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Suitable water-immiscible organic solvents include aromatic hydrocarbons, eg toluene, xylene, naphthalene, tetrahydronaphthalene and methyl naphthalene; chlorinated aromatic hydrocarbons, eg chlorobenzene, fluorobenzene, chloronaphthalene and bromonaphthalene; esters, eg butyl acetate, ethyl acetate, methyl benzoate, ethyl benzoate, benzyl benzoate, butyl benzoate, phenylethyl acetate, butyl lactate, benzyl lactate, diethyleneglycol dipropionate, dimethyl phthalate, diethyl phthalate, dibutyl phthalate, di(2-ethylhexyl) phthalate; alcohols having six or more carbon atoms, eg hexanol, octanol, benzyl alcohol, phenyl ethanol, phenoxy ethanol, phenoxy propanol and phenoxy butanol; ethers having at least 5 carbon atoms, preferably C 5-14 ethers, eg anisole and phenetol; nitrocellulose, cellulose ether, cellulose acetate; low odour petroleum distillates; turpentine; white spirits; naphtha; isopropylbiphenyl; terpene; vegetable oil; mineral oil; essential oil; and natural oil; and mixtures of any two or more thereof.
适用于水互溶的有机溶剂包括芳香族碳氢化合物,如甲苯,二甲苯,萘,四氢萘和甲基萘;氯代芳香族碳氢化合物,如氯苯,氟,氯萘和萘;酯类,如醋酸丁酯,醋酸乙酯,苯甲酸甲酯,苯甲酸乙酯,苄酯,苯甲酸正丁酯,苯,醋酸丁酯乳酸,乳酸苄,二甘醇二丙酸酯,邻苯二甲酸二甲酯,邻苯二甲酸二乙酯,邻苯二甲酸二丁酯,二(2乙基己基)酯;醇有6个或更多碳原子,如己醇,辛醇,苯甲醇,苯乙醇,苯氧基乙醇,丙醇和苯氧基苯氧丁醇;醚至少有5个碳原子,最好荤5-14醚,如苯甲醚和phenetol;硝化棉,纤维素醚,醋酸纤维素,低气味石油蒸馏;松节油;白酒,石脑油isopropylbiphenyl;萜类,植物油,矿物油,挥发油;和天然油,以及任何两个或两个以上其混合物。
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The results indicated that the use of such membrane could achieve satisfactory separation effects (condensate of high alcoholicity and rich flavoring substances was obtained, membrane-flowing rate: ethanol>esters except ethyl lactate>aldehyde>other alcohol>water), the membrane had good selectivity to ethanol and ethyl caproate had good membrane-flowing rate and membrane-passing percentage, however, ethyl lactate, aldehyde and methanol had poor mambrane-passing percentage with heavy loss during membrane-passing.
结果表明,渗透汽化膜有良好的分离性能,可得到高酒精度、香味物质富集的冷凝液;过膜速率:乙醇>酯类>醛类>其他醇类>水;膜对乙醇选择性好,己酸乙酯的过膜率及过膜速率高;乳酸乙酯、醛类及甲醇过膜率较小、损失量较大;渗透汽化膜用于白酒的香气成分分离有良好的工业应用前景。
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The results showed that there were 8 kinds of aliphatic, 5 kinds of esters, 2 kinds of aldehydes, 2 kinds of nitrogen sulfur heterocyclic rings and one kind of hydrocarbon, alcoholics, ketone, lactones respectively in the analyzed 21 kinds of aroma components, and the content of furfural,β-methyl valeric acid, palmitic acid, nicotine, neohytadiene were higher, next were acetyl ethyl propionate, caleric acid, phenyl ethyl acetate, hydroxylic diethyl succinate.
结果表明,在分析出的21种香气成分中,分别有脂肪酸类8种,酯类5种,醛类2种,氮硫杂环类2种,烃类、醇类、酮类、内酯类各l种,其中相对含量较高的物质成分是糠醛、β-甲基戊酸、十六碳酸、烟碱、新植二烯,其次是乙酰丙酸乙酯、异戊酸、苯乙酸乙酯、羟基丁二酸二乙酯等。
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Analytical results showed that the upper clear liquid of pyrolysis oils was mainly consisted of water-soluble substances,such as phenol,cresol,xylenol,sugars,hydantoins,morpholines,pyranones and pyridine derivatives compounds,etc.,while the lower sediment was mainly insoluble or hardly water-soluble substances,such as the big substituent phenolics(the number of substituent carbon atoms of which is greater than or equal to 2),aryl phosphate esters,fatty acid esters and nitrile compounds,and so on.
