- 更多网络例句与羟基相关的网络例句 [注:此内容来源于网络,仅供参考]
-
Because the olefinic hydroxyl groups are linked with olefinic carbon, so it can ionize H〓 ion and present the properties of weak acid, and so the olefinic hydroxyl groups change into the structure of alcoholate in the presence of alkali , but the structure of alcoholate may change into the structure of olefine alcohol again, after the Na〓 ions is removed, or when the pH value of its solution turn into pH. Because the structure of the olefine alcohol is not stable and is easy to isomerizate to become the structure of olefine ketone, so there appear the ca. 1730cm〓 C=O absorption peak in the IR spectra of the products.
明确指出了在C〓、C〓富勒醇中存在烯碳羟基与叔碳羟基等二类羟基,烯碳羟基由于与一个共轭体系相连,从而其羟基可以离解而呈现出弱酸的性质,因而在碱性条件下易形成烯醇钠盐的结构,当除去钠离子后或在酸性溶液中,烯醇钠盐结构转变为烯醇结构,但由于烯醇结构不如烯酮结构稳定,从而形成烯醇结构后,烯醇结构异构化为烯酮结构,因此在其产物的IR谱图上出现1730cm〓附近的C=0吸收信号。
-
Ophenyl phenol,ophenyl phenol sodium salt tetrahydrate,7ADCA,2ethyl phenyl hydrazine hydrochloride,2,3dihydrofuran,7ethyl3(2hydroxy ethyl)indole,methyl ester of etodolac; 1,8diethyl1,3,4,9tetrahydropyrano[3.4b] indole1acetic acid methyl ester,5chloro2methoxy benzoic acid,4(2aminoethyl)benzene sulfonamide,5cyano phthalide,phthalhydrazide,9thioxanthenone,n[(1,4benzodioxane2yl)carboxyl]piperazine HCL,2chloro4amino6,7dimethoxyquinazoline,2chloro benzimidazole,1(4fluorobenzyl)2chlorobenzimidazole,2methylthio4pyrimidone,5amino4imidazole carboxamide HCL,6chloro2hexanone,11oxo6.11hydrodibenzothiepin,6,11dihydrodibenzooxepin11one,10,11dihydrodibenzocyclohepten5one;dibenzosuberone,dibenzo cyclohepten5one;dibenzosuberenone,3,5dihydroxy benzoic acid,3,5dihydroxy benzyl alcohol,2mercapto benzimidazole,3,4dihydroxy benzaldehyde,3,4dihydroxy benzonitrile,2amino5chloro benzonitrile,2(4chlorophenoxy)ethyl chloride,2(4chloro phenoxy)tert,butane,ditrimethylol propane;DTMP,2,2bis(4hydroxyphenyl)butane; bisphenol B,1,1'bis(4hydroxyphenyl)cyclohexane;bisphenol Z,tetrabromobisphenolS,3,5ditertbutyl salicylic acid,3,4,5trihydroxy benzoic acid stearyl ester,1,2,4trimethoxybenzene.
