- 更多网络例句与联吡啶相关的网络例句 [注:此内容来源于网络,仅供参考]
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In complex 1,Cucan be described as a four-coordinated square planar geometry.Compound 8 is the sodium salt of plumbagin and exists as ionic compound.Compounds 9-16 are the rare earth complexes of plumbagin with La,Y,Dy,Sm,Gd,Nd,Erand Eu.Compound 17 is binuclear Y complex.18 is mononuclear Ycomplex with plumbagin and another ligand from Plumbago Zeylanica.Compounds 19-21 are the ternary complexes with plumbagin and 2,2\'-bpy and phen as assistant ligand.In 19, the geometry of Cucan be described as five-coordinated distorted square pyramid that exists in a dimer through the weak bonding,and 1-D chain structure is formed by intermolecular hydrogen bonds.
化合物1的单晶结构分析表明1具有四配位平面四边形结构,化合物8是白花丹素的Na盐,以离子化合物形式存在;化合物9~16为白花丹素的La,Y,Dy,Sm,Gd,Nd,Er,Eu的稀土金属配合物;化合物17是白花丹素的双核钇结构;化合物18为白花丹素的单核钇结构,该配合物除了含白花丹素外,还有来自白花丹植物中的另一个单体化合物也参与配位;化合物19~21是以2,2\'-联吡啶和邻菲咯啉等含N配体为辅助配体,具有白花丹素—含N配体—金属离子的三元配合物,化合物19是白花丹素和2,2\'-联吡啶与Cu的配合物,具有五配位的四方锥构型,通过Cu…O弱的成键作用形成二聚体,再通过分子间的氢键作用进一步形成一维链状结构,化合物20和化合物21是白花丹素分别与2,2\'-联吡啶和邻菲咯啉的Zn配合物,都具有六配位八面体构型的双核锌配合物,呈一维链状结构,化合物20中链与链之间的大量氢键将一维链扩展成二维层,分子间的π-π堆积作用进一步形成三维结构。
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The influences of different organic bridging ligands pyrazine,2-pyrazinecarboxylate,4,4′-bipyridine and 1,2-bis(4-pyridyl)ethane on the cobalt vanadate system were explored.
同时还研究了不同的有机桥式配体吡嗪、2-吡嗪羧酸、4,4′-联吡啶和1,2-联(4-吡啶基)乙烷在钴钒体系中的作用。
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Four non-ionic europium complexes,〓-phen(11),〓·bipy(12),〓·dia(13) and 〓(14)(TTA=2-thenoyltrifluoroacetone, DBM=dibenzoylmethane, phen=phenanthroline, bipy=2,2'-bipyridine, dia=4,5- diazafluoren-9-one, dmbp=4,4'-dimethyl-2,2,-bipyridine), were synthesised and the triboluminescent phenomena of 12, 13 and 14 were firstly observed. Structure determinations of 11,12 and 14 were carried out. The triboluminescence maxima of 12 and 13 are similar to those of their photoluminescence. X-Ray structure analyses show that Eu atoms all exhibit eight-coordinate tetragonal antiprismatic geometries and complexes 11, 12 and 14 are all centrosymmetric.
二、合成了四个非离子型的铕的配合物:〓、〓、和〓(14)[HTTA=2-噻吩三氟甲酰丙酮,DBM=二苯甲酰基甲烷,phen=邻菲罗啉, bipy=2,2'-联吡啶,dia=4,5-二氮杂芴-9-酮,dmbp=4,4'-二甲基-2,2'-联吡啶],首次报道了12、13及14的摩擦发光性质,测定了11、12及14的晶体结构,并系统地讨论了晶体结构和摩擦发光活性之间的关系。12及13的摩擦发光光谱的极大值均类似与其相应的光致发光光谱,表明它们有相同的激发态。
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The adsorption behavior of probing molecule of pyridine and bipyridine at Zn electrode has been studied utilizing the SERS technique.
两种联吡啶分子和锌的作用都比吡啶强,2,2'-联吡啶在锌表面存在由电位变化引起的两种表面吸附物种构型的转换。
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In the procedures of syntheses, we chose 2,2"-bipyridine (2,2"-bipy), 4,4"-bipyridine (4,4"-bipy), 1,10-phenanthroline (1,10-phen) and 8—hydroxyquinoline as neutral ligands, and lead, copper, zinc, cadmium and manganese as metal ions in our research.
使用的中性配体为2,2′-联吡啶(2,2′-bipy)、4,4′-联吡啶(4,4′-bipy)、1,10-邻菲罗啉(1,10-phen)和8—羟基喹啉,研究的金属离子为主族金属Pb以及过渡金属Cu、Zn、Cd和Mn。
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In this paper, according to principles of molecular design, Cu,Ag, Cu,Fe, Ni, Mn, and Co were selected as templates, 8,8'-Dithiodiquinoline,4-cyanopyridine,2,2'-Bipyridyl-3,3'-dicarboxylic acid, 4,4'-bipyridine as building blocks.
