碘化

基本解释 (translations)

iodination

与碘化相关的网络例句 [注：此内容来源于网络，仅供参考]

Garlic essence is used for raw material which conducts chemical reaction with iodine or iodine chloride to generate iodated modified garlic essence. Said modified garlic essence is then passed through emulsifying and glucose absorption to make into odourless powder with good dispersiveness in water.

碘化改性大蒜素的制备方法是采用大蒜素为原料和碘或氯化碘发生化学反应，生成碘化改性大蒜素，再经乳化、葡萄糖吸附制成无臭的水中分散性良好的粉剂。

Result: 1. The method of arc-needle injection with 131I-iodinated oil step-by-step sector-shapely improved obviously the drug distribution, comparing with routine linearity injection. 2. SPECT image reconstruction detect 131I-iodinated oil three-dimensional distribution quantitatively. 131I-iodinated oil metabolism equation may obtained by continuous measurements, in order to calculate absorption dose of p particle at target. 3. ZT glue lengthens obviously 131I-iodinated oil retention in mouse local subcutis and rabbit liver which can rise local radiation effect, decrease injury at normal tissue.

结果：1、弧形针分段扇形注射~(131)I-碘化油，比常规使用的线性注射明显改善药物弥散均匀度。2、SPECT断层扫描定量检测~(131)I-碘化油的三维分布，连续测量建立~(131)I-碘化油的代谢方程，并计算~(131)I对靶区的β辐射贡献的吸收剂量。3、ZT胶明显延长~(131)I-碘化油在大鼠皮下、兔肝脏内的滞留。

I-iodinated oil metabolism equation may obtained by continuous measurements, in order to calculate absorption dose of β particle at target. 3. ZT glue lengthens obviously 〓I-iodinated oil retention in mouse local subcutis and rabbit liver which can rise local radiation effect, decrease injury at normal tissue.

结果：1、弧形针分段扇形注射〓I-碘化油，比常规使用的线性注射明显改善药物弥散均匀度。2、SPECT断层扫描定量检测〓I-碘化油的三维分布，连续测量建立〓I-碘化油的代谢方程，并计算〓I对靶区的β辐射贡献的吸收剂量。3、ZT胶明显延长〓I-碘化油在大鼠皮下、兔肝脏内的滞留。

In chapter four, the preperation of ytterbium diiodide was examined. The reductive cleavage of Se-Se bond and S-S bond induced by ytterbium diiodide was investigated. The reaction of diselenides and disulfides with allylic bromide promoted by ytterbium diiodide was also examined. The intermolecular Barbier-type reaction induced by ytterbium diiodide was studied. In the last section of this chapter, the intermolecular reductive coupling of nitriles with azides induced by samarium diiodide was investigated.

第四章，研究了二碘化镱的制备方法，以及二碘化镱作为一种优良的单电子转移试剂在有机合成中的应用：二硒醚的Se--Se键和二硫醚S-S键的还原断裂，及其在合成烯丙基硒醚，硒代酯和烯丙基硫醚，硫代酯中的应用，实验结果表明二碘化镱也能促进分子间的Barbier反应，而文献认为二碘化镱不能促进分子间的Barbier反应；最后研究了二碘化钐促进的叠氮化合物与腈的交叉还原偶联反应，一步高收率地制备脒的方法。

The chapter two was focused on the samarium diiodide promoted organic reactions and their applications in organic synthesis, firstly, a new synthesis of highly substituted cyclopentadienes from a,β-alkynone promoted by samarium diiodide was investigated and the highly substituted cyclopentadienes were prepared in moderate to good yields under mild conditions. Secondly, the Michael addition and Michael-aldol tandem reaction of diorganyl diselenides or diorganyl disulfides with α,β-alkynones mediated by samarium diiodide were studied and a series of alkenylsulfides and alkenylselenides were prepared in good yields. Then the highly regioselecfive nucleophilic addition of the allylsamarium bromide to α,β-alkynones were explored. We found that the allylsamarium bromide reacts with α,β-alkynones to afford regiospecificly 1. 2-nucleophilic addition products in good yields under mild condition. At last we studied the coupling reaction of aryl halides promoted by NiCl〓/PPh〓/Sm〓.

