脱醇

基本解释 (translations)

dealcoholization  ·  dealcoholize

与脱醇相关的网络例句 [注：此内容来源于网络，仅供参考]

New contributions of this work are as follows:(1). Preparation of Spherical MgCl_2-Supported Late-Transition Metal Catalysts for Ethylene PolymerizationFacile and effective immobilization of late-transition metal catalysts. 2,3-bis-(2,6-diisopropylphenyl) butane diimine nickel dibromide (1) and 2,6-bis-[1-(2,4,6-trimethylphenylimino)ethyl]pyridine iron dichloride (2), for ethylene polymerization has been achieved, using spherical MgCl_2 supports obtained by thermal dealcoholization of MgCl_2·2.56C_2H_5OH, and the effects of dealcoholization temperature on supported late-transition metal catalysts and the properties of resultant polymers were studied, the results indicated that:1.Supports with appropriate mechanical strength, high surface area and high porosity could be prepared by thermal dealcoholization of spherical MgCl_2·2.56C_2H_5OH supports; 2.BET, XRD, IR, SEM, GPC and DSC analyses indicate that the activities of the supported late-transition metal catalysts and the properties of resultant polymers are strongly dependent on the dealcoholization temperature.

本工作的新贡献如下：(1)、球形氯化镁负载后过渡金属催化荆催化乙烯聚合本文将配合物2，3-双(2，6-二异丙基苯亚胺)丁烷二溴化镍(1)和配合物2，6-二[1-(2，4，6-三甲基苯亚胺)乙基]吡啶二氯化铁(2)分别直接负载于经不同热脱醇温度处理的球形氯化镁载体上，研究了氯化镁载体的脱醇温度对负载化后过渡金属催化剂及其聚合物的影响，研究表明：1、通过对球形MgCl_2·2.56C_2H_5OH载体进行热脱醇处理，可以获得合适机械强度、较高比表面积和较高孔隙度的球形氯化镁载体；2、BET，XRD，IR，SEM，GPC和DSC研究表明，脱醇温度极大地影响负载后过渡金属催化剂的活性和聚合物的性能。

New contributions of this work are as follows:(1). Preparation of Spherical MgCl_2-Supported Late-Transition Metal Catalysts for Ethylene Polymerization Facile and effective immobilization of late-transition metal catalysts. 2,3-bis-(2,6-diisopropylphenyl) butane diimine nickel dibromide (1) and 2,6-bis-[1-(2,4,6-trimethylphenylimino)ethyl]pyridine iron dichloride (2), for ethylene polymerization has been achieved, using spherical MgCl_2 supports obtained by thermal dealcoholization of MgCl_2·2.56C_2H_5OH, and the effects of dealcoholization temperature on supported late-transition metal catalysts and the properties of resultant polymers were studied, the results indicated that: 1.Supports with appropriate mechanical strength, high surface area and high porosity could be prepared by thermal dealcoholization of spherical MgCl_2·2.56C_2H_5OH supports; 2.BET, XRD, IR, SEM, GPC and DSC analyses indicate that the activities of the supported late-transition metal catalysts and the properties of resultant polymers are strongly dependent on the dealcoholization temperature.

本工作的新贡献如下：(1)、球形氯化镁负载后过渡金属催化荆催化乙烯聚合本文将配合物2，3-双(2，6-二异丙基苯亚胺)丁烷二溴化镍(1)和配合物2，6-二[1-(2，4，6-三甲基苯亚胺)乙基]吡啶二氯化铁(2)分别直接负载于经不同热脱醇温度处理的球形氯化镁载体上，研究了氯化镁载体的脱醇温度对负载化后过渡金属催化剂及其聚合物的影响，研究表明： 1、通过对球形MgCl_2·2.56C_2H_5OH载体进行热脱醇处理，可以获得合适机械强度、较高比表面积和较高孔隙度的球形氯化镁载体； 2、BET，XRD，IR，SEM，GPC和DSC研究表明，脱醇温度极大地影响负载后过渡金属催化剂的活性和聚合物的性能。

The main sterol in the rice bran oil deodorizer distillate was stigmasterol, campesterol and sitosterol, but the total sterol content was only 0.32%. In addition, the deodorizer distillate contained a trace of germanical sterol, lanosterol, stigmastan-3, 5-diene etc.