研究表明,热解油上层清液主要是一些较易溶于水的物质,如苯酚、甲酚、二甲酚、糖类、乙内酰脲类、吗啉类、吡喃酮类和吡啶类化合物等;而下层沉淀则主要为不溶或难溶于水的物质,如大取代基酚类(取代基碳原子数≥2)、磷酸三芳基酯类、脂肪酸酯类和腈类化合物等。
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ABSTRACT The thesis aims at the studies on the total synthesis of α-alkylidene -β-hydroxy-γ-butyrolactones. It consists of the following three parts: Part Ⅰ: Review: Some studies on the total the synthesis of α-methylene-γ-butyrolactones, polysubstitution-γ-butyrolactones and α-alkylidene-β-hydroxy-γ-butyrolactones, were reviewed.
本论文以α-亚烷基-β-羟基-γ-丁内酯类天然产物的全合成研究为主,包括三个部分:第一部分:文献综述:着重介绍了α-亚甲基-γ-丁内酯萜类,多取代-γ-丁内酯类和α-亚烷基-β-羟基-γ-丁内酯类天然产物的全合成研究工作。
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The esterifying effects of monascus, daqu and rhizopus strain on single acid (acetic acid, caproic acid, lactic acid, butyric acid) and mixed acid (acetic acid,caproic acid,lactic acid, and butyric acid mixed together according to the ratio of 1∶1∶1∶1) were studied.
对红曲霉、大曲以及根霉菌对单一酸(乙酸、己酸、乳酸、丁酸)和混合酸(四大酸按1∶1∶1∶1混合)的酯化效果进行了研究,结果表明,红曲霉能促进己酸、丁酸及混合酸与乙醇的酯化作用,生成的酯类物质均为己酸乙酯,而且酯化能力极强;大曲能促进己酸、丁酸及混合酸与乙醇的酯化作用,生成的酯类物质均为己酸乙酯,并且能促进乙酸与乙醇的酯化生成乙酸乙酯;根霉能促进己酸和混合酸与乙醇的酯化作用,生成少量的己酸乙酯和乳酸乙酯。
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In addition, a benzene, toluene (0.32%), was also detected in 80% ripening fruit. In 90% ripening fruit were detected 27 kinds of aroma components belonging to 2 categories. Among the components, 17 were esters, and 10 alkenes. Of the 17 esters, methyl octanoate is the highest (21.00%), followed by ethyl hexanoate (17.64%), methyl hexanoate (14.34%). Of the 10 alkenes cis-β-ocimene is the highest (1.00%), followed by à-copaene (0.81%) and trans-ocimene (0.48%).
在9成熟果实中检测到2类共27种香气成分,分别是酯类17种和烯类10种;在酯类中,相对含量最高的是辛酸甲酯(25.27%),其次是辛酸乙酯(21.00%)、己酸乙酯(17.64%)、己酸甲酯(14.34%);在烯类中相对含量较高的有β-顺式-罗勒烯(1.00%)、à-蒎烯(0.81%)和反式-罗勒烯(0.48%)。
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The result showed due to yeast fermentation process there were many new aroma components in jujube wine which were different from the juice: Isoamyl alcohol, Phenylethyl alcohol, Benzyl alcohol and so on; jujube juice hexadecanoic acid and other senior fatty acid composition obviously degradated; Alcohols and esters composition were sharply upward.
反映出发酵过程由于酵母的繁殖代谢产生了很多新成分,如异戊醇,丁酸乙酯,辛酸乙酯等;枣汁中十六酸等高级脂肪酸成分明显降解,苯乙醇,2,3-丁二醇,己二酸(2-甲基)丁酯,己二酸二异丙酯等醇类和酯类成分呈急剧上升的趋势。
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Phthalic acid esters are widely used in the many fields of industry. So many countries including China have come to pay attention to them and make up the codes for limiting the content in some products such as textile. By combining international codes, the thesis selects coating and textile that have close relative with people as objections. The research results are as follows:1. The thesis has established the textiles preparation method by a series of experimentations such as extraction solvent, extraction time, solid-phase extraction. The average recoveries of eleven phthalates are from 80.30% to 98.00%, and the relative standard deviations from 0.59% to 2.56%, the results show that this method is accurate and credible.2. The thesis set up the simultaneous determination of benzene, toluene, xylenes and phthalates in coatings.
