- 更多网络例句与联本基相关的网络例句 [注:此内容来源于网络,仅供参考]
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The present invention relates to a process for rapid solution synthesis of a peptide, the process comprising repetitive cycles of steps-: a coupling step, using an excess of an activated carboxylic component to acylate an amino component, a quenching step in which a scavenger is used to remove residual activated carboxylic functions, wherein the scavenger may also be used for deprotection of the growing peptide, one or more aqueous extractions and optionally, a separate deprotection step, followed by one or more aqueous extractions, characterised in that the process comprises at least one step, referred to as step, in which an amine or a thiol comprising a free anion or a latent anion is used as a scavenger of residual activated carboxylic functions.
本发明涉及快速溶液合成肽的方法,该方法包括步骤-的重复循环:偶联步骤,使用过量的活化羧基成分酰化氨基成分,淬灭步骤,在该步骤中使用清除剂除去残余的活化羧基官能团,其中该清除剂还可以用于使生长中的肽去保护,一或多个水抽提和任选地,独立的去保护步骤,之后进行一或多次水抽提,其特征在于该方法包括至少一个步骤,称作步骤,在该步骤中包含自由阴离子或潜阴离子的胺或硫醇用作残余活化羧基官能团的清除剂。
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In this research, we used a sol-gel process to prepare UV-curable antiglare coatings. First the inorganic monomer tetraethoxylsilane was formed into colloidal silica by hydrolysis and condensation reactions. Then, added the couple agent 3- propyl methacrylate and surfactant fluoroalkylsilane (13F) to modify the colloidal silica. Finally, organic monomer dipentaerythritol hexaacrylate were added to form hybrid material.
中文摘要本研究是经由溶胶凝胶制程,将无机单体四乙氧基矽烷先行水解、缩合反应成为二氧化矽,接著分别加入偶合剂三异丙基矽基丙烯酸酯、氟化矽氧烷(13F)、对二氧化矽微粒进行表面改质;之后再导入交联剂DPHA加以强化合成出奈米混成涂料。
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Keane had already cast doubt over his long-term future at United earlier this season when, in a live phone-in, he said he believed that his current contract, which was due to expire at the end of this season, would be his last.
在赛季初期基恩就已经澄清了他在曼联长期效力后的未来,在一个电话采访中他说他相信他眼下这份在本赛季结束后到期的合同将是他与曼联的最后一份合同。
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The specific properties of materials, such as the palate adhesion, dynamic cruor, anti-bacterial and the degradability of lysozyme, were studied, which provide valuable data for further application. The main creative ideas are listed as follows:(1) The water-retention chitosan/poly vinyl alcohol blend fiber was obtained by coagulating in 10% NaOH/ethanol solution, and the blend and crosslink due to GA can enhance the mechanical properties of fiber;(2) The controlled degradable chitosan/gelatin blend fiber was obtained by solution filature, and the mechanical properties were improved;(3) The N-acylchitosan with the different degree of substitution were successfully prepared, and the relationship between structure and properties was estabilished;(4) By a new solvent system of 6% NaOH/4% urea for cellulose, the blood anti-coagulant function films were prepared by blending cellulose with chitin;(5) In the same solvent system above mentioned, the anti-bacterial blend films based on cellulose and carboxymethyl-chitosan were prepared, and the relationship of DS and the anti-bacterial property was concluded;(6) The controlled degradable chitosan films was obtained by the chemical crosslink.
