硝基苯

基本解释 (translations)

nitrobenzene  ·  mirbane  ·  nitrobenzol

词组短语

mirbane oil · myrbane oil

与硝基苯相关的网络例句 [注：此内容来源于网络，仅供参考]

Is a high-tech private enterprise, located in Laohekou City, Hubei Province, the main products are: 3,4 - dichloro-nitrobenzene; 3,4 - dichloroaniline; 2,4 - dimethyl-nitramine p; 2,4 - dimethylaniline; 2,6 - dimethyl-nitrobenzene; 2,6 - dimethylaniline; 3,5 - dimethyl-nitrobenzene; 3,5 - dimethyl Aniline; acrolein; Glutaraldehyde and other fine chemical products.

老河口联谊化工有限公司为一家高科技民营企业，位于湖北省老河口市，主要产品有：3，4-二氯硝基苯；3，4-二氯苯胺；2，4-二甲基硝基苯；2，4-二甲基苯胺；2，6-二甲基硝基苯；2，6-二甲基苯胺；3，5-二甲基硝基苯；3，5-二甲基苯胺；丙烯醛；戊二醛等精细化工产品。

First, the preparation of l,2-dichloro-4-nitrobenzene, which l-chloro-4-nitrobenzene reacted with chlorine in a self-designed chlorinator, in presence of Lewis acid catalyst,.was investigated. By means of the Orthogonal Experiments design and single factor experiments, the influence of several reaction variables on the yield were examined and the optimum reaction conditions under the intervallic operation were obtained, the yield of l,2-diehloro-4-nitrobenzene was 83.26%.

为此，本文首先在自行设计的塔式氯化器中，以对硝基氯苯为原料，路易氏酸作催化剂，分子氯氯化合成3，4-二氯硝基苯(合成3-氯-4-氟-硝基苯的原料)，根据该氯化过程特征，利用正交试验设计方法结合单因素实验考察了有关因素对氯化过程的影响，优化得到了最佳的氯化工艺条件，3，4—二氯硝基苯的收率可达83.26％。

Using solution culture experiment, discussed the influnce of nitrobenzene to the germinationrates and seedling growth of ten leguminous crops, and results showed that, when the nitrobenzeneconcentration was 1～100mg·L~(-1), it had little influnce to germination rates of leguminous crops,with the increasing of nitrobenzene concentration, emergence rates of leguminous crops decreased,but no significance compared with control, and found that the toxicity of nitrobenzene toleguminous related with the concentration, the thresholds of nitrobenzene toxicity to differentleguminous crops were different, under the test conditions, the inhibition of root was larger thanhypocotyl, according to the relationship between the inhition rates of root and hypocotyl length andthe nitrobenzene concentration, the sensitive order of the ten leguminous crops to nitrobenzenewas:small-seedsoybean＞kidneybean＞Dongnong42＞brownbean＞Dongnong49＞Dongnong46＞ormosia＞french bean＞black bean＞mung bean.

本研究探索了硝基苯对十种豆类作物的发芽率及幼苗生长的影响，结果表明：硝基苯浓度为1～100mg·L~(-1)时，对豆类作物发芽率影响不大，随着硝基苯浓度的增加，豆类作物出苗率有所降低，但与对照差异不显著，研究发现硝基苯对豆类作物的生物学毒性同浓度有关，硝基苯对不同的豆类作物的毒害阈值不同。

The catalyst, palladium supported with chitosan condensated with salicylaldehyde, was studied in hydrogenation ofα-octene, nitrobenzene, 4-nitrophenol and m-dinitrobenzene, it was active and good selectivity forα-octene and nitrobenzene, when the activation time is 90 min, the catalyst showed the best hydrogenation active.

壳聚糖缩水杨醛负载不同比例PdCl_2的催化剂对α-辛烯、硝基苯、4-硝基酚和间二硝基苯的催化性能进行了研究，结果表明该催化剂活化90 min时加氢催化活性最好，对α-辛烯，硝基苯的催化选择性在催化5 h时达到了100%。

Humic acids, oxidizable fraction and lipids were the main fractions affecting the sorption capacity. The humic acids had the maximum adsorption capacity for nitrobenzene and aniline, the lipids naturally present in the soil strongly compete for hydrophobic sorption sites within the soil organic matter, and the adsorption capacity of mineral surface for nitrobenzene and aniline were only 2.31mg·kg-1 and 3.63mg·kg-1, respectively.

硝基苯和苯胺在湿地土壤中的吸附主要受腐殖酸、易氧化有机质组分和脂类化合物的影响，其中腐殖酸对硝基苯和苯胺具有最大的吸附容量；脂类化合物表现为与硝基苯、苯胺竞争土壤有机质结构中的吸附位点，去除脂类化合物后残余物的吸附量增大；矿物组分对硝基苯和苯胺的吸附是次要的，吸附容量仅为2.31mg·kg-1和3.63mg·kg-1。

The results of batch experiments showed that the anaerobic biodegradation kinetics of 2-CNB and 4-CNB by granular sludge were follwed by first-order reaction. The nitro groups of 2-CNB and 4-CNB were more easily attacked by electron than chlorines and they were reductively biotransformed to amino groups under anaerobic conditions. The acclimated anaerobic granular sludge, which could dechlorinate 4-chloroanline to aniline, showed that it had the ability of para-dechlorinating. The anaerobic biodegradating on pathway of 2-CNB and 4-CNB were suggested as follows:AbstractIn ZVI(zero-valent iron, Fe0)-reduction system, the nitro groups of 2-CNB and 4-CNB were reductively transformed to amino groups.