通过对米糠油脱臭馏出物不皂化物的分析检测可知，米糠油脱臭馏出物中主要备醇的种类为豆苗醇、菜油苗醇、谷苗醇，总甾醇含量很少，仅为0.32%；除此之外，还有少量日耳曼苗醇、羊毛甾醇、3，5-二烯豆苗烷等。

Yields from chiral bisoxazolines (5a) with diethyl oxalate using NaOCH〓 as base for the first time. The structures of chiral multioxazolines and their intermediates, multi (β-hydroxylamide) s, were characterized by 〓H NMR, IR, mass spectra and elemental analysis. The catalytic activities and enantioselectivities of chiral multi (β-hydroxylamide) s (4) and chiral multioxazolines (5～8) were investigated by using acetophenone and β-acetonaphthone as former chiral ketone, KBH〓 or NaBH〓 as reductive reagent in chapter three.

在此基础上，对合成方法作了创新，以羧酸或酯为原料，在无催化剂的条件下与手性α-氨基醇反应，通过回流分水或脱醇的方法，一步反应合成了手性多噁唑啉（5～8），产率为89.2%～98.4%；以手性双噁唑啉（5a）为原料，在NaOCH〓的作用下，与草酸二乙酯反应，首次合成了呋喃类双嗯唑啉（6a），产率为72.9%～75.6%。

Experiments indicate that wine dealcoholization by pervaporation is greatly promising and has an excellent application perspective in wine industry.

因此新型PDMS平板复合膜进行渗透汽化脱醇制造低醇/无醇新酒品，具有广阔的工业应用前景。

Dealcoholization temperature markedly influences the surface area and porosity of the resultant MAO-supports. When the support was pretreated at lower or higher temperature, the corresponding MAO-support shows very low surface area;2.XRD and IR analyses indicate that MAO has reacted with the residual ethanol in the supports, which is an important manner to get MAO fixed on the carrier. Morever, XPS analyse indicates that MAO can also be coordinated with MgCl_2, which is another way to get MAO fixed on the support;3.ICP and EDX analyses indicate that dealcoholization temperature not only determined the element content on the solid catalyst, but also influences the element distribution on the carrier;4.The activities of the supported phenoxy-imine catalysts and the properties of resultant polymers are strongly dependent on the dealcoholization temperature. The support (MSP-5) obtained by treating MgCl_2·2.56C_2H_5OH at 160℃for 4 h, then modified by MAO is very effective for immobilizing complex 3, the resultant solid catalyst (MSPC-5) shows very high activity in ethylene polymerization, and its kinetics of polymerization is stable during the reaction process. Finally, PEs with spherical morphology and high bulk density (over 0.35g/ml) were obtained, without reactor fouling;5.In this work, polymerization conditions such as alkylaluminums, Al/Zr ratio, temperature and H_2 had a pronounced effect on the activity of MSPC-5 and properties of PE;(3). New MgCl_2-Supported Single-Site Catalysts for Ethylene PolymerizationIn this work, a kind of new MgCl_2 support was obtained by anhydrous MgCl_2 co-milled with solid MAO, and it is a creative contribution. Then some single-site catalysts were supported on the new MgCl_2 support, and the resulted solid catalysts were tested in ethylene polymerization, the results indicated that:1.XRD and IR analyses indicate that MAO does be coordinated with MgCl_2, which is in good agreement with the results obtained by XPS;2.co-mlling time had no obvious effect on the texture of support after 12 hours;3.In this work, MgCl_2 was co-milled with solid MAO for different hours, and then complex 3 was supported on these co-milled supports. It was found that co-milling time markedly influences the activity of solid catalysts, but it had negligible effect on the kinetic profile and the properties of resultant PE.