本论文的主要创新点:(1)以NaOH水溶液/无水乙醇为凝固液,采用溶液纺丝法制备出保水性壳聚糖/聚乙烯醇纤维,共混和戊二醛交联极大提高了壳聚糖纤维力学性能;(2)用壳聚糖和明胶共混,以溶液纺丝法制备出可控降解的壳聚糖/明胶纤维,并大幅度提高了壳聚糖共混纤维的干、湿态抗张强度;(3)确立了不同取代度N-酰基壳聚糖的合成方法及其膜的结构与性能的关系;(4)利用纤维素新溶剂6%NaOH/4%尿素制备出抗凝血性纤维素/甲壳素共混膜;(5)利用上述纤维素新溶剂制备出抗菌性纤维素/羧甲基壳聚糖共混膜,揭示了羧甲基壳聚糖取代度与抗菌性能的关系;(6)制备出可控降解壳聚糖交联膜。
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Three kinds of optically active pnthalocyanine derivatives modified with chiral 2'-methyoxy-1,1'-binaphthyl; chiral binathyl crown ether; chiral 6,6'-didodecyl- 1,1'-binaphthyl crown ether, have been synthesized and characterized, respectively.
本论文以手性联萘、手性联萘冠醚、冠醚等功能性基团为化学修饰基元,分别合成了三类光学活性酞菁衍生物和两类共轭聚合物,对它们的组装行为以及某些光、电功能性进行了研究。
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In this paper, according to principles of molecular design, Cu,Ag, Cu,Fe, Ni, Mn, and Co were selected as templates, 8,8'-Dithiodiquinoline,4-cyanopyridine,2,2'-Bipyridyl-3,3'-dicarboxylic acid, 4,4'-bipyridine as building blocks.
本课题通过分子设计,以Cu,Cu,Mn,Co,Ni,Fe,Ag为模板,以8,8'-二硫联喹啉,4-氰基吡啶,4,4'-联吡啶和2,2'-联吡啶-3,3'-二羧酸为构件,用溶剂热法合成新的配位聚合物,测定其晶体结构,并研究其导电性和热行为。
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The first part is to synthesize 5-formyl -8- quinolinol from 8-uinolinol and chloroform , using ethanol as a solvent. Then analysizing the 5-formyl-8-quinolinol by IR. The second part is , according to ideas of molecule designing, to synthesize the new self-assembly Inorganic-Organic coordination polymers Co(u2-bpyV2O6,(C4H4N2)Ni2(H2O)2-V4Ol2,(Cl2Hl2N2)Co-V2O6 using Cu, Ni, and Co as templating, 4-cyano-pyridine(4-CNPy), 4,4-bipyridine,pyrazine, l,2-bis(4-pyridyl)ethane, 5-formyl -8- quinolinol as building blocks and Ammonium Metavanadate (NH4VO3) as subordinate building blocks by Hydrothermal , analysizing their content of element determining their structures by X-Ray diffraction.
本课题实验分为两部分:一是配体的合成,以8-羟基喹啉、三氯甲烷为原料,以乙醇为溶剂,合成了5—甲醛基—8羟基喹啉并且对其进行了IR的分析测定;二是配位聚合物的合成,通过分子设计,采用溶剂热法以Cu、Ni、Co为中心离子,以5—甲醛基—8羟基喹啉、4,4-联吡啶、吡嗪、1,2-二吡啶基乙烷为配体,以偏钒酸根(VO_3~-)为辅助配体,通过水热法自组装合成了新的3-D网状结构配位聚合物Co(μ_2-bpy)V_2O_6,(C_4H_4N_2)Ni_2(H_2O)_2·V_4O_(12),C_(12H_(12)N_2Co·V_2O_6,并对其进行了元素分析和晶体结构的测定。
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The Suzuki reaction, the coupling of organoborate compounds with organic electrophiles catalyzed by Palladium complexes, is a valuable Csp2-Csp bond forming reaction. The reaction has been drawing increased attention in that the reaction permit the use of organoboron compounds that are thermally stable and inert to water and oxygen.In this section microwave promoted Suzuki reaction of phenylboronic acid with benzyl halides catalyzed by Pd(PPh3)2Cl2 DMF/H2O(v/v=10 : 2) was first reported.
