配合

基本解释 (translations)

assortment  ·  conjugate  ·  conjugation  ·  cooperate  ·  ordonnance  ·  conjugating  ·  cooperated  ·  cooperates  ·  proportioning

词组短语

co-operate · fitting-in

与配合相关的网络例句 [注：此内容来源于网络，仅供参考]

In complex 1,Cucan be described as a four-coordinated square planar geometry.Compound 8 is the sodium salt of plumbagin and exists as ionic compound.Compounds 9-16 are the rare earth complexes of plumbagin with La,Y,Dy,Sm,Gd,Nd,Erand Eu.Compound 17 is binuclear Y complex.18 is mononuclear Ycomplex with plumbagin and another ligand from Plumbago Zeylanica.Compounds 19-21 are the ternary complexes with plumbagin and 2,2\'-bpy and phen as assistant ligand.In 19, the geometry of Cucan be described as five-coordinated distorted square pyramid that exists in a dimer through the weak bonding,and 1-D chain structure is formed by intermolecular hydrogen bonds.

化合物1的单晶结构分析表明1具有四配位平面四边形结构，化合物8是白花丹素的Na盐，以离子化合物形式存在；化合物9～16为白花丹素的La，Y，Dy，Sm，Gd，Nd，Er，Eu的稀土金属配合物；化合物17是白花丹素的双核钇结构；化合物18为白花丹素的单核钇结构，该配合物除了含白花丹素外，还有来自白花丹植物中的另一个单体化合物也参与配位；化合物19～21是以2，2\'-联吡啶和邻菲咯啉等含N配体为辅助配体，具有白花丹素—含N配体—金属离子的三元配合物，化合物19是白花丹素和2，2\'-联吡啶与Cu的配合物，具有五配位的四方锥构型，通过Cu…O弱的成键作用形成二聚体，再通过分子间的氢键作用进一步形成一维链状结构，化合物20和化合物21是白花丹素分别与2，2\'-联吡啶和邻菲咯啉的Zn配合物，都具有六配位八面体构型的双核锌配合物，呈一维链状结构，化合物20中链与链之间的大量氢键将一维链扩展成二维层，分子间的π-π堆积作用进一步形成三维结构。

In 300mg/kg JSS treatment, the yolk color was 6 degree too. While added 500mg/kg JMH into the basal diet, the egg yolk color was up to 9 degree. Supplement of oxytetracycline + JMH or chlortetracy dine + JMH in the basal diet, the egg yolk color was up to 8 and 6 degree respectively and decreased one and three color unit respectively than that of JMH treatment. Added oxytetracyclimne + JSS or chlortetracycline + JSS, the egg yolk color was up to 8 and 6degree respectively. When added arsanilic acid + JSS, the egg yolk color was up to 7 degree and improved one color unit than that of JSS treatment. When added arsanilic acid +JMH to basal diet, the egg yolk color was up to 8 degree and decreased one color unit than that of JMH treatment.

饲料中添加300mg/kg的金闪闪，蛋黄颜色也是6级，没有产生增色效果，添加500mg/kg的加美黄，可使蛋黄颜色达到9级，提高3个比色单位，土霉素与加美黄配合使用，蛋黄颜色为8级，比加美黄组降低1级，金霉素与加美黄配合使用蛋黄颜色为6级，比加美黄组降低3级，土霉素与金闪闪配合使用可使蛋黄颜色升到8级，比金闪闪组提高2级，金霉素与金闪闪配合使用蛋黄颜色仍为6级，阿散酸与金闪闪配合使用，蛋黄颜色为7级，比金闪闪组提高1级，阿散酸与加美黄配合使用蛋黄颜色为8级，比加美黄组降低1级。

The crystal structures have been determined by single-crystal X-ray diffraction.Cadmium atoms in compounds 1 and 2 show an eight-coordinated distorted square-antiprismatic geometry and a seven-coordinated distorted pentagonal bipyramidal geometryrespectively. Copper atoms in compounds 3 and 4 show a six-coordinated distorted threeprismatic geometry and a four-coordinated distorted tetrahedral geometry respectively.