第二章 研究了二碘化钐、金属钐促进的有机反应：1、二碘化钐促进下α，β-炔基酮的偶联环化反应，提供了一种制备多取代环戊二烯的新方法；2、二碘化钐促进下的二硫醚、二硒醚与α，β-炔基酮的Michael加成反应，为高产率地制备多取代的烯基硫或烯基硒化合物提供了方便可靠的新方法；3、二碘化钐促进下的二硫醚、二硒醚与α，β-炔基酮和醛、酮的Michael—aldol串联反应，提供了一种一锅法高产率地制备多取代的含硫的烯丙基醇或含硒的烯丙基醇类化合物的方便可靠的原子经济性的新方法；4、烯丙基溴化钐与α，β-炔基酮的高度区域选择性的1，2-亲核加成反应；5、NiCl〓/PPh〓/Sm〓促进的卤代芳烃的偶联反应-一种从各种卤代芳烃制备联苯类化合物的有效方法。

The iodination of fluorinated ylide-anions using element iodine or 1,2-diiodoethane wassuccessfully underwent and a series of of perfluoroalkylated α-iodo-α,β-unbsaturated nitriles were prepared.

成功地进行了含氟叶立德阴离子的碘化反应，通过用不同的碘化试剂即单质碘或〓， 2-二碘乙烷制备了一系列全氟烷基化的α—碘代—α，β-不饱和腈。

About tetra-n-butyl ammonium polyiodides: triiodide and pentaiodide anions are the basic building blocks; heptaiodide anion and undecaiodide anion are composed by triiodide anion, and nonaiodide anion is composed by pentaiodide anion. Therefore the character of triiodide, heptaiodide and undecaiodide polyiodides is similar, and that of pentaiodide and nonaiodide polyiodides is similar.

正四丁基多碘化铵化合物中：碘三离子和碘五离子是基本的结构单元，碘七离子和碘十一离子是由碘三离子构成的，碘九离子是由碘五离子构成的，所以碘三、碘七和碘十一形式的高聚碘具有相似的性质，碘五和碘九形式的高聚碘具有相似的性质。

The following conclusions have been gotten from a large amount of experiments and determinations: Triiodide, pentaiodide, heptaiodide, nonaiodide, undecaiodide of solid tetra-n-butyl ammonium polyiodides and tetrabutyl ammonium bromide polyiodides can be synthesized by solid phase process which is a economic easy way, while its not suitable for synthesizing solid tetramethyl ammonium polyiodides; Solution polyiodides of triiodide, pentaiodide can be synthesized through the complexation process, and TX-10 is a better complexing agent; Triiodide, pentaiodide, heptaiodide resinic polyiodides were synthesized by ion-exchange of resinifying process, and that is a viable easy way.

在大量实验和分析的基础上，可得到以下结论：用固相法可以合成出碘三、碘五、碘七、碘九和碘十一形式的正四丁基多碘化铵固体高聚碘和四丁基多碘化溴化铵固体高聚碘系列化合物，是制备高聚碘的经济、方便的合成方法，但此法对合成四甲基多碘化铵固体高聚碘系列化合物并不适用；TX-10是合成溶液高聚碘较佳的络合剂，通过其络合作用可以合成出碘三和碘五形式的溶液高聚碘；采用树脂法，通过离子交换，合成出了碘三、碘五和碘七形式的树脂高聚碘，此法简单可行。

The electric conductivity of solid polyiodides increases largely as the aggrandizement of polyiodide anions"polymerization degree. The solid polyiodides have excellent sterilizing effects and the effect of tetra-n-butyl ammonium undecaiodide is the best of them, and the sterilizing effects increase as the aggrandizement of polyiodide anions" polymerization degree. The sterilizing effects of resinic polyiodides increase as the aggrandizement of polyiodide anions polymerization degree, the heptaiodide resinic polyiodide has better sterilizing effects than the triiodide and pentaiodide.