华业公司产品:邻苯基苯酚,邻苯基苯酚钠盐,7氨基3去乙酰氧基头孢烷酸,邻乙基苯肼盐酸盐,2,3二氢呋喃,7乙基色氨醇,依托度酸甲酯,5氯2甲氧基苯甲酸,4(2氨乙基)苯磺酰胺,5氰基苯酞,双酮酞嗪,9噻吨酮,N〔(1,4苯并二恶烷2基)羰基〕哌嗪盐酸盐,2氯4氨基6,7一二甲氧基喹唑啉,2氯苯并咪唑,1(4氟苄基)2氯苯并咪唑,2甲硫基4嘧啶酮,5氨基咪唑4 甲酰胺盐酸盐,6氯2已酮,11氧6.11二氢苯并〔b.c〕虑平,11氧代6,11二氢二苯并氧杂卓,10,11二氢二苯并环庚烯5酮,二苯并环庚烯5酮,3,5二羟基苯甲酸,3,5二羟基苯甲醇,2巯基苯并咪唑,3,4二羟基苯甲醛,3,4二羟基苯腈,2氨基5氯苯腈,2(4氯苯氧基)1氯乙烷,2(4氯苯氧基)叔丁烷,双丙烷,2,2二(4羟基苯基)丁烷;双酚B,1,1'双(4羟基苯基)环己烷;双酚Z,2[3,5二溴4(2,3二溴丙氧基)]苯砜,3,5二叔丁基水杨酸,3,4,5三羟基苯甲酸十八烷基脂,1,2,4三甲基氧基苯。
-
In order to research the relations of carbon sources to structure of PHAs, six kinds of PHAs sample were synthesized by activated sludge with six different carbon sources respectively in the aerobic-anaerobic-anoxic process. Their structures were determined by 〓HNMR、〓CNMR and GC-MS. When the carbon source was acetate, the unit composition of PHAs was 93. 91mol% 3-hydroxybutanoic acid and 6. 09mol% 3-hydroxypentanoic acid ; When the carbon source was propionate, the unit composition of PHAs was 28. 66mol% HB, 63. 13mol%HV, 2. 55mol% 2-methy-3-hydroxy-butanoic acid (2MHB) and 5. 66mol% 2-methyl-3-hydroxypentanoic acid (2MHV); When the carbon source was 80% butyrate and 20% 1, 4-butanediol, the unit composition of PHAs was 65. 03mol% HB, 28. 06mol%HV, 1. 91mol%2MHB, 2. 69mol% 2MHV, 0.73mol% 4-hydroxy butanoic acid (4HB), 0.78mol% 4-methyl-3-hydroxy-pentanoic acid (4MHV), 0.80mol% 3-hydroxyhexanoic acid ; When the carbon source was 20% butyrate and 80% 1, 4-butanediol, the unit composition of PHAs was 61. 39mol% HB, 23. 01mol%HV, 4. 58mol%2MHB, 5. 97mol% 2MHV, 0.91mol% 4HB, 2. 37mol% 4MHV, 1. 77mol% HHx; When the carbon source was 60% pentanoate and 40%glucose, the unit composition of PHAs was 41. 24mol% HB, 58. 76mol%HV; When the carbon source was 60% benzoate and 40% glucose, the unit composition of PHAs was 65. 48mol% HB and 34. 52mol% HV.
为了研究不同碳源与产物PHAs结构的关系,采用好氧-厌氧-缺氧模式利用6种不同碳源培养活性污泥得到6种不同的PHAs样品,通过〓HNMR、〓CNMR和GC-MS谱图确定了这6种PHAs的单体成分和比例:以乙酸钠培养活性污泥得到的PHAs的单体组成是93.91mol%3-羟基丁酸和6.09mol%3-羟基戊酸;以丙酸钠培养活性污泥得到的PHAs的单体组成除28.66mol%HB、63.13mol%HV外,另外还有2.55mol%3-羟基2-甲基丁酸(2MHB)和5.66mol%3-羟基2-甲基戊酸(2MHV);以80%丁酸钠和20%1,4-丁二醇混合溶液培养活性污泥得到的PHAs含有七种单体组成:65.03mol%HB,28.06mol%HV,1.91mol%2MHB,2.69mol%2MHV,0.73mol%4-HB(4-羟基丁酸),0.78mol%4MHV(3-羟基-4-甲基戊酸),0.80%HHx(3-羟基己酸);以20%丁酸钠和80%1,4-丁二醇培养活性污泥所得到的PHAs含有与3#样品相同的七种单体,只是比例不同,分别是61.39mol%,23.01mol%,4.58mol%,5.97mol%,0.91mol%,2.37mol%,1.77mol%;以60%戊酸钠和40%葡萄糖培养活性污泥所得到的PHAs由HB和HV组成,比例是41.24 mol%∶58.76 mol%;以60%苯甲酸钠和40%葡萄糖培养活性污泥所得到的PHAs也由HB和HV组成,比例是65.48 mol%∶34.52 mol%。
-