所有配合物的晶体结构都通过单晶X-射线衍射确定：配合物1中的镉离子周围显示八配位的扭曲四方反棱柱构型；而配合物2中的镉离子周围显示七配位的扭曲五角双锥构型；配合物3中的铜离子周围显示六配位的扭曲三棱柱构型；配合物4中的铜离子周围显示四配位的扭曲四面体构型；配合物5中的锌离子周围显示六配位的扭曲八面体构型。

In this thesis, a series of complexes based on aromatic multicarboxylic acids have been successfully synthesized in solutions or under hydrothermal conditions. Their structure and properties are investigated.(1) Eight complex compounds have been synthesized and characterized by X-ray single crystal diffractive technology: The eight complexes are listed as following: [Cu242] complex 1 [Cd22(H2O)4]·4H2O complex 2 [Co(H2btc)(H2O)3] complex 3 [Co2(H2O)2]·H2O complex 4 [Ni22(H2O)4] complex 5 [Cu22(H2O)4] complex 6 [Co(H2biim)2(H2O)2](H2btc) complex 7 [Zn(H2biim)2(H2O)2](H2btc) complex 8 The structure of complex 1 is dinuclear complex resulted from weak interactions（0-D chain）; complex 2 is 1-D chain stucture result from interactions of water molecules; complex 3、4、5、6 are coordination polymers using hydrothermal synthses, where the first kind ligand is H4btc, the second kind ligand is phen and Co2+、Ni2+、Cu2+ as center ions, respectively. While the coordination enviroment of Co2+ is the same in complex 3, the coordination geometries around the Co atoms in complex 4 are obviously different because of the different reaction conditions. In complex 4, the 1-D chains are connected into 2-D layer through carboxy groups of ligand H4btc. The structures of complex 5、6 are 1-D chain stucture result from interactions of carboxy groups in ligand H4btc. Complex 7、8 are homeomorphy compounds. Either of them are linked to the 3-D chains through intermolecular hydrogen bonds. Each H4btc lose two protons and H2btc2- acts as negative electron balance.

合成了8个结构新颖的配合物，并用X-射线单晶结构分析方法确定了晶体结构，分别为： [Cu242] 配合物1 [Cd22(H2O)4]·4H2O 配合物2 [Co(H2btc)(H2O)3] 配合物3 [Co2(H2O)2]·H2O 配合物4 [Ni22(H2O)4] 配合物5 [Cu22(H2O)4] 配合物6 [Co(H2biim)2(H2O)2](H2btc)配合物7 [Zn(H2biim)2(H2O)2](H2btc)配合物8 配合物1是一个依靠弱作用连接的双核铜结构；配合物2借助水分子形成一维链状结构；配合物3、4、5、6是以H4btc为第一配体、phen为第二配体，通过水热法合成的配合物，其中，Co2+、Ni2+、Cu2+为中心离子；配合物3中的二价钴离子具有相同的配位环境，不同反应条件下得到的配合物4中的二价钴离子存在不同的配位环境，在配合物4中，一维链通过H4btc上的羧基形成一个二维层结构；配合物5、6是借助H4btc上的羧基形成的一维链状结构；配合物7、8属于异质同晶结构，它们的分子通过分子间氢键形成三维网状结构，H4btc上的羧基失去2个质子，作为一个二价负离子起到电荷平衡作用。

We studied the fluorescent capability of Binolate lanthanide complexes. Thefluorescent analysis shows that both ligand and complexes exhibit luminescence. Insolid state and solution, they have the different luminescence mechanism, intensity andcolor. So we can synthesize the complexes of dissimilar fluorescence performance bychanging the state and solvent polarity. According to the literatures, the complexes playan important role in luminescence material and probe with the development of theinformation technique.

对合成的八个邻萘酚稀土配合物进行发光性能研究，通过荧光光谱分析显示，配体和配合物都能够发出荧光，并且在固体状态和溶液中的发光机制、光强度及发光颜色都不同，所以通过改变邻萘酚稀土配合物的状态以及所选溶剂极性的不同，可以得到荧光性能不同的邻萘酚稀土配合物；根据查阅的文献可知，这类配合物在发光方面的应用很少，所以在当前信息显示技术高速发展的今天，邻萘酚类发光稀土配合物在发光器件、荧光探针等材料的研究领域当中不仅具有理论意义还有实际的应用价值。

In order to get the information of interaction between metal complex and DNA and select metal complexes which can cleave DNA effectively, twenty seven transition metal complexes containing O/N coordinate atoms have been synthesized in this thesis. We report the synthesis, crystal structure and properties of the complexes. One of the complexes is the first μ〓-oxalato tetranuclear Cu complex, in which there is ferromagnetic interaction between the copper atoms bridged by oxalate ions. Two trinuclear copper complexes containing partial cubane Cu〓O〓 cores have been synthesized and discussed the magnetic properties.

