- 更多网络例句与草酰胺相关的网络例句 [注:此内容来源于网络,仅供参考]
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Aim To study whether the derivative of in-dol-3-glyoxylic acid amide induced apoptosis on human galactophore cancer HeLa cells line in vitro and the feasible mechanisms of apoptosis.
目的 研究吲哚3-草酰胺衍生物YB-13在体外试验中诱导宫颈癌细胞株发生凋亡及其作用机制。
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Studies on Synthesis and Crystal Structure of N, N'-Bis(4-Hydroxy-3-Methoxybenzyl) Oxalamide
篇名 N,N'-双(4-羟基-3-甲氧基苯甲基)草酰胺的合成及晶体结构研究
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DFT Study on Heterobinuclear Cu-Co Complex of N,N'-bis (3-carboxyl Salicyl Aminal Ethylene) Oxalamide
篇名 N,N'-双(3-羧基水杨醛叉缩胺乙基)草酰胺Cu-Co异双核配合物的密度泛函研究
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The new oxalamide bridging ligands N, N'-bis (4-hydroxy-3-methoxy-benzyl) oxalamide (H4LB) was designed and synthesized.
设计合成一种新型对称的草酰胺桥联配体:N,N'-二(4-羟基-3-甲氧基苯甲基)草酰胺配体(H4LB)。
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The structure analysis indicates that the reverse symmetry ligand H4LB molecules are linked into a 2D supermolecular network by two types of hydrogen bonds. One type occurs between the oxalamide oxygen group and the phenol hydroxyl qroup of the nearest molecule with d=2.906(2) and ∠O-H…O=151.8°. The other type is between the oxalamide nitrogen group and the oxalamide oxygen group of anther molecule with d=2.849(2),∠N-H…O=158.7°.
晶体结构研究表明配体H4L为顺式桥联分子,晶体中存在两种氢键,一种是草酰胺基团的O原子与苯环上的酚羟基形成O-H…O氢键[d=2.906(2),∠O-H…O=151.8°];另一种是草酰胺基团的氨基与相邻草酰胺基上的O原子形成N-H…O氢键[d=2.849(2),∠N-H…O=158.7°],通过上述两种氢键将化合物H4LB连接成二维网络结构。
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Through condensing o-aminobenzoic acid, ethyl oxalyl chloride and ethylenediamine(or 1,2-propylenediamine), two new ligands N-benzoato-N′-(2- aminoethyl)oxamido(H3oxbe) and N-benzoato-N-(2-amino-2-methylethyl)oxamido(H3oxbt) have been synthesized. Their mononuclear complexes Na·1.5H2O and Na·1.5H2O have also been obtained.
2以邻氨基苯甲酸、草酸乙酯酰氯和乙二胺(或1,2-丙二胺)缩合制得了两种具有不对称草酰胺结构配体N-(2-苯甲酰基)-N&-(2-氨乙基)草酰胺(H3oxbe)和N-(2-苯甲酰基)-N&-(2-氨丙基)草酰胺(H3oxbt),并得到了它们的单核配合物:Na·1.5H2O和Na·1.5H2O。
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The effects of acidity and temperature on the fluorescent characteristics of N-N-bis-(O-Carboxylphenyl)-Oxamide have been studied in details.
本文首次研究了酸度、温度对对称草酰胺:N-N-二-邻羧基苯基草酰胺荧光特性的影响。
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For AP based propellants, oxamide (NH 2 CO 2 ) 2 is particularly effective in reducing burn rate, without sacrificing performance.
为鸭基于推进剂,草酰胺(信息NH 2的CO 2 ) 2 ,特别是有效地减少烧伤率,在不牺牲性能。
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Finally, the cytotoxic and antibacterial activities of the oxamido-bridged binuclear complexes were studied in vitro.. This dissertation consists of three sections as follows:1. The crystal structure of a oxamide dinitrate,(1) [H_4dmaeoxd](NO_3)_2 H_2dmaeoxd = N,N\'-bis[2-ethyloxamide, has been obtained. The diversity of complexes with different structures is carried out by successful synthetic strategy of controlling species of metal ions, counter anions, pH values and solvents in the course of synthesis. Four dinuclear complexes bridged by trans-dmaeoxd2-: [Cu_2_2](ClO_4)_2 (2), [Cu_2_2](ClO_4)_2 (3),、[Cu_2(Me_2phen)_2](ClO_4)_2 (4), [Cu_2_2(H_2O)_2] (5); Four dinuclear complexes bridged by cis-dmaeoxd2-: [NiNi_2](ClO_4)_2 (6), [CuNi_2](ClO_4)_2·2CH_3OH (7), [CuZn_2]-(ClO_4)_2·2H_2O (8), [Cu(H_2O)Ni_2](ClO_4)_2.0.5CH_3OH (9); three 1-D polynuclear complexes: [Cu_2]_n·nH_2O (10), [Cu_2(H_2O)_2-]_n·4nH_2O (11), [Cu_2(H_2O)]_n(NO_3)_n·2nH_2O (12); one 2-D polynuclear complex,[Cu_6_3(μ_3-OH)_2(H_2O)_2]_n(ClO_4)_(4n).2nH_2O (13); the others: [VO(H_2O)]·2H_2O (14), [Zn_2_4](ClO_4)_2·H_2O (15), [Cu_2]·2DCM (16) have been synthesized and characterized by X-ray single crystal diffraction, elemental analysis, IR spectra.