The method involves exposing the cells to a compound having the formula I in which: w is a nucleic acid x is a non-amino acid or non-peptide nucleic acid binding group y is a spacer having a chain length equivalent to 1-30 carbon-carbon single covalent bonds or is absent R4 is H or halogen or CH2O-R3; and R1, R2 and R3 are the same or different and are either hydrogen, methyl, ethyl, alkyl, alkenyl, hydroxylated alkyl, hydroxylated alkenyl groups or ether containing alkyl, alkenyl, hydroxylated alkyl or hydroxylated alkenyl groups optionally being an acyl group having a carbon chain length equivalent to 3-24 carbon atoms saturated or unsaturated, with the proviso that at least one of R1, R2 or R3 includes a group having a carbon chain of 3-24 carbon atoms saturated or unsaturated, or to a compound having the formula II in which: w is a nucleic acid x is a non-amino acid or non-peptide nucleic acid binding group y is a space having a chain length equivalent to 1-30 carbon-carbon single covalent bonds or is absent, R5 is alkyl, alkenyl, hydroxylated alkyl, hydroxylated alkenyl group or ether containing alkyl, alkenyl, hydroxylated alkyl or hydroxylated alkenyl group optionally being an acyl group having a carbon chain length equivalent to 3-24 carbon atoms saturated or unsaturated, with the proviso that R5 includes a group having a carbon chain of 3-24 carbon atoms saturated or unsaturated.
该方法包括使细胞暴露于具有式的化合物,在式中:w是核酸,x是非氨基酸或者非肽核酸结合基团,y是具有等于1―30个碳―碳单共价键的链长的间隔基或者不存在,R4是H或者卤素或者CH2O-R3;R1、R2和R3是相同的或者不同的并且是氢、甲基、乙基、烷基、链烯基、羟基化烷基、羟基化链烯基或者包含烷基、链烯基、羟基化烷基或羟基化链烯基的醚,任选地是来源于具有等于3―24个碳原子的碳链长的饱和或不饱和脂肪酸的酰基,其条件是R1、R2或者R3的至少一个包括具有3―24个碳原子的饱和或不饱和碳链的基团,或者使细胞暴露于具有式的化合物,在式中:w是核酸,x是非氨基酸或者非肽核酸结合基团,y是具有等于1―30个碳―碳单共价键的链长的间隔基或者不存在,R5是烷基、链烯基、羟基化烷基、羟基化链烯基或者包含烷基、链烯基、羟基化烷基或羟基化链烯基的醚,任选地是具有等于3―24个碳原子的饱和或不饱和碳链的链长的酰基,其条件是R5包括具有3―24个碳原子的饱和或不饱和碳链的基团。
-
Their structures were characterized as dihydroconiferyl dihydro-p-coumarate, vanillin, apocynin, p-hydroxybenzaldehyde, syringaldehyde, syringic acid, syringylethanone,α-hydroxypropiosyringone, coniferyl aldehyde, dihydroconiferyl alcohol, 2-hydroxyphenylpropanol, and 3-hydroxy-4-methoxy-phenylethanol, respectively.
结果 从该植物中分离得到12个酚性化合物,其结构分别为二氢松柏醇二氢对羟基桂皮酸酯,香草醛,罗布麻宁,对羟基苯甲醛,丁香醛,丁香酸,丁香乙酮,α-羟基丁香丙酮,松柏醛,二氢松柏醇,2-羟基苯丙醇和3-羟基-4-甲氧基苯乙醇。
-
Seven Schiff bases of N-(4-hydroxyphenylmethylene)-1-naphthylamine, N-(4-hydroxyphenylmethylene)-p-methoxyaniline, N-(4-hydroxyphenylmethylene)-benzylamine, N-(4-hydroxy-3-methoxyphenylmethylene) furfurylamine, N-(4-hydroxy-3-methoxyphenyl methylene)-p-methylaniline, N-(4-hydroxy-3-methoxyphenylmethylene)-p-methoxyaniline and N-salicylidene-4-aminoantipyrine were first synthesized by the one step solid phase reactions between aromatic aldehydes with phenolic hydroxyl and amines at room temperature without solvent.
