- 更多网络例句与苯膦基相关的网络例句 [注：此内容来源于网络，仅供参考]
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To improve the cyano reactivity, cyano-terminated PPENs were prepared by the end-capping reaction of PPEN-OL with CBN; benzonitrile terminated polys were also prepared by the polycondensation of excess 4,4'-oxydianiline with 1,2-dihydro-2-(4-carboxyphenyl)-4-[4-(4-carboxyphenoxyl)phenyl]-phthalazinone, followed by end-capping with CBA. The polymers synthesized exhibited good solubility in NMP, DMAc and DMF, and were crosslinked to afford phenyl-s-triazine-containing polymers under the similar conditions.
为提高氰基活性，以对氯苯腈为原料，对PPEN-OL进行封端，设计合成了含氰端基的聚芳醚腈；以含二氮杂萘酮联苯结构二酸单体与4，4'-二氨基二苯醚为原料，经Yamazaki膦酰化缩聚，并用对氰基苯甲酸进行封端，合成了含氰端基的聚芳醚酰胺。
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Studies on the reactions of isomerized products of butaduene and isoprene iron complexes with triphenyl phosphine and triphenyl phosphite
丁二烯-和异戊二烯二羰基铁配合物的异构化产物与三苯膦和亚磷酸三苯酯的反应研究
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New ruthenium benzylidene complexes benzylidene[1,3-bis(2,6-dimethylphenyl)-4,5-dihydroimidazol-2-ylidene] [k~2-diphenylphosphinoacetato] monochlororuthenium (46), benzylidene[1,3-bis(2,6-dimethylphenyl)-4,5-dihydroimidazol-2-ylidene][k~2-3-propionato]monochlororuthenium (47), benzylidene[1,3-bis(2,6-dimethylphenyl)-4,5-dihydroimidazol-2-ylidene] [k~2-2-benzonato]monochlororuthenium (48) featured five-membered, flexible six-membered and rigidsix-membered chelating rings respectively are prepared by reactions of complex 41 withcorresponding sodium phosphino-carboxylates. It is confirmed by X-ray crystallographicanalysis that the coordination geometries of complexes 46 and 47 are distorted squarepyramids with phosphino-carboxylate ligands chelating to ruthenium, and the coordinationbetween ruthenium and benzylidene ligands are strengthened.
用二苯基瞵乙酸盐、二苯基膦丙酸盐、二苯基膦苯甲酸盐与钌卡宾配合物41反应合成了三个新的钌卡宾配合物：含五元膦-氧螯合环的1，3-二-(2，6-二甲苯基)-4，5-二氢咪唑基1-苯亚甲基--一氯合钌(46)、含六元柔性膦-氧螯合环的[1，3-二-(2，6-二甲苯基)-4，5-二氢咪唑基1-苯亚甲基--一氯合钌(47)及含六元刚性膦-氧螯合环的[1，3-二-(2，6-二甲苯基)-4，5-二氢咪唑基]-苯亚甲基--一氯合钌(48)。X射线单晶衍射分析证明，配合物46、47都为变形的四方锥构型，膦-氧与钌形成螯合配位，其中苯亚甲基与钌的配位得以加强。
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A series of sulfonated poly(arylene thioether/ether phosphine oxide)s was prepared by direct polycondensation of sBFPPO and BFPPO with the diphenol-type or dimercapto-type monomers such as hydroquinone, bisphenol-A, 4,4'-biphenol, 4,4'-diphenol (6F), 1,5-dihydroxynaphthalene, 4,4'-dihydroxybiphenyl, and 4,4'-thiobisbenzenethiol, respectively.
将BFPPO与sBFPPO分别与多种二羟基或二巯基单体，如对苯二酚、双酚A、4，4'-二苯酚、双酚F、1，5'-二羟基萘、4， 4'-二羟基二苯硫醚和4，4'-二巯基二苯硫醚，直接共聚制备了一系列磺化聚芳醚三苯基氧膦，侧重考察了二羟基和二巯基单体结构单元对产物的耐氧化性能的影响。
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Novel phosphazene cyclomatrix network polymers were synthesized via nucleophilic displacement of activated nitro groups of tri (4-nitrophenoxy)tri cyclotriphosphazene and hexa cyclotriphosphazene with the hydroxyls of bisphenol A.
以三对硝基苯氧基三苯氧基环三膦腈和六对硝基苯氧基环三膦腈为主要单体，采用活性硝基亲核取代的方法，合成了一类新的环簇膦腈聚合物。
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Novel phosphazene cyclomatrix network polymers were synthesized via nucleophilic displacement of activated nitro groups of tri (4-nitrophenoxy) tri cyclotriphosphazene and hexa (p-nitrophenoxy) cyclotriphosphazene with the hydroxyls of bisphenol A.