本课题通过分子设计,以Cu,Cu,Mn,Co,Ni,Fe,Ag为模板,以8,8'-二硫联喹啉,4-氰基吡啶,4,4'-联吡啶和2,2'-联吡啶-3,3'-二羧酸为构件,用溶剂热法合成新的配位聚合物,测定其晶体结构,并研究其导电性和热行为。
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First,the interaction between bipyridyl and In was investigated by the methods of electrochemistry,UV spectra and difference UV spectra.Then the interaction between In and DNA was investigated by the methods of electrochemistry.At last the electrochemistry behavior of interaction between In complex and DNA was studied.
本文选用联吡啶为配体,首先研究了In与联吡啶相互作用的电化学及紫外光谱性质,又对In与DNA的相互作用进行了初步研究,最后进一步研究了联吡啶In配合物与DNA作用的电化学行为。
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In order to solve the backward electron transfer problem, 9 kinds of rhenium bipyridyl photosensitive dyes with different electron donating groups on the p or m-position of the pyridine rings, 2 kinds of rhenium bipyridyl and 2 kinds of ruthenium tris-bipyridyl photosensitive dyes with two tyrosine ethyl ester groups on the bipyridyl rings were designed and synthesized.
本文针对该类太阳能电池中存在的电子回传问题,设计合成了在吡啶配体的间位和对位带有不同供电基团的9种铼联吡啶光敏染料,在联吡啶配体上带有两个酪氨酸基团的2种铼联吡啶和2种钌三联吡啶光敏染料。
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This is the first example of two-dimensional lanthanide MOFs with one dimensional water chains.2、Coordination polymer[Nd_2_3(H_2O)_2]·bpy·4H_2O(2)(bpdc=2, 2′-bipyridine-3,3′-dicarboxylate,bpy=4,4′-bipyridine)had been synthesized under hydrothermal conditions and its structures were determined by X-ray diffraction,and confirmed by IR and TG analysis.
该结构是在二维骨架的镧系配位聚合物中首次观察到的一维的水链结构。2、以Nd_2O_3,2,2′-联吡啶-3,3′-二羧酸和4,4′-联吡啶为原料,采用水热法合成了一个具有二维骨架结构的配位聚合物[Nd_2_3(H_2O)_2]bpy·4H_2O,通过IR、x射线单晶衍射分析和热重等手段对其结构进行了表征。
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The dosages of additives were determined as 5 mg/L K4Fe6, 5 mg/L2, 2'-dipyridyl, 10 mg/L L-arginine, and 5 mg/L 2,2'-dipyridyl +10 mg/L L-arginine.
添加剂最佳使用量分别为:5 mg/L亚铁氰化钾;5 mg/L2,2'-联吡啶;10 mg/L L-精氨酸以及二元复合添加剂5 mg/L2, 2'-联吡啶+10 mg/LL-精氨酸。
- 更多网络解释与联吡啶相关的网络解释 [注:此内容来源于网络,仅供参考]
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biphenyl:联二苯
biotite 黑云母 | biphenyl 联二苯 | bipyridyl 联吡啶
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direct factor:直接因素
dipyridyl 联吡啶 | direct factor 直接因素 | direct rope haulage 头绳运输
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pyridine:吡啶
二乙基亚硝胺(diethylnitrosamine)联氨(hydrazine),乙烯氯化物(vinylcholoride),有促癌作用的如甲醛,有致癌作用者如氰化物,丙烯醛(acrolein),乙醛,还有其他有害物质,如氮氧化物(95%为氧化亚氮,N0),吡啶(pyridine)和一氧化碳(CO)等,
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Binuclear Ruthenium complex:双核钉联吡啶络合物
包合物:Inclusion complexes | 双核钉联吡啶络合物:Binuclear Ruthenium complex | 双核酞(?)钴磺酸盐:binuclear cobalt phthalocyanine sulfonate
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Bipyridine:(二一)联吡啶
(二十)苯甲氯 Benzyl chloride | (二一)联吡啶 Bipyridine | (二二)溴 Bromine
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Bipyridine:联吡啶
苯甲氯 Benzyl chloride | 联吡啶 Bipyridine | 溴 Bromine
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2"-bipyridine derivatives:2"-联吡啶衍生物
8-羟基喹啉衍生物:8-hydroxylquinoline derivatives | 2"-联吡啶衍生物:2"-bipyridine derivatives | 苯氧基衍生物:derivatives containing phenoxy group
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bipyridyl:联吡啶
bipropellant 双组元推进剂 | bipyridyl 联吡啶 | biquinolyl 联喹啉
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dipyridyl:联吡啶
dipyre 针柱石 | dipyridyl 联吡啶 | direct factor 直接因素
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bridging ligands:桥联配体
双吡啶配体:bispyridine ligands | 桥联配体:bridging ligands | 固体配体:immobilized ligands