固体高聚碘系列化合物的电导率随着高聚碘阴离子聚合度的增加而增加，并且增幅较大；固体高聚碘对常见细菌均具有很好的杀灭作用，并且随着高聚碘阴离子聚合度的增加，杀菌能力也随着增强，其中正四丁基十一碘化铵杀菌剂的效果最佳；树脂高聚碘随着高聚碘阴离子聚合度的增加，杀菌能力增强，碘七树脂高聚碘的杀菌效果要明显好于碘三树脂和碘五树脂高聚碘。

In solid phase process, the polyiodides, which include triiodide, pentaiodide, heptaiodide, nonaiodide and undecaiodide tetra-n-butyl ammonium iodide, tetrabutyl ammonium bromide and tetramethyl ammonium iodide poly-compounds, were synthesized by the low-heat solid phase reaction between iodine and tetra-n-butyl ammonium iodide, tetrabutyl ammonium bromide or tetramethyl ammonium iodide; In complexation process, solution polyiodides were synthesized by complexing action of different agents; In resinifying process, triiodide, pentaiodide, heptaiodide resinic polyiodides were synthesized by ion-exchange when the strong basicity styrene anion exchange resin, potassium iodide and iodine were used as raw materials.

固相法是用正四丁基碘化铵、四丁基溴化铵或四甲基碘化铵分别与碘作用，通过低热固相反应，合成出碘三、碘五、碘七、碘九和碘十一形式的正四丁基碘化铵、四丁基溴化铵或四甲基碘化铵的系列高聚碘化合物；在络合法合成溶液高聚碘的实验中，选用几种络合剂通过络合作用首次合成了溶液高聚碘；树脂法合成高聚碘的实验是采用强碱性苯乙烯系阴离子交换树脂、碘化钾和碘为原料，通过离子交换，合成了碘三、碘五和碘七形式的树脂高聚碘。

与碘化相关的网络解释 [注：此内容来源于网络，仅供参考]

platinum diiodide：二碘化铂,碘化铂

platinum difluoride 二氟化铂 | platinum diiodide 二碘化铂,碘化铂 | platinum dish 白金杯

iodinate：碘化

iodinase碘化酶 | iodinate碘化 | iodinatedcasein碘化酪蛋白

iodization：碘化作用

iodization碘化作用 | iodize加碘;碘化 | iodizedstarch碘化淀粉

iodize：加碘;碘化

iodization碘化作用 | iodize加碘;碘化 | iodizedstarch碘化淀粉

iodinated casein; iodocasein：碘化酪蛋白

碘化酶 iodinase | 碘化酪蛋白 iodinated casein; iodocasein | 碘化(作用) iodination

boron monobromide diiodide：一溴二碘化硼

三碘化硼 boron iodide | 一溴二碘化硼 boron monobromide diiodide | 一溴二碘化硼 boron mono-bromide diiodide

platinous iodide：碘化铂(II);二碘化铂

氢氧化铂(II);二(氢氧)化铂 platinous hydroxide | 碘化铂(II);二碘化铂 platinous iodide | 氧化铂(II);一氧化铂 platinous oxide

selenic iodide：碘化硒(IV);四碘化硒

氟化硒(IV);四氟化硒 selenic fluoride | 碘化硒(IV);四碘化硒 selenic iodide | 二氯氧化硒 seleninyl chloride

thallous iodide：碘化亚铊,碘化铊,一碘化铊

thallous hydroxide 氢氧化铊 | thallous iodide 碘化亚铊,碘化铊,一碘化铊 | thallous oxide 一氧化二铊,一氧化铊

iodized salt：碘化食盐,碘化盐

iodized poppy-seed oil ==> 碘化罂粟油 | iodized salt ==> 碘化食盐,碘化盐 | iodized starch ==> 碘化淀粉