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In addition, electrolytic experiments were carried out with platinum as anode and titanium as cathode at constant current in electrolytic cell without membrane.
使用无隔膜的电解池,以钛基镀铂电极为阳极,以钛电极为阴极,在恒电流的条件下进行了电解实验。
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The problems in current increase of diaphragm electrolyzer and the countermeasures were introduced.
介绍了在隔膜电解槽电流提升过程中所遇到的问题及采取的解决方法和措施。
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The influences for main technical standard and safety production of diaphragm electrolyzer were mainly analyzed.
介绍了频繁升降电流对隔膜烧碱生产装置的影响,着重分析了对隔膜电槽主要技术指标及安全生产的影响,提出了限电时期的升降电流频率及幅度。
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In an electrolytic cell with proton exchange membrane as the diaphragm, it was found from the electrooxidation of 3-picoline at a PbO2 electrode in acetone/water mixed solvents that the current density at the same anode potential not only increases remarkably, but also the selectivity and the current efficiency of electrooxidation from 3\|picoline to nicotinic acid increase obviously compared with the pure water as the solvent.
在以质子交换膜为隔膜的电解槽内,通过3-甲基吡啶在PbO2电极上的电氧化研究,发现在丙酮-水混合溶剂中,与纯水作溶剂相比,不仅在相同阳极电位下电流密度大幅度上升, 3-甲基吡啶电氧化生成烟酸的选择性和电流效率也明显提高。
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Along with of microprocessor of development, the urgent demand have to match with it mutually of connect the issue that ocular exterior measure the equipments directly, root for a living through applied personnel in technique in science, find out a kind of exits already of but the past was output the equipments by the tiny electric current, electric voltage that people neglect, namely the high man in Rogowski electric current spreads to feel machine with divide to press the machine, its output's is several 100 peaceful electric current s/ V electric voltage can control with tiny model protection directly the equipments pick up a people, satisfying the request that protection control measure, and basic dissolves traditional electromagnetism type the electric current, electric voltage feels with each other saturated weakness in machine.
随着微机的发展,迫切要求有配合它的相互连接的问题,眼球的外部测量设备直接,根为口奔驰,通过应用型人才,在技术科学,找到了一种已经退出的,但过去仅仅是输出设备是由微小的电流,电压,人们忽视,即高文在罗柯夫斯基电流差突然觉得机器与隔膜,迫使机,其输出的是几个100和平电流s音频/视频电电压可控制与微小模型直接保护的设备,接了一个人,满足了要求保护控制措施,并基本溶化传统的电磁式电流,电压觉得与对方饱和疲软机器。
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With addition of benzene and under certain current density and temperature, the indirect organic electrosynthesis using lead tetraacetate as media could be carried out in one compartment and no lead metal was deposited on the counter electrode.
在该醋酸电解液中加入一定量的苯,控制一定的电流密度、温度等条件可以阻化铅在对电极上的析出,实现了无隔膜电解槽中四醋酸铅的电解生成,并应用于间接有机电合成。
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In order to solve chromium waste water by means of electrolyzed deoxidation, we apply polyacrylonitrile carbon blanket as pole, graphite as bipolar plate, positive ion film as diaphragm, to an oxidation-reduction system, in which negative pole electrolyzes and reduces chromium waste water; meanwhile, oxides Fe~{2+} into Fe~{3+} in positive pole.
为了电解还原处理含铬废水,以聚丙烯腈碳毡作电极,石墨板作双极板,以阳离子交换膜为隔膜,组装出氧化还原电池系统。此系统阴极电解还原处理含铬废水,同时阳极氧化Fe2+为Fe3+。电池系统的平均电流效率达92.29%,处理后废水中铬含量小于10-5mol/L,达到国家排放标准
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Respectively proceeding with bromine complexing agent of anode, modified membrane and electrolytic additive of cathode, mainly referring to specific power of battery, ratio of self-discharge and zinc dendrite, this paper has studied the influences of different anode additive and modified membrane on specific energy of battery by means of charge and discharge curves, and the influences of electrolytic additive(NH4+, OP-10, TX-10 and dodecyl trimethyl ammonium bromide) on zinc dendrite by means of current-time curve and microscopic morphology observation.