邻苯二甲酸酯类化合物被广泛地应用在工业领域的各个方面,国际上已经开始重视邻苯二甲酸酯作为一种内分泌干扰素的危害性,对在一些产品中的用量作出了限制,但没有具体的分析测定方法,本论文结合国际法规选择了与人们生活密切相关的涂料和纺织品来研究其中邻苯二甲酸酯类环境激素的测定方法,研究内容如下:(1)通过对提取溶剂、提取方式、提取时间的选择实验以及固相萃取的一系列条件实验,首次建立了纺织品中测定邻苯二甲酸酯类环境激素的前处理方法,并对分析方法作了准确度、精密度验证。
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Alcohols, ketones, esters, alcohols, ethers common media are methanol, ethanol, ethylene glycol, propanol, etc., ketones medium with acetone, methyl ethyl ketone, etc., there are a variety of methyl esters of medium, ethyl ester, ether medium with ether, ethyl ether, butyl ether, etc., they basically did not corrosive materials can be used for the specific use of the property should also be under the media and related requirements to make reasonable choices.
醇类、酮类、酯类、醚类常见的醇类介质有甲醇、乙醇、乙二醇、丙醇等,酮类介质有丙酮、丁酮等,酯类介质有各种甲酯、乙酯等,醚类介质有甲醚、乙醚、丁醚等,它们基本没有腐蚀性,常用材料均可适用,具体选用时还应根据介质的属性和相关要求做出合理选择。
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ester:酯(类)
与 颜料膏(MC-Colors)不变黄颜料拉卡(NY-Colors)兼容性良好, 物性优良具中等光泽度,薄膜韧性佳耐磨性优异不会粉化 或圭化,耐旋光性(UV light)特优且具有良好之白色遮盖力与均 匀度. 溶剂(Solvent): 酯类 (Ester)、酮类 (Ketone)、醇类 (Alcohol)
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Jojoba Esters:霍霍巴酯类
Cetyl Ethylhexanoate, 鲸蜡醇乙基己酸酯 | Jojoba Esters, 霍霍巴酯类 | Pentaerythrityl Tetraethylhexanoate, 季戊四醇四(乙基己酸)酯
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Decyl Oleate:油酯癸酸,合成酯类
Panthenol:维B5 | Decyl Oleate;油酯癸酸,合成酯类 | Octyldodecanol:辛基十二烷醇,界面活性剂,稠化剂,刺激性较强
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geranyl:(香叶酯) 酯类
CitronellaI (香茅醛) 醛类 | Geranyl (香叶酯) 酯类 | Menthone (薄荷类) 酮类
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ARGAN OIL PEG-8 ESTERS:阿干树油 PEG-8 酯类
ARGANIA SPINOSA KERNEL OIL刺阿干树(ARGANIA SPINOSA)仁油 | ARGAN OIL PEG-8 ESTERS阿干树油 PEG-8 酯类 | ARGAN OIL POLYGLYCERYL-6 ESTERS阿干树油聚甘油-6 酯类
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ARGAN OIL POLYGLYCERYL-6 ESTERS:阿干树油聚甘油-6 酯类
ARGAN OIL PEG-8 ESTERS阿干树油 PEG-8 酯类 | ARGAN OIL POLYGLYCERYL-6 ESTERS阿干树油聚甘油-6 酯类 | ARGEMONE MEXICANA OIL蓟罌粟(ARGEMONE MEXICANA)油
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Esters:酯类
在oregano中的四种主要的化学的物质说明了其巨大的治愈品质: 醇类(alcohols),酯类(esters),酚类(phenols),和松烯类(terpenes). 醇类使oregano有著一流的防腐性和抗病毒性. 酯有抗真菌和镇静性的能力. 酚在身体中有防腐和抗氧剂反应,
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HAZEL SEED OIL POLYGLYCERYL-6 ESTERS:榛籽油聚甘油-6 酯类
HAZEL SEED OIL PEG-8 ESTERS 榛籽油 PEG-8 酯类 | HAZEL SEED OIL POLYGLYCERYL-6 ESTERS 榛籽油聚甘油-6 酯类 | HC BLUE NO. 2 HC 蓝 NO. 2
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HAZEL SEED OIL PEG-8 ESTERS:榛籽油 PEG-8 酯类
HAY WATER 干草水 | HAZEL SEED OIL PEG-8 ESTERS 榛籽油 PEG-8 酯类 | HAZEL SEED OIL POLYGLYCERYL-6 ESTERS 榛籽油聚甘油-6 酯类
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propylene glycol dicaprate:丙二醇二癸酸酯,合成酯类润肤剂
linoleic acid:亚麻仁油酸 | propylene glycol dicaprate:丙二醇二癸酸酯,合成酯类润肤剂 | pentylene glycol:戊二醇,有抑菌的作用哦