以三对硝基苯氧基三苯氧基环三膦腈和六对硝基苯氧基环三膦腈为主要单体，采用活性硝基亲核取代的方法，合成了一类新的环簇膦腈聚合物。
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First, the geometry optimization for 1-phenyldibenzophosphole and triphenylphosphine were carried out using quantum chemical AM1 method.
用量子化学AM1方法优化了1-苯基二苯并膦和三苯基膦的几何构型，比较了两种化合物的电子结构和空间结构，发现PDBP作为羰基合成铑膦催化剂的配体要优于三苯基膦；系统研究了PDBP的合成方法，其最佳合成条件为：在无水无氧的条件下，采用二乙胺锂与溴化四苯基膦摩尔比为3，反应温度为22 ℃，反应5 h，反应后酸化， pH值为1～2，产物收率可达到85％～88％。
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The reaction of isomerized butadieneiron complex (I; R = Ph, p-tolyl) with triphenylphosphine and tri-Ph phosphite gave products II (same R; R1 = Ph, OPh), at -60 to -30? When I was reacted with triphenylphosphine in hexane at 60 to 70?
丁二烯二羰基铁配合物的异构化产物，C4H62FeC(OC2H5)Ar(1，Ar=苯基， 2， Ar=对甲苯基)，在己烷溶液中于-60到-40℃与三苯膦或亚磷酸三苯酯反应生产产物3-6。
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In order to study the effect of PPh_2 group in the application of chiral ligands 4, 5, 7 and 8 to asymmetric reactions, two ferrocenyl amino alcohols 9a and 9b were Scheme 3 synthesized from chiral amino alcohol derived imines 3 (Scheme 3) and applied in the same asymmetric reactions.
为了探讨二苯氧膦基在配体参与不对称催化反应时对其催化活性和选择性的影响，合成了两个手性二茂铁基氨基醇配体9a和9b(Scheme 3)。
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In this dissertation, preparation of polysubstituted ethene and heterocyclic compounds based on 2-hydroxyalkyl phenyl selenides andα-phenylselenopropionic acid reagents were further investigated as follow: Firstly, O-ethyl-O-vinyl phosphonates were prepared in a one-pot, two-step transformation by Mitsunobu reaction of 2-hydroxyalkyl phenyl selenides with monoethyl esters of phosphonic acid in the presence of diethyl azodicarboxylate and triphenyl phosphine (PPh3) followed by oxidation-eliminatio...
中文摘要：本文主要进一步探索了2-羟基烷基苯基硒醚、α-苯硒基丙酸试剂在制备多取代乙烯和杂环化合物反应中的应用，具体研究内容和结果如下：一、在偶氮二羧酸乙酯和三苯膦(PPh3)存在下，苯基-2-羟基烷基硒醚和O-乙基膦酸单酯发生Mitsunobu反应，无需分离和纯化反应中间体，直接使用30 %的双氧水进行氧化-消除反应，提供了&两步、一锅&合成O-乙基-O-乙烯基膦酸酯的新方法，该方法反应条件温和，操作简便，产物收率良好(76-82 %)。
- 更多网络解释与苯膦基相关的网络解释 [注：此内容来源于网络，仅供参考]
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DOA：已二酸二辛酯
主营产品: 卡托辛 叔丁基二茂铁 亚铬酸铜 氧化膦 防老剂H 辛基二茂铁 正辛基二茂铁 三苯基铋 麝香105 10-羟基癸酸 10-溴代癸酸 二氯磷酸苯酯 昆虫性外激素 无定形元素硼 癸二酸二辛酯(DOS) 已二酸二辛酯(DOA) 三醋酸甘油酯 三
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phosphaturia：高磷酸盐尿
phosphaturia 磷酸盐尿 | phosphaturia 高磷酸盐尿 | phosphenyl 苯膦基
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phosphaturia：磷酸盐尿 高磷酸盐尿
phosphatoptosis 磷酸盐沉积 | phosphaturia 磷酸盐尿 高磷酸盐尿 | phosphenyl 苯膦基
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benzenoid hydrocarbons：苯型烃类
benzenephosphonic acid 苯膦酸 | benzenoid hydrocarbons 苯型烃类 | benzenyl fluoride 次苄基三氟
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phosphenyl：苯膦基
phosphaturia 磷酸盐尿 高磷酸盐尿 | phosphenyl 苯膦基 | phosphideeutectic 磷共晶
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acetyl phosphonate：乙酰膦酸盐、酯或根
acetylphenylsulfinic acid 乙酰苯基亚磺酸 | acetyl phosphonate 乙酰膦酸盐、酯或根 | acetylruthenocene 乙酰釕基链式并苯,乙酰釕基省
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diphenylhydantoin：二苯乙内酰脲 地仑丁 苯妥英
diphenylheptylphosphineoxideDPHPO 二苯基一庚基氧膦 | diphenylhydantoin 二苯乙内酰脲 地仑丁 苯妥英 | diphenylhydantoinsodium 苯妥英钠