分别以带酚羟基的芳醛与胺类反应,首次通过室温固相反应一步合成了N-(4-羟基苯基亚甲基)-1-萘胺、N-(4-羟基苯基亚甲基)-对甲氧基苯胺、N-(4-羟基苯基亚甲基)-苄胺、N-(4-羟基-3-甲氧基苯基亚甲基)糠胺、N-(4-羟基-3-甲氧基苯基亚甲基)-对甲苯胺、N-(4-羟基-3-甲氧基苯基亚甲基)-对甲氧基苯胺和N-亚水杨基-4-氨基安替比林7种Schiff碱,反应15min完成,产率均超过90%。
-
On the basis of spectral analysis, these compounds were identified as Kaempferol , Kaempferol-3-O-β-D-glucopyranoside , Kaempferol-3-O-β-D-galactopyranoside, Quercetin , Quercetin-3-O-β-D-arabinopyranoside, Quercetin-3-O-β-D-galactopyranoside, gallic acid, methyl gallate-4-O-β-D- galactopyranoside, caffeicacid, methyl caffeate, 4-cafeoyl-(3"a, 4"a, 5"β)- trihydroxyquinic acid, 3"-cafeoyl-(3"a, 4"P, 5"P )-trihydroxyquinic acid methyl ester, 5"-cafeoyl-galactonic acid , pumiloside, loganic acid , 5R,6S,7E-megastima-3-on-7-en-9-ol 9-O-β-D-glucopyranoside. 2a, 3β-dihydroxy-oleanoic acid , 2a, 3β, 23-trihydroxy-oleanoic acid, 3a, 6a-dihydroxy-oleanoic acid, 3β-hydroxy-ursoic acid, 2a, 3a, 23-trihydroxy-ursoic acid , 2a, 3β, 23-trihydroxy-ursoic acid, 2β, 3β, 19a -trihydroxy-ursoic acid, 2a , 3β, 19a -trihydroxy-ursoic acid-28-O-β-D-glucopyranoside , 2a. 3a, 19a-trihydroxy-ursoic acid-28-O-β-D-glucopyranoside, 2a, 3a, 19a, 23-tetrahydroxy-ursoic acid, 1a, 3a, 19a, 23-tetrahydroxy-ursoic acid-28-O-β-D-glucopyranoside , 3a, 19a, 23-trihydroxy-ursoic acid.
从珙桐中分离鉴定得到了28种化合物,它们分别是:山奈酚,3-O-β-D-吡喃葡萄糖基-山奈酚甙,3-O-β-D-吡喃半乳糖基-山奈酚甙,槲皮素,3-O-β-D-吡喃阿拉伯糖基-槲皮素甙,3-O-β-D-吡喃半乳糖基-槲皮素甙,没食子酸,4-O-β-D-吡喃半乳糖基-没食子酸甲酯,咖啡酸,咖啡酸甲酯,4-咖啡酰基-(3&α,4&α,5&β)-三羟基鸡纳酸,4-咖啡酰基-(3&α,4&β,5&β)-三羟基鸡纳酸甲酯,5'-咖啡酰基-半乳糖酸,pumiloside,loganic acid,5R,6S,7E-megastima-3-on-7-en-9-ol9-O-β-D-glucopyranoside,2α,3β-二羟基齐墩果酸,2α,3β,23-三羟基齐墩果酸,3α,6α-二羟基齐墩果酸,3β-羟基熊果酸,2α,3α,23-三羟基熊果酸,2α,3β,23-三羟基熊果酸,2β,3β,19α-三羟基熊果酸,2β,3β,19α-三羟基熊果酸-28-O-β-D-吡喃葡萄糖甙,2α,3α,19α-三羟基熊果酸-28-O-β-D-吡喃葡萄糖基甙,2α,3α,19α,23-四羟基熊果酸,2α,3α,19α,23-四羟基熊果酸-28-O-β-D-吡喃葡萄糖基甙,3α,19α,23-三羟基熊果酸。