为了解金属配合物与DNA的相互作用及筛选能有效切割DNA的金属配合物，为无机药物合成及应用提供基础信息，本文利用十个含N、O原子的多齿配体设计合成了二十七个未见文献报道的过渡金属配合物，并解析了它们的晶体结构：其中包括首例μ〓-草酸根的四核铜配合物；合成了两个具有μ〓-OH〓三核缺角立方烷结构的Cu配合物；以HCBP衍生物为配体合成了七个过渡金属配合物；以SCN〓、N〓，C〓O〓等为桥联配体，以dmpyen为端基配体合成了十一个配合物。

All the ligands and complexes have been characterized with ~1H-NMR, MS and EA.X-Ray single crystal diffraction reveals that zirconium complex containing the tert-butyl substituted N_2O_2 ligand is an oxo- and hydroxyl-bridged dinuclear structure, which is possibly formed by partial hydrolysis of chlorides at one of the zirconium centers. A tetranuclear zirconium complex has been obtained and chacaterized, which is formed by complete hydrolysis of the chlorides at the zirconium centers.

通过研究配合物的单晶结构，我们发现叔丁基取代的不对称N_2O_2配体与ZrCl_4反应生成的锆配合物为氧桥和羟基桥连接的双核锆配合物，中间过程涉及单核锆配合物中氯原子部分水解，并得到氯原子部分水解的双核锆配合物和全部水(来源：8e6eAB67C论文网www.abclunwen.com)解的四核锆配合物的晶体结构，在晶体培养过程中发现双核锆配合物能够以手性自发拆分结晶析出。

The main contributions of this thesis are:(1) Seven mononuclear complexes of tetradentate ligand NTB have been obtained using N〓 or SCN〓 as the additional ligand;(2) Seventeen binuclear complexes of Fe , Zn , Co , Cu have been designed and the complexes of Co , Cu exhibit antiferromagnetic properties;(3) Changing the bridged-ligand such as PO〓, CO〓, o-phth, mai, Ag (CN 〓, Au 〓, etc , fourteen tetranuclear complexes of polypridine ligand have been synthesized;(4) Two antiferromagnetic 1D chain complexes of KH〓pdc ligand have been prepared from hydrothermal reactions; in addition, one ferromagnetic 1D chain copper complex of tpdp which is bridged by oxalate has been obtained.

本论文的主要贡献为：(1)合成了配体NTB的七个新型单核配合物；(2)合成了十七个铁、锌、钴及铜系列混桥双核配合物，其中双核钴和双核铜配合物为反铁磁偶合；(3)选用多吡啶配体tpdp和TPA，改变桥联配体，合成了十个四核配合物；(4)选择配体KH〓pdc，采用水热合成方法得到了反铁磁性一维链状锰、铜配合物；以草酸根为桥联配体，合成了配体tpdp的一维链状铜配合物，该化合物为铁磁偶合，文献较少报道。

Several novel structures have been determined: Unique ninenuclear complexesincorporating 3d, 4f metals with a sodium ion center, the sodium ion may be serve as atemplate in the formation of these novel complexes; Novel tetranuclear 〓complexes with channels formed by intermolecular weak interactions; First 〓type tetranuclear complex; Peculiar "dimer of dimers" complexes derived frombinuclear complex; Unusual one-dimensional wave chain formed by weakcoordination bonds and hydrogen bonds and two dimensional coordination polymerconstructed through coordination bonds and hydrogen bonds.