本论文主要包括以下三部分:一、合成得到了一个草酰胺配体硝酸盐的单晶结构,[H_4dmaeoxd](NO_3)_2 (1);通过调控金属离子的种类、端基配体、抗衡阴离子、溶剂、pH值等条件定向合成了四个反式草酰胺桥联双核铜配合物:[Cu_2_2](ClO_4)_2 (2)、[Cu_2_2](ClO_4)_2 (3)、、[Cu_2(Me_2phen)_2](ClO_4)_2 (4)、[Cu_2_2(H_2O)_2] (5);四个顺式草酰胺桥联同/异双核配合物:[NiNi_2](ClO_4)_2 (6)、[CuNi_2](ClO_4)_2·2CH_3OH (7)、[CuZn_2]-(ClO_4)_2·2H_2O (8)、[Cu(H_2O)Ni_2](ClO_4)_2.0.5CH_3OH (9);三个一维聚合物: [Cu_2]_n·nH_2O (10)、[Cu_2(H_2O)_2-]_n·4nH_2O (11)、[Cu_2(H_2O)]_n(NO_3)_n·2nH_2O (12);一个二维聚合物: [Cu_6_3(μ_3-OH)_2(H_2O)_2]_n(ClO_4)_(4n)。2nH_2O (13);单核钒配合物[VO(H_2O)]·2H_2O (14)、草酸根桥联双核锌配合物[Zn_2_4](ClO_4)_2·H_2O (15)、美洛西康铜配合物[Cu_2]·2DCM (16),利用元素分析、摩尔电导、红外光谱、电子光谱和单晶X-射线衍射对上述所得化合物进行了结构表征,探讨了结构影响因素,并研究了其超分子结构。
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Several novel structures have been determined: Unique ninenuclear complexesincorporating 3d, 4f metals with a sodium ion center, the sodium ion may be serve as atemplate in the formation of these novel complexes; Novel tetranuclear 〓complexes with channels formed by intermolecular weak interactions; First 〓type tetranuclear complex; Peculiar "dimer of dimers" complexes derived frombinuclear complex; Unusual one-dimensional wave chain formed by weakcoordination bonds and hydrogen bonds and two dimensional coordination polymerconstructed through coordination bonds and hydrogen bonds.
1获得了多个文献首报和罕见的特殊结构的配合物:两个同时含有碱金属-过渡-稀土金属的独特的九核配合物;两个具有孔道的稀土-过渡金属异四核配合物;草酰胺类〓四核配合物;两个由双核配合物通过叠氮和单个氯原子连成的四核配合物,尤其是以单个氯桥相连的化合物非常少见;一个由弱配键和氢键连成的具有一维波浪形结构的配合物;一个通过配位键和氢键连成的二维配位聚合物。
- 更多网络解释与草酰胺相关的网络解释 [注:此内容来源于网络,仅供参考]
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oxalic acid dianilide:乙二酰胺苯;草酰胺苯
乙二酸二烯丙酯;草酸二烯丙酯 oxalic acid diallyl ester | 乙二酰胺苯;草酰胺苯 oxalic acid dianilide | 乙二酸二异戊酯;草酸二异戊酯 oxalic acid diisoamyl ester
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oxalamide:草酰胺
oxalaldehyde 草醛 | oxalamide 草酰胺 | oxalate 草酸 草酸盐 草酸盐酯 乙二酸盐
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butyl oxamate:草酰胺酸丁酯;乙酰胺酸丁酯
丁基邻[草(之上)+叨]基醚;丁基邻甲苯基醚 butyl o-tolyl ether | 草酰胺酸丁酯;乙酰胺酸丁酯 butyl oxamate | 丁氧乙醇 butyl oxitol; butyl glycol
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ethyl oxamate:草酰胺酸乙酯
草乙酸[二]乙酯 ethyl oxalacetate | 草酰胺酸乙酯 ethyl oxamate | 乙醚;二乙基醚 ethyl oxide
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oxamic acid:草酰胺酸
草酰脲 oxalylurea; parabanic acid | 草酰胺酸 oxamic acid | 草酰胺酰肼;胺草酰肼 oxamic acid hydrazide; semioxamazide; oxamic hydrazide
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oxamic acid hydrazide; semioxamazide; oxamic hydrazide:草酰胺酰肼;胺草酰肼
草酰胺酸 oxamic acid | 草酰胺酰肼;胺草酰肼 oxamic acid hydrazide; semioxamazide; oxamic hydrazide | 草酰胺;乙二酰二胺 oxamide
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oxamide:草酰胺
oxamicacid 草氨酸 | oxamide 草酰胺 | oxanilide 草酰替苯胺
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oxamide:草酰胺;乙二酰二胺
草酸;草酸盐 oxalate | 草酰胺;乙二酰二胺 oxamide | 盐酸羟胺 oxammonium hydrochloride
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ethanediamide; oxamide:乙二酰胺;草酰胺
乙二醛;草醛 ethanedial; glyoxal | 乙二酰胺;草酰胺 ethanediamide; oxamide | 乙二腈;氰;二氰 ethanedinitrile; cyanogene; dicyanogene
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pentanamide; valeramide:戊酰胺;缬草酰胺
戊醛;缬草醛 pentanal; valeraldehyde | 戊酰胺;缬草酰胺 pentanamide; valeramide | 戊烷 pentane