signal relates with Cu~(2+) occupying the ditrigonal cavities of Si-O sheet. And, the supper fine line of g ca. 2. 2 - 2. 7 suggests Cu~(2+) migrating into octahedral vaeancies.

同时，该蒙脱石热处理产物的EPR研究表明、g=2.14信号与蒙脱石层间的水合铜离子相关， g=2.07信号和g为约2.7-2.2超精细结构线分别与进入了粘土矿物Si-O四面体片复三方形孔洞和铝氧八面体空位中的Cu相关。

Part II:The electrocatalytic oxidation of guanine, adenine, guanosine-5'-monophosphate and ssDNA was performed in the presence of iron bis(2,2':6',2"-terpyridine) and Fe tris(1,10-phenanthroline) complexes as a homogeneous catalysts with Fe redox couple. The electrocatalytic and electroanalytic properties of guanine with an iron bis(2,2':6',2"-terpyridine) complex was measured by the amperometry method using the rotating disk electrodes. Electropolymerization of iron tris(5-amino-1,10-phenanthroline) complex produced thin polymer films on a gold, platinum, nickel, and glassy carbon electrode.

第二部分利用iron bis(2，2'：6'，2&-terpyridine)和Fetris(1，10-phenanthroline)之金属错合物当作均相的催化剂对於鸟嘌呤、腺嘌呤、5'-鸟嘌呤核苷单磷酸盐(guanosine-5'-monophosphate)和单股DNA进行电催化氧化的研究。iron bis(2，2'：6'，2&-terpyridine)之金属错合物对於鸟嘌呤的电催化和电分析性质可利用计时安培法并使用旋转环-碟电极进行测量。rontris(5-amino-1，10-phenanthroline)之金属错合物可经由电聚合过程所形成的聚合薄膜固定在黄金、白金、镍和玻璃碳电极上。

Formylation and diformylation of dithieno [2,3-b:3',2'-d] thiophene were prepared by two methods. Firstly, aromatic carbanions were prepared by 1 Br/Li exchange of bromo dithieno[2,3-b:3',2'-d]thiophene with n-BuLi in THF at low temperature; 2 deprotonation of dithieno[2,3-b:3',2'-d]thiophene with LDA.

二噻吩并[2，3-b：3'，2'-d]噻吩单醛与双醛的制备首先通过两种方法产生芳基负离子：1溴代并三噻吩在四氢呋喃中与正丁基锂发生的溴锂交换；2用LDA对二噻吩并[2，3-b：3'，2'-d]噻吩去质子化作用。

SM6 and SM7 of uncrystal were analyzed through GC-MS, the results showedthat SM6 main contained unsaturated fatty aldehyde with fragrance, i.e.-2,4-decadienal(58%), tetradecanoic acid (55.78%), 2-decenal(50%), Phthalic acid isobutylundecyl ester(47%), 2, 4-Decadienal(41%), 2-Undecenal (31%), 2-Methyl-Z,Z-3, 13-octadecadi-enol(18.84%), and SM7 contained saturation alkanes, i.e. 1, 2-Benzenedicarboxylic acid, butyl cyclohexyl ester(23.90%), Triacontane(22.63%),Nonacosane(21.04%), Heptadecane(18.84%), Octacosane(13.58%). Toxicological experiments were done to insure the pigment safety.

并对紫红丝膜菌色素非晶体部分的黄色油状物SM6和紫色粉末物SM7作了GC-MS分析，结果显示SM6中主要为具有香气成分的不饱和脂肪醛，其中含量较高的依次为：-2，4-癸二烯醛(58％)、十四烷酸(55.78％)、2-癸烯醛(50％)、邻苯二甲酸异丁基十一烷酯(47％)、2，4-癸二烯(41％)、2-十一碳烯醛(31％)、2-甲基-Z，Z-3，13-十八碳二烯酸(18.45％)等；SM7中主要为饱和直链烷烃，其中含量较高的依次为：1，2-苯二羧酸丁基环己酯(23.90％)、三十烷(22.63％)、二十九烷(21.04％)、十七烷(18.84％)、二十八烷(13.58％)。

Despite evidence implicating prostaglandins as critical factor in male reproductive functions, little is known about expression and function of COX-2 in the male reproductive system. By using immunohistochemistry, RT-PCR and Western-blot, the content of this research included:(1) The expression and localization of COX-2 in mature rat and human testis were examined.(2) We investigated the changes of spermatogenesis and testosterone levels in testis after by using the COX-2 specific inhibitor-rofecoxib at 2, 4 and 8 weeks.(3) To explore the relationship between the intratesticular level of testosterone and expression of COX-2 by completely destroying the Leydig cells of mature male rats with injection of a single I.

本课题应用免疫组织化学、RT-PCR和Western-blot等方法检测以下内容：(1)在mRNA和蛋白水平检测正常成年男性及大鼠睾丸组织中COX-2的表达及定位情况；(2)实验组大鼠持续给予COX-2酶的特异性抑制剂Rofecoxib，分别于用药后2周、4周和8周检测大鼠的精子生成以及睾丸组织内睾酮浓度的变化；(3)另一组实验大鼠给予特异性Leydig细胞灭活剂EDS，在特定时间内抑制睾丸组织内合成的睾酮，于用药后2周和4周，采用免疫组织化学及RT-PCR方法观察大鼠睾丸组织内睾酮浓度变化对COX-2合成的影响。

Methyl-5-ethyl-2-thiouracil,m.p.211°,was prepared according to the direc- tions of Johnson and Baily.4-Methyl-5-ethyl-uracil,m.p.236°,was formed in a 81% yield from 4-methyl-5-ethyl-2-thiouracil by boiling the latter with an aqueous solution of monochloroacetic acid.4-Methyl-5-ethyl-uracil reacted with phosphorous oxychloride and phosphorous pentachloride,giving 4-methyl-5-ethyl-2,6-dichloropy- rimidine in a 79% yield.

14-甲基5-乙基-2，6-二氯代嘧啶曾用磷醯氯和五氯化磷与其相应的2，6-二羟基嘧啶作用制取。(2)4-甲基-5-乙基-2，6-二氯代嘧啶与醇钠作用，极易转变成4-甲基-5-乙基-2，6-二烷氧基嘧啶。(3)4-甲基-5-乙基-2，6-二甲氧基嘧啶和2-氧代-3，4-二甲基-5-乙基-6-甲氧基嘧啶在高温时重排成其稳定构型的的异构体：1，3，4-三甲基-5-乙基-2，6-二氧代嘧啶。

By the time of its fall, most of the prisoners were writers who had written against the corruptions of the government.

到它被攻陷的时候，里面多数的犯人是写了反对政府贪污文章的作家。

The most obvious variation to ovum morphological character was that the color was changed from light green to sepiaceous in embryonic development, and all the ovums were almost hatched after 96h.

在胚胎发育过程中卵的形态特征最明显的变化是颜色从淡绿到深褐色，卵在发育96h后卵基本全部孵化。