-
To study the bioactive components from water soluble extract of the Chinese eaglewood, various column chromatography of Chinese eaglewood led to the isolation of ten compounds. Their structures were elucidated as 2,3-bis(3-hydroxyphenyl)- propan-1-ol (1), [(2R,3R)-3-(4-amino-3,5-dimethoxyphenyl)oxiran-2-yl]methanol (2), 8-chloro-4'- methoxy-5,6,7,3'-tetrahydroxy-2-(2-phenethyl)-5,6,7,8-tetrahydrochromone (3), 4'-methoxy-5,6,7,3'-tetrahydroxy-2--5,6,7,8-tetrahydrochromone (4), the isomer of 4 (5), 4'-methoxy-5,6,7,8-tetrahydroxy-2-(3'-hydroxyphenethyl)-5,6,7,8- tetrahydrochromenone (6), 4'-methoxyisoagarotetrol (7), 6-hydroxy-2-(2-hydroxy-2- phenethyl)-chromone (8), 6-hydroxy-2-(2-phenethyl)-chromone (9), 6-hydroxy-2-(4'- hydroxy-2-phenethyl)-chromone (10), and Guaiacylacetone (11) by means of spectral analysis and comparison with references.
为了进一步发现沉香中具有生理活性的化学成分,本文对国产沉香的水溶性成分进行了研究,从中分离得到11个化合物,通过红外、紫外、质谱、核磁共振(1H-NMR, 13C-NMR, COSY, HSQC, HMBC, ROESY)波谱解析,分别鉴定为:2,3-二(3-羟基苯基)-丙-1-醇(1),[(2R,3R)-3-(4-氨基-3,5-二甲氧苯基)-2-氧化烯基]甲醇(2),8-氯-4'-甲氧基-5,6,7,3'-四羟基-2-(2-苯乙基)-5,6,7,8-四氢色原酮(3),4'-甲氧基-5,6,7,3'-四羟基-2-(2-苯乙基)-5,6,7,8-四氢色原酮(4),化合物3的差向异构体(5),4'-甲氧基-5,6,7,8-四羟基-2-(3'-羟基-2-苯乙基)-5,6,7,8-四氢色原酮(6),4'-甲氧基异沉香四醇(7),6-羟基-2-(2-羟基-2-苯乙基)色原酮(8),6-羟基-2-(2-苯乙基)色原酮(9),6-羟基-2-(4'-羟基-2-苯乙基)色原酮(10)和Guaiacylacetone (11)。
-
The more the number of hydroxyl substitution in phenyl ring, the better the ability of scavenging DPPH free radical. That is, trihydroxy is better than dihydroxy, and dihydroxy is better than monohydroxy. Moreover, when the polyhydroxy exists in phenyl ring and it is ortho-position or para-position, the ability of scavenging DPPH free radical is better too.
