- 更多网络例句与重氮甲烷相关的网络例句 [注:此内容来源于网络,仅供参考]
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The recognition capability and adsorption rate of MIP can be significantly enhanced by selective modification.Separation factor could be increased from 1.60 to 3.06 after modification when naringenin was chosen as competitive molecules, and the time needed for adsorption equilibrium could be reduced from 100 min to 60 min.Within a certain range, increasing template molecule concentration or diazomethane dosage, or adopting solvent which had weaker hydrogen bond action with template molecules could all improve the modification effect.
结果表明,选择性修饰能明显提高MIP的识别能力与吸附速度,以柚皮素为竞争分子,分离因子可从修饰前的1.60提高到修饰后的3.06,吸附平衡时间从修饰前的100 min降低至修饰后的60 min;在一定范围内提高模板分子浓度,增大重氮甲烷用量,采用形成氢键能力较弱的溶剂,均能提高修饰效果。
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Molecularly imprinted polymer using quercetin as template molecules, methacrylic acid as functional monomers, ethylene glycol dimethacrylate as crosslinking agent were prepared, and the binding sites of MIP were selectively modified with diazomethane.The effects of template molecule concentration, solvent and diazomethane usage on modification were discussed.
以槲皮素为模板分子,甲基丙烯酸为功能单体,乙二醇二甲基丙烯酸酯为交联剂,制备了分子印迹聚合物,并以重氮甲烷为修饰剂,对MIP的结合点进行了选择性修饰,探讨了模板分子浓度、溶剂及重氮甲烷用量等对修饰效果的影响。
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Herein, we report the enantioselective total syntheses of slagenins A-C and their antipodes. Starting from readily available ethyl -4-chloro-3-hydroxy-butanonate, elongation of the carbon chain with diazomethane, followed by oxidation of the given α-diazoketone using distilled DMD, afforded a key intermediate α-ketoaldehyde .
本文从方便易得的-4-氯-3-羟基-丁酸乙酯出发,经重氮甲烷延伸碳连、DMD氧化相应的α-重氮酮,制得α-酮醛;该化合物与尿素在氢氟酸作用下,以协同方式非对映选择性的直接构建了cis-四氢呋喃并[2,3-d]咪唑啉-2-酮双环结构,进而合成了天然产物slagenins A、B、和C的对映体。
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Methylimidazole in soy sauce was extracted with methylene chloride,diazotized to forms a red colored azo-compound with the highly absorbance at the wave length of 440nm and determined by ultraviolet-visible spectrometry.
酱油样品在层析柱中用二氯甲烷洗脱,经重氮化后在波长440nm处具有最大吸收,据此建立了紫外可见光谱法测定酱油中4-甲基咪唑的方法。
- 更多网络解释与重氮甲烷相关的网络解释 [注:此内容来源于网络,仅供参考]
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diazomethane:重氮甲烷
用于制备重氮甲烷(diazomethane)的前体物质. 用于转移金属复合物、氨基、负碳离子等的亚硝基化试剂.
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diazomethane:重氮甲烷 重氮甲烷
diastereomeric excess;DE 非對映體過量 非对映体过量 | diazomethane 重氮甲烷 重氮甲烷 | dictyostele 網狀中柱 网状中柱
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4-methylphenyl diazomethane:4-甲苯基重氮甲烷
"2-methylpentene","2-甲基戊烯" | "4-methylphenyl diazomethane","4-甲苯基重氮甲烷" | "2-methylpropane","2-甲基丙烷"
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azimethane; azimethylene; diazomethane:重氮甲烷
重氮乙烷 aziethane; aziethylene; diazoethane | 重氮甲烷 azimethane; azimethylene; diazomethane | 偶氮亚胺苯 azimidobenzene; aziminobenzene
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diazonium:重氮
diazomethane 重氮甲烷 | diazonium 重氮 | diazoniumsalt 重氮盐
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diazonium:重盐
diazomethane 重氮甲烷 | diazonium 重盐 | diazotization 重氮化作用
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diazonium halide:卤化重氮
diazomethane 重氮甲烷 | diazonium halide 卤化重氮 | diazonium salt 重氮盐
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diazonium compound:重氮化合物
diazonium ion 重氮离子 | diazonium compound 重氮化合物 | diazomethane 重氮甲烷
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aziethane; aziethylene; diazoethane:重氮乙烷
迭氮苯 azidobenzene | 重氮乙烷 aziethane; aziethylene; diazoethane | 重氮甲烷 azimethane; azimethylene; diazomethane
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azimino; diazoamine:重氮胺
"azimethane; azimethylene; diazomethane","重氮甲烷" | "azimino; diazoamine","重氮胺" | "azimuthal effect","[角]方位效应"