XPS研究结果表明，MAO不仅仅只和乙醇作用，MAO还与MgCl_2本身有一定的作用，这是一个极为重要的发现；3、通过ICP和EDX表征，发现载体的脱醇温度直接影响着元素在固体催化剂中的含量及分布；4、脱醇温度极大地影响着负载苯氧基亚胺类催化剂的活性和聚合物的性能，特别是原始载体经160℃活化4小时制备得到的固体催化剂MSPC-5的活性明显高于其他脱醇温度条件下制得的固体催化，并且催化剂寿命长，表现出稳定的动力学行为，最终获得了高堆密度(大于0.35g／ml)的球形聚乙烯颗粒；5、本文选择MSPC-5为研究对象，考察了聚合反应参数对催化剂的活性及其聚合物的影响，研究发现：不同的烷基铝对催化剂具有非常重要的影响，特别足TIBA对MSPC-5的助催化活性最高，烷基铝的加入量有一个较佳值，聚合温度为80度时活性最高，H_2的加入使催化剂的活性明显降低且聚合物的分子量也减小；、新型氯化镁载体负载单活性中心催化剂催化乙烯聚合本文创造性采用固体MAO与无水氯化镁直接进行共研磨，制备出了一种的新型的氯化镁载体，并将该载体用于多种单活性中心催化剂的负载化研究，研究表明：1、通过BET、XRD的表征，再次证实了MAO与MgCl_2之间具有直接作用，与XPS的研究结果相一致；2、当研磨时间高于12小时时，延长研磨时间对载体的结构没有显著的影响；3、将配合物3负载于共研磨时间不同的一系列载体上，乙烯聚合结果表明，尽管共研磨时间对负载催化剂的活性具有明显的影响，但是它对聚合物的性能以及催化剂的影响不明显。

Dealcoholization temperature markedly influences the surface area and porosity of the resultant MAO-supports. When the support was pretreated at lower or higher temperature, the corresponding MAO-support shows very low surface area; 2.XRD and IR analyses indicate that MAO has reacted with the residual ethanol in the supports, which is an important manner to get MAO fixed on the carrier. Morever, XPS analyse indicates that MAO can also be coordinated with MgCl_2, which is another way to get MAO fixed on the support; 3.ICP and EDX analyses indicate that dealcoholization temperature not only determined the element content on the solid catalyst, but also influences the element distribution on the carrier; 4.The activities of the supported phenoxy-imine catalysts and the properties of resultant polymers are strongly dependent on the dealcoholization temperature. The support (MSP-5) obtained by treating MgCl_2·2.56C_2H_5OH at 160℃for 4 h, then modified by MAO is very effective for immobilizing complex 3, the resultant solid catalyst (MSPC-5) shows very high activity in ethylene polymerization, and its kinetics of polymerization is stable during the reaction process. Finally, PEs with spherical morphology and high bulk density (over 0.35g/ml) were obtained, without reactor fouling; 5.In this work, polymerization conditions such as alkylaluminums, Al/Zr ratio, temperature and H_2 had a pronounced effect on the activity of MSPC-5 and properties of PE;(3). New MgCl_2-Supported Single-Site Catalysts for Ethylene Polymerization In this work, a kind of new MgCl_2 support was obtained by anhydrous MgCl_2 co-milled with solid MAO, and it is a creative contribution. Then some single-site catalysts were supported on the new MgCl_2 support, and the resulted solid catalysts were tested in ethylene polymerization, the results indicated that: 1.XRD and IR analyses indicate that MAO does be coordinated with MgCl_2, which is in good agreement with the results obtained by XPS; 2.co-mlling time had no obvious effect on the texture of support after 12 hours; 3.In this work, MgCl_2 was co-milled with solid MAO for different hours, and then complex 3 was supported on these co-milled supports. It was found that co-milling time markedly influences the activity of solid catalysts, but it had negligible effect on the kinetic profile and the properties of resultant PE.

XPS研究结果表明，MAO不仅仅只和乙醇作用，MAO还与MgCl_2本身有一定的作用，这是一个极为重要的发现； 3、通过ICP和EDX表征，发现载体的脱醇温度直接影响着元素在固体催化剂中的含量及分布； 4、脱醇温度极大地影响着负载苯氧基亚胺类催化剂的活性和聚合物的性能，特别是原始载体经160℃活化4小时制备得到的固体催化剂MSPC-5的活性明显高于其他脱醇温度条件下制得的固体催化，并且催化剂寿命长，表现出稳定的动力学行为，最终获得了高堆密度(大于0.35g／ml)的球形聚乙烯颗粒； 5、本文选择MSPC-5为研究对象，考察了聚合反应参数对催化剂的活性及其聚合物的影响，研究发现：不同的烷基铝对催化剂具有非常重要的影响，特别足TIBA对MSPC-5的助催化活性最高，烷基铝的加入量有一个较佳值，聚合温度为80度时活性最高，H_2的加入使催化剂的活性明显降低且聚合物的分子量也减小；、新型氯化镁载体负载单活性中心催化剂催化乙烯聚合本文创造性采用固体MAO与无水氯化镁直接进行共研磨，制备出了一种的新型的氯化镁载体，并将该载体用于多种单活性中心催化剂的负载化研究，研究表明： 1、通过BET、XRD的表征，再次证实了MAO与MgCl_2之间具有直接作用，与XPS的研究结果相一致； 2、当研磨时间高于12小时时，延长研磨时间对载体的结构没有显著的影响； 3、将配合物3负载于共研磨时间不同的一系列载体上，乙烯聚合结果表明，尽管共研磨时间对负载催化剂的活性具有明显的影响，但是它对聚合物的性能以及催化剂的影响不明显。