1获得了多个文献首报和罕见的特殊结构的配合物：两个同时含有碱金属-过渡-稀土金属的独特的九核配合物；两个具有孔道的稀土-过渡金属异四核配合物；草酰胺类〓四核配合物；两个由双核配合物通过叠氮和单个氯原子连成的四核配合物，尤其是以单个氯桥相连的化合物非常少见；一个由弱配键和氢键连成的具有一维波浪形结构的配合物；一个通过配位键和氢键连成的二维配位聚合物。

According to Johnson's Rule and IR spectra, their possible structures are suggested. The bonding parameters of those complexes are calculated by ESR parameters. And the crystal field parameters are calculated by using electronic spectral data. It can be seen that the vanadyl complexes in the solution are ionic complexes and that the α〓 values of those complexes decrease following the increasing of the N donor replacing the O donor of water on the equatorial plane in those complexes. This means that the covalent bonding between vanadium and ligand increases as Ser, Phen or Bipy replace water ligands. The results show the competitive coordinate law that the coordination reactivity of Phen and Bipy is much stronger than that of Ser. The simulation program of ESR is compiled by the theory of ESR in the present work.

测定了VO-丝氨酸二元体系、VO-丝氨酸-邻菲咯啉三元体系和VO-丝氨酸联吡啶三元体系在不同酸度下（pH=1.0～14.0）的乙二醇／水（V／V=1：1）溶液低温ESR谱，发现不同pH下，溶液中具有不同组成的配合物，根据不同pH下ESR谱的变化，利用Johnson的加合规则并结合红外光谱，推测了它们在溶液中的可能结构；利用波谱参数计算了配合物键参数；利用电子光谱数据计算了配合物的晶体场参数，讨沦了它们的成配特性，结果表明：VO配合物属离子型配合物，随取代水分子的配体（Ser、Phen或Bipy）数目增加，键参数减小，配合物共价性增强，同时得出这些体系中，生物配体竞争配位规律：Phen和Bipy与VO的配位能力比Ser强。

与配合相关的网络解释 [注：此内容来源于网络，仅供参考]

mate：配合

这些位置约束从工程设计角度可分为以下五类:(1)面配合(mate)及等距配合(mateoffset):面配合要求装配体部件的两个表面相互接触,即两面的法向量相反,面的等距配合要求两个表面相向平行且相距某个距离.

snug fit：密配合,滑动配合,滑配合

snuffle valve 泄气阀 | snug fit 密配合,滑动配合,滑配合 | snug washer 平垫圈

fit tolerance：配合公差

配合公差(fit tolerance)是指组成配合的孔、轴公差之和. 它是允许间隙或过盈的变动量. 孔和轴的公差带大小和公差带位置组成了配合公差. 孔和轴配合公差的大小表示孔和轴的配合精度. 孔和轴配合公差带的大小和位置表示孔和轴的配合精度和配合性质.

Complexes：配合物

配合物基础和配位立体化学配合物(complexes)的基本观念配合物(complexes)的基本观念配合物的异构(isomerism)现象一.配合物(complexes)的基本观念双齿配体 乙二胺(en) 联吡啶(bpy)大环配体配合物的模板(template)合成:Cu2+与2,

clearance fit：间隙配合, 动座配合, 活动配合

clearance fee ==> 出港手续费 | clearance fit ==> 间隙配合,动座配合,活动配合 | clearance for expansion ==> 膨胀间隙

close fit：过盈配合,紧配合

close || 关闭(用于档案),闭合(用于边界,线,面域) | close fit || 过盈配合,紧配合 | close running fit || 紧配合,紧转配合

close running fit：紧配合,紧转配合

close fit || 过盈配合,紧配合 | close running fit || 紧配合,紧转配合 | close the door behind you || 请随手关门

driving fit bolt：牢配合螺栓,密配合螺栓

driving fit ==> 牢配合 | driving fit bolt ==> 牢配合螺栓,密配合螺栓 | driving flange ==> 传动凸缘

tight fit：紧配合,静配合,静配合,牢配合

tight financing policy ==> 紧缩性财政政策 | tight fit ==> 紧配合,静配合,静配合,牢配合 | tight fitting ==> 密封连接

shrink fit pressure：热套表面压力,热套配合压力

shrink fit ==> 收缩配合,冷缩装配,热套,热套配合,红套配合 | shrink fit pressure ==> 热套表面压力,热套配合压力 | shrink flange ==> 收缩法兰