第四章:微波辐射下Pd配合物催化端烯与芳卤偶联反应研究本章中我们在微波辐射条件下,研究了PdclZ(P Ph3):催化端烯与芳卤的偶联反应,合成出了七种乙烯基化合物;并分别考察了微波辐射功率、辐射时间、原料配比、和PTc等因素对反应的影响,优选出了较佳的反应条件,并根据文献及实验结果,讨论了可能的反应机理。
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This PhD thesis mainly summarizes the original results on studies of aromatic amide-derived phosphines,including the precatalyst system consisting of Aphos and Pd_2 and the applications for promoting room temperature Suzuki cross-coupling of aryl chlorides and aryl/vinyl bromides,respectively,with aryl/vinyl boronic acids,and alkyl boranes.
本博士学位论文主要总结了对芳基酰胺衍生的膦配体的研究,以及该类型配体与Pd_2组成的催化剂在室温下催化氯代芳烃、溴代芳烃、溴代烯烃分别同芳基硼酸、烯基硼酸及烷基硼试剂进行的Suzuki偶联反应中的表现。
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The recent research progress of oxidation carbonylation of amines/β-amino alcohols, alkoxycarbonylation of epoxides, carbonylative Suzuki coupling, carbonylative Sonogashira, and double carbonylation of aryl iodides has been presented, focusing on the carbonylation reactions studied by us in the past few years, with 81 references.
综述了胺/氨基醇类化合物氧化羰化、环氧化合物氢酯基化、碘代芳烃的羰化Suzuki偶联、羰化Sonogashira以及双羰基化等重要羰基化反应的研究状况,特别是结合本课题组近年来在该领域中的工作,并对羰基化反应的发展及应用前景进行了展望。
- 更多网络解释与联本基相关的网络解释 [注:此内容来源于网络,仅供参考]
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diploe moment:偶极子矩
diphenylene naphthalene 联二亚本基奈 | diploe moment 偶极子矩 | dipmeter 倾斜测量仪
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hessian:黄麻布
[摘要]一、产品简介1.PVC蓬布涂塑高强涤纶防水布是以高强度的涤纶帆布为基布,涂敷聚氯乙烯(PVC)糊状树脂配加增速 剂、防霉剂、防老化剂、抗静电剂等多种化学助剂,经...[摘要]本公司经营黄麻布,质量保证,欢迎咨询洽谈. 黄麻布 (HESSIAN) 发布单位:南宁市联信印刷物资有限责任公司 公司地址:南宁市东葛路73号2单元603号 纸张
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hydrazine:联胺
预期有相同的特性.所 以本计画拟采间接方法,先合成马来酸酐-苯乙烯 共聚合物(Maleic Anhydride-Styrene Copolymer; MAn-St)作为母体,再与联胺(Hydrazine)反应,转换成环醯□基( Cyclic HydrazideGroup)之马来醯□-苯乙烯共聚合物( MHz-St),
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hydrogel:水性凝胶
水性凝胶基质大多在水中溶胀成水性凝胶(hydrogel)而不溶解. 本类基质一般易涂展和洗除,无油腻感,能吸收组织渗出液不妨碍皮肤正常功能. 还由于粘滞度较小而利于药物,特别是水溶性药物的释放. 1.卡波沫(carbomer) 系丙烯酸与丙烯基蔗糖交联的高分子聚合物,
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Vinyl chloroacetate:氯乙酸乙烯酯
氯乙酸乙烯酯(Vinyl chloroacetate) 制造对酸性染料有良好亲和力的甲基丙烯酸纤维的原料;生产高耐热水性薄膜的原料;用作丙烯酸酯、乙烯等高分子弹性体的交联单体;本品与具有羟基或羧基的单体及甲基丙烯酸酯进行乳液聚合,可制得碱性交联乳液;
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diphenylene naphthalene:联二亚本基奈
diphase 双相,二相 | diphenylene naphthalene 联二亚本基奈 | diploe moment 偶极子矩
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divinyl benzene:二乙烯基苯
二乙烯基苯(divinyl benzene)分子式:C10H10 ;分子量:130; CAS:1321-74-0含量:55-80;二乙苯:≤5-≤3;乙烯基乙苯:≤40 本品是重要的交联剂,作用离子交换树脂,聚酯树脂和聚合单组分.