当苯甲醯基的苯环上羟基取代数量越多,其清除DPPH自由基的能力越好,三羟基效果优於双羟基、单羟基,双羟基效果优於单羟基;而苯甲醯基苯环上若为多羟基且羟基的位置为邻位或对位的关系时,其在清除DPPH自由基的能力较佳。
-
Itamin D from the skin and diet is metabolized in the lier to 25-hydroxyitamin D (Figure 1), which is used to determine a patient's itamin D status1,2,3,4; 25-hydroxyitamin D is metabolized in the kidneys by the enzyme 25-hydroxyitamin D-1-hydroxylase (CYP27B1) to its actie form, 1,25-dihydroxyitamin D.1,2,3,4 The renal production of 1,25-dihydroxyitamin D is tightly regulated by plasma parathyroid hormone leels and serum calcium and phosphorus leels.1,2,3,4 Fibroblast growth factor 23, secreted from the bone, causes the sodium–phosphate cotransporter to be internalized by the cells of the kidney and small intestine and also suppresses 1,25-dihydroxyitamin D synthesis.5 The efficiency of the absorption of renal calcium and of intestinal calcium and phosphorus is increased in the presence of 1,25-dihydroxyitamin D (Figure 1).2,3,6 It also induces the expression of the enzyme 25-hydroxyitamin D-24-hydroxylase (CYP24), which catabolizes both 25-hydroxyitamin D and 1,25-dihydroxyitamin D into biologically inactie, water-soluble calcitroic acid.2,3,4
从皮肤和食物来的维生素D在肝中代谢为25-羟基维生素D(图1),被用来决定病人体内维生素D情况的1,2,3,4;25-羟基维生素D在肾中被25-羟基维生素D1羟化酶(CYP27B1)转变为有活性的1,25-二羟基维生素D 。1,2,3,4由肾产生1,25-二羟基维生素D是被血浆甲状旁腺激素和血清钙,磷水平紧密调节。1,2,3,4由骨分泌的成纤维细胞生长因子23使钠磷协同转运蛋白被肾和小肠细胞内化及抑制1,25-二羟维生素D合成。5 在1,25-二羟基维生素D作用下肾和小肠吸收钙及磷的效率增高(图1)。2,3,6 它也包括25-羟四- 24 -羟化酶的表达(CYP24),且将1,25二羟基维生素D和25羟基维生素D异化成无生物活性,水溶性的维生素D3-23羧酸。2,3,4
- 更多网络解释与羟基相关的网络解释 [注:此内容来源于网络,仅供参考]
-
Butyl Paraben:对羟基苯甲酸丁酯
对羟基苯甲酸甲酯 methylparaben | 对羟基苯甲酸丁酯 butyl paraben | 对羟基苯甲酸丙酯 propyl paraben
-
hydroxy citronellal:羟基香茅醛
222 3-hydroxy-2-butanone 3-羟基-2-丁酮 2008 I1232 | 223 hydroxy citronellal 羟基香茅醛 2583 A3017T | furanone 4-羟基-2,5-二甲基-3-
-
hydroxy coumarin:羟基香豆素
hydroxy amide 羟基酰胺 | hydroxy coumarin 羟基香豆素 | hydroxy ester 羟基脂
-
hydroxy acid:羟基酸,羟基烃酸
hydroximic acid 异羟肟酸 | hydroxy acid 羟基酸,羟基烃酸 | hydroxy fatty acid 羟基脂肪酸
-
hydroxyl value:羟基值
hydroxyl ion 羟基离子 | hydroxyl value 羟基值 | hydroxyl 羟基
-
hydroxyl radical:羟基自由基
(三)羟基自由基 (hydroxyl radical) HO.羟基自由基算是最会跑的自由基之一,除自由基转换之外,在很多情况下也会大量产生 HO..它会造成体内脂质过氧化进一步破坏细胞,且会和胺基酸,核醣体,磷脂质等生物体内 反应.多元饱和脂肪酸(PUFA)和羟基自由基关系非常密切,
-
Purpurin:羟基茜草素
[化学成分]根含多种羟基蒽醌衍生物,如茜草素(alizarin)异茜草素(purpuro-xanthin)羟基茜草素(purpurin)伪羟基茜草素(pseudopurpurin)茜草酸(munjistin)茜草甙(rubia,ruberythric acid)大黄素甲醚等,又分离得升白活性成分茜草萘酸甙Ⅰ及Ⅱ,
-
8-Hydroxy Quinoline:8-羟基喹啉
8-羟基硫酸喹啉 8-HYDROXY QUINOLINE SULPHATE | 8-羟基喹啉 8 Hydroxy quinoline | 8-羟基喹啉 8 Hydroxy Quinoline Min. 99%
-
hydroxy stearic acid:羟基硬脂酸
hydroxy silicone oil emulsion 305 羟基硅油乳液305 | hydroxy stearic acid 羟基硬脂酸 | hydroxy-iso-butyric acid 羟基异丁酸
-
hydroxy acid:羟基酸,羟基烃酸
hydroximic acid 异羟肟酸 | hydroxy acid 羟基酸,羟基烃酸 | hydroxy fatty acid 羟基脂肪酸