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Moreover, we found that N-heterocyclic carbene could served as an efficient and novel catalyst for the reactions of aziridines with silylated nucleophiles or acid anhydrides.
随后，我们发现氮杂环卡宾也可以作为一种有机小分子催化剂，分别催化各类硅试剂或酸酐对氮杂环丙烷化合物的开环。
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Platinum and rhodium catalyst are applied largely and widely, because these two kinds of catalysts are so efficient for hydrosilylation that they were researched since a long time ago. Very recently, N-heterocyclic carbene Pt and N-heterocyclic carbene Rh complexes were used as catalysts in hydrosilylation.
最近，铂和铑的卡宾金属配合物作为催化剂应用于各种不饱和化合物的硅氢加成反应，表现出非常优良的催化性能和稳定的物理化学性质，受到了化学工作者们广泛的关注。
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Wada M,Kamiya K,Nasu H.X-ay diffraction analysis of SiO2 gel prepared from monomethyl-tri-ethoxysilane by the sol-gel method.
晏良宏，蒋晓东，江波，吕海宾，袁晓东，"利用氟硅烷提高溶胶-凝胶SiO2增透膜的疏水性"，强激光与粒子束 19，
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Via comprehensive computations, the possibilities of vinylidene and allene intermediates were excluded, and the reaction mechanism was found to contain the following three steps:(1) gold-catalyzed cyclization to give the cyclic intermediate,(2) the cyclic intermediate undergoing a 1,3-H migration to give a more stable intermediate, with the assistance of water-cluster,(3) finially, the 1,2-H or 1,2-silyl migration occuring for generation of the observed product.
通过对各种可能的反应路径的进行计算和比较，排除了亚甲基卡宾和连二烯中间体的可能性，并确定该异构化反应机理包含以下三个步骤：（1）炔丙基吡啶反应在金催化条件下发生分子内的成环得到环状中间体；（2）环状中间体在水分子簇的协助下优先发生1，3-氢迁移反应，异构化得到更为稳定的中间体；（3）最后再进行1，2-氢迁移或是1，2-硅烷基团迁移即得到实验中所观察到的环异构化产物。
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Silene：硅宾
silencer 消声器 | silene 硅宾 | silent block 阻尼器;减震器