The result shows:In presence of N 2 and in vacuum the new alkanolamides 1∶1 5 type are prepared in high yield by diethanolamine with fatty acid methyester,which is made by reacting methanol with rice bran oil or cotton seed oil.

研究表明，用棉油或米糠油和甲醇反应制得脂肪酸甲酯，然后在氮气保护真空条件下，使脂肪酸甲酯和二乙醇胺脱醇缩合，可高产地制得高活性1∶15型的新型烷醇酰胺。

Synthesis of dodecyl polyglucoside by means of exchange method was studied.

摘 要：采用交换法合成十二烷基葡萄糖苷，考察了催化剂、醇糖比、反应时间、反应温度及脱醇工艺等对反应结果的影响。

The synthetic process for a new plasticizer used in low temperature, dibutyl nylonic acid ester, was introduced.

介绍了一种新型耐寒增塑剂尼龙酸二正丁酯的合成工艺，用价廉、易得的尼龙酸(由制己二酸母液中获得的C4～C6混合二元酸)及正丁醇为原料，浓硫酸为催化剂，经酯化、脱醇、中和、沉降及减压蒸馏等工序而制得产品。

与脱醇相关的网络解释 [注：此内容来源于网络，仅供参考]

acetaldehyde reductase：醇脱氢酶

acetaldehyde ammonia 乙醛合氨 | acetaldehyde reductase 醇脱氢酶 | acetaldoxime 乙醛肟

alcoholic fermentation：生醇发酵

alcohol dehydrogenase醇脱氢酶;乙醇脱氢酶 | alcoholic fermentation生醇发酵 | aldehyde醛;乙醛

cyclohexanol dehydrogenation：环己醇脱氢

cyclohexanedione 烯巳二酮 | cyclohexanol dehydrogenation 环己醇脱氢 | cyclohexanol 环己醇

gossypol：棉子醇

去甲二氢愈创木酸(NDGA)、棉子醇(gossypol)和芬宁东(phenidone)对脱甲基反应的强烈抑制作用提示,SLO起催化作用. 还原型谷胱甘肽(GSH)或二硫苏糖醇参与反应时,甲醛的累积量明显降低,表明SLO对灭害威脱甲基作用时,产生自由基.

sorbitol dehydrogenase：山梨醇脱氢酶

3B265 丙酮酸激酶 pyruvate kinase | 3B270 山梨醇脱氢酶 sorbitol dehydrogenase | 3B275 苹果酸盐脱氢酶 malate dehydrogenase

back sweetening：加硫醇后以试硫液脱残余游离硫法

back support | 后撑 | back sweetening | 加硫醇后以试硫液脱残余游离硫法 | back talk | 回嘴, 顶嘴(尤指对上级或长辈的顶撞),反唇相讥

BUTOXY CHITOSAN：丁氧基脱乙酰壳多糖

BUTETH-3 CARBOXYLIC ACID丁醇聚醚-3 羧酸 | BUTOXY CHITOSAN丁氧基脱乙酰壳多糖 | BUTOXYDIGLYCOL丁氧基双甘醇

dealcoholization：脱醇(作用)

dealbation 漂白 | dealcoholization 脱醇作用 | deamidase (脱)酰胺酶

Glycol Decolorization：甘油醇脱色

2.7 Amine Purification 胺类的提纯 | 2.9 Glycol Decolorization 甘油醇脱色 | 2.10 Solvent Recovery 溶剂回收

malic dehydrogenase：苹果酸脱氢酶

丙二酸是琥珀酸的类似物,是琥珀酸脱氢酶强有力的竞争性抑制物,所以可以阻断三羧酸循环. 在苹果酸脱氢酶(malic dehydrogenase)作用下,苹果酸仲醇基脱氢氧化成羰基,生成草酰乙酸(oxalocetate),nad+是脱氢酶的辅酶,接受氢成为nadh.h+