本文分别从正极溴络合剂、隔膜改性和负极的电解液添加剂入手,以电池的比能量、自放电率以及锌枝晶生长情况为主要的性能指标,用电池充放电曲线等方法研究不同正极添加剂和隔膜改性对电池比能量的影响;用电流-时间曲线以及微观形貌观察等方法研究电解液添加剂(NH_4~+、OP-10、TX-10以及十二烷基三甲基溴化铵)对锌枝晶生长的影响。
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The research results demonstrated that it was a good method that hydrxoypivalic acid was prepared from hydroxypivalaldhyde by the direct electrooxidation method at the lead dioxide and tin dioxide electrodes.
以羟基新戊醛为原料,PbO2电极对羟基新戊醛的电催化活性最高,以硫酸为支持电解质,有隔膜电解槽内,生成羟基新戊酸的选择性和电流效率最高。
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The main research work of this dissertation is as follows: Based on the chemical reaction engineering theory and the nitrobenzene electroreduction mechanism, the plate and frame electrolyzer was designed and applied to the process of electroreduction nitrobenzene to p-aminophenol. This dissertation measured the residence time distribution data of the electrolyzer by means of the pulse response method and studied the rule of flow pattern along with the current capacity change. Under different conditions ,this dissertation studied the cyclic voltammetry properties of nitrobenzene on different electrodes by means of the dynamic cyclic voltammetry method and the electrode materials applied to the NB electroreduction have been selected primarily.Baseed on the results of cyclic voltammetry tests, this dissertation used p-electrode systems to measure the steady-state- polarization curves of nitrobenzene on different electrodes in H-type diaphragm cell, and obtained each primary factor s influence rule and the exchange current density value of each electrode.And then on the basis of the conclusions of fundamental researchs upword, the effects of influence factors on the the yield of p-aminophenol and the current efficiency,such as electrode material, current density, quantity of electricity circulated, nitrobenzene concentration . sulpuric acid concentration and so on, have been studied in detail in the systems of hign temperature , strong acidity and oxygen-poorthrough a series of electrolysis experiments in this paper.After all using Pb as anode Monel metal as cathode Dupont Nafion 417 cation-exchange membrane as membrane, this dissertation obtained the optimum technological condition: reaction temperature about 85C, current density 500A m-2, sulphuric acid concentration 20%wt.
论文的主要研究工作为:运用化学反应工程理论,结合硝基苯的电还原机理,设计出用于硝基苯直接电还原合成对氨基苯酚实验的板框式电解槽,并利用脉冲响应法测定了该板框式电解槽的停留时间分布数据,研究了流型随流量变化的规律;通过动态循环伏安法研究了硝基苯在不同电极上、不同条件下的循环伏安特性,初步评选出了用于硝基苯电还原的电极材料;结合循环伏安的测定结果,在H型隔膜电解槽中采用三电极体系测定了硝基苯在不同电极上、不同条件下的稳态极化曲线,得到了各主要因素的影响规律及硝基苯在各个电极上电还原的交换电流密度数值;在基础研究结论指导下,采用板框式电解槽,在高温、强酸、贫氧系统中,进行了一系列的电解实验,分别考察了电极材料、电流密度、通电量、硝基苯浓度、硫酸浓度等因素对收率及电流效率的影响,最终选择以蒙乃尔合金电极作为阴极、铅合金为阳极、Dupont Nofion 417阳离子交换膜为隔膜,得到由硝基苯直接电还原制对氨基苯酚的最佳电解工艺条件:反应温度85℃,电流密度500A·m~(-2),硫酸浓度20%wt。
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diaphragm current:隔膜电流
diaphragm gauge 隔膜压力计 | diaphragm current 隔膜电流 | diaphragm cell 隔膜电解槽