2分批试验结果证明，颗粒污泥降解2-CNB和4-CNB遵循一级动力学，在厌氧条件下，CNB发生序列的硝基还原与脱氯作用，苯环上的硝基比氯原子更容易受到亲电子攻击，发生还原反应生成氨基；所获得的颗粒污泥具有对位脱氯活性，可使4-CA进一步脱氯形成苯胺。2-CNB和4-CNB厌氧降解的建议性途径为： ZVI(Zero-valentiron)对2-CNB和4-CNB的作用主要是将苯环上的硝基还原为氨基；在ZVI与污泥共还原转化体系中，ZVI对氯代硝基苯的硝基转化具有一定的促进作用，但因ZVI对中间产物的吸附特性，终产物形成速率趋慢。

First, by using p-methoxybenzaldehyde , p-hydroxybenzaldehyde and pyrrole as raw materials, 5-(p-hydroxyphenyl)-10,15,20-tri(p-methoxyphyenyl)porpyrin was prepares under acidity condition and the let reacted with benzoyl chloride, o-nitrobenzoyl chloride, m- nitrobenzoyl chloride and p- nitrobenzoyl chloride respectively under alkalinity condition with DMF as solvent.

以对-甲氧基苯甲醛、对-羟基苯甲醛和吡咯为原料，在酸性条件下合成了5-对羟苯基10，15，20-三对甲氧苯基卟啉，再以该化合物为原料分别与苯甲酰氯、邻-硝基苯甲酰氯、间-硝基苯甲酰氯和对-硝基苯甲酰氯反应，在碱性条件下以DMF为溶剂合成了四种目前尚未见文献报道的对-甲氧基卟啉硝基苯甲酸酯类化合物。

There are three different nucleophilic reagent respectively reaction with m-dinitrobenzene ramification at distint alkaline term:With the nitrobenzene 、 m-nirtobenzenesulfone sodium salt 、 2.4-dinitro chlorobenzene 、 m-dinitrobenzene for bottom thing, benzyl cyanide、 benzyl chloride、 benzyl chloropyridine、is a nucleophilic reagent reaction for under the different term proceeds a series reaction. At the same time ,discuss about the impact factor to nucleophilicity such as the number of attract electron group、 ability of attract electron and the nucleophilic substitution reaction part.

设计了三类不同的亲核试剂分别与活化芳环在不同的碱性条件下发生反应：以苄基氰、苄基氯化吡啶为亲核试剂，以硝基苯、间二硝基苯、间硝基苯磺酸钠、2，4-二硝基苄基氯为底物进行亲核取代反应；并且对亲核试剂的体积效应、溶剂效应对亲核性影响，底物上吸电子基团的数目、吸电子能力对亲电性的影响，以及亲核取代反应的发生部位受哪些因素影响进行探讨。

The calculated results with B3LYP/6-31G-DFT show:(1)the molecular total energy of benzofuroxan is lower than that of o-dinitrosobenzene;(2)the activation energy(Ea+=51.0kJ/mol)of forward reaction that benzofuroxan isomerises into o-dinitrosobenzene,is in agreement with the experimental(58.6kJ/mol)provided by reference,and the activation energy(Ea-=4.6kJ/mol)of back-ward reaction is very small.It is concluded thereby that benzofuroxan is more stable than o-dinitrosobenzene.In addition,the corresponding ab initio calculations at the level of HF/3-21G,HF/6-31Gand MP2/6-31G//6-31G were completed,and it was found that the calculated results by B3LYP-DFT method are superior to those from ab initio calculation.

结果表明，苯并氧化呋咱的分子总能量比邻二亚硝基苯的低；由苯并氧化呋咱异构为邻二亚硝基苯的正向反应活化能（Ea+=51.0kJ/mol），与文献实测值（58.6kJ/mol）较接近，而其逆向反应活化能（Ea-=4.6kJ/mol）很小，从而揭示了苯并氧化呋咱比邻二亚硝基苯更稳定·此外，进行了HF/3-21G、HF/6-31G和MP2/6-31G//6-31G水平下相应的计算，发现B3LYP-DFT的结果较abinitio为优。

The main research work of this dissertation is as follows: Based on the chemical reaction engineering theory and the nitrobenzene electroreduction mechanism, the plate and frame electrolyzer was designed and applied to the process of electroreduction nitrobenzene to p-aminophenol. This dissertation measured the residence time distribution data of the electrolyzer by means of the pulse response method and studied the rule of flow pattern along with the current capacity change. Under different conditions ,this dissertation studied the cyclic voltammetry properties of nitrobenzene on different electrodes by means of the dynamic cyclic voltammetry method and the electrode materials applied to the NB electroreduction have been selected primarily.Baseed on the results of cyclic voltammetry tests, this dissertation used p-electrode systems to measure the steady-state- polarization curves of nitrobenzene on different electrodes in H-type diaphragm cell, and obtained each primary factor s influence rule and the exchange current density value of each electrode.And then on the basis of the conclusions of fundamental researchs upword, the effects of influence factors on the the yield of p-aminophenol and the current efficiency,such as electrode material, current density, quantity of electricity circulated, nitrobenzene concentration . sulpuric acid concentration and so on, have been studied in detail in the systems of hign temperature , strong acidity and oxygen-poorthrough a series of electrolysis experiments in this paper.After all using Pb as anode Monel metal as cathode Dupont Nafion 417 cation-exchange membrane as membrane, this dissertation obtained the optimum technological condition: reaction temperature about 85C, current density 500A m-2, sulphuric acid concentration 20%wt.

论文的主要研究工作为：运用化学反应工程理论，结合硝基苯的电还原机理，设计出用于硝基苯直接电还原合成对氨基苯酚实验的板框式电解槽，并利用脉冲响应法测定了该板框式电解槽的停留时间分布数据，研究了流型随流量变化的规律；通过动态循环伏安法研究了硝基苯在不同电极上、不同条件下的循环伏安特性，初步评选出了用于硝基苯电还原的电极材料；结合循环伏安的测定结果，在H型隔膜电解槽中采用三电极体系测定了硝基苯在不同电极上、不同条件下的稳态极化曲线，得到了各主要因素的影响规律及硝基苯在各个电极上电还原的交换电流密度数值；在基础研究结论指导下，采用板框式电解槽，在高温、强酸、贫氧系统中，进行了一系列的电解实验，分别考察了电极材料、电流密度、通电量、硝基苯浓度、硫酸浓度等因素对收率及电流效率的影响，最终选择以蒙乃尔合金电极作为阴极、铅合金为阳极、Dupont Nofion 417阳离子交换膜为隔膜，得到由硝基苯直接电还原制对氨基苯酚的最佳电解工艺条件：反应温度85℃，电流密度500A·m~(-2)，硫酸浓度20％wt。

与硝基苯相关的网络解释 [注：此内容来源于网络，仅供参考]

dinitrobenzene：二硝基苯

淮安疾控,健康热线,12320,疾控中心,卫生应急本标准是为工作场所有害因素职业接触限值配套的监测方法,用于监测工作场所空气中芳香族硝基化合物 [包括硝基苯(Nitrobenzene)、二硝基苯(Dinitrobenzene)、二硝基...工作场所空气有毒物质测

dinitrobenzene：二硝基苯(各种异构体)(皮)

二硝基甲苯酰胺 Dinimlmide | 二硝基苯(各种异构体)(皮) Dinitrobenzene | 二硝基邻甲酚(皮) Dinitro-o-cresol

D.N.B.; dinitrobenzene：二硝基苯

二硝丁基酚 dinitrobutyl phenol | 二硝基苯 D.N.B.; dinitrobenzene | 二硝基苯 dinitrobenzene

nitrobenzene：硝基苯

硝基苯(Nitrobenzene)无色或微黄色具苦杏仁味的油状液体,难溶于水,易溶于乙醇、乙醚、苯和油;遇明火、高热会燃烧、爆炸,与硝酸反应剧烈. 倾泻在环境中的硝基苯,会散发出刺鼻的苦杏仁味,在80℃以上其蒸气与空气的混合物具爆炸性;倾倒在水中的硝基苯,

nitrobenzene nitrobenzol：硝基苯

溴化硝基苯 nitrobenzene bromide | 硝基苯 nitrobenzene; nitrobenzol | 硝基苯磺酸 nitrobenzenesulphonic acid

nitrobenzene poisoning：硝基苯中毒

nitrobenzal-acetophenone 硝基亚苄基乙酰苯 | nitrobenzene poisoning 硝基苯中毒 | nitrobenzoic acid 硝基苯甲酸

nitrobenzene bromide：溴化硝基苯

硝基苯甲醚 nitroanisole | 溴化硝基苯 nitrobenzene bromide | 硝基苯 nitrobenzene; nitrobenzol

dinitro benzol：二硝基苯

二硝基苯胺 dimtroaniline | 二硝基苯 dinitro benzol | 二硝基苯类 dinitrobenzenes

Trinitrophenylmethyl Nitramine：硝甲铵基三硝基苯

Trinitrobenzene 三硝基苯 ( 湿的 ) | Trinitrophenylmethyl Nitramine 硝甲铵基三硝基苯 | Triphenyl Phosphate 磷酸三苯酯

trinitrobenzene：三硝基苯 ( 湿的 )

Trimethylphosphite 亚磷酸三甲酯 | Trinitrobenzene 三硝基苯 ( 湿的 ) | Trinitrophenylmethyl Nitramine 硝甲铵基三硝基苯