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The results show that for collectors of the same kind, their selectivity is in linear relationship with HOMO energy and can be predicted well. For collectors of different kinds, it can be concluded from shape of HOMO and atomic HOMO density that the selectivity of ethoxycarbonyl thionocarbamates is better than the one of xanthogen formates.
结果表明:对于同种类型的捕收剂,其选择性与HOMO能量呈线性关系,依据HOMO能量能较准确地预测这两种捕收剂的选择性能;对于不同种类的捕收剂,通过对HOMO形状以及组成原子的HOMO密度的讨论可知,乙氧羰基硫氨酯类捕收剂的选择性能要比黄原酸甲酸酯类捕收剂的强。
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Major procurement of goods: a three-chlorosilanes, dichloromethane, AE activity ester, 3-iodine Silane, special acid, pentyl chloride, triethylamine, thiadiazole, tetrazolylazo acid, 2 - Acetamide, tetrahydrofuran, the four-guanidine, isopropanol, five phosphorus trichloride, sodium vary bitter, acid, sodium phenylacetate, 6-2 silicon n-amine, Ethylacetoacetate , Methyl isobutyl ketone, potassium dihydrogen phosphate, aluminium oxide, DL methionine, N, N-dimethylaniline, NN-diethyl aniline, 4 sodium EDTA, Anhydrous sodium sulfate, ammonium sulfate, potassium sulfate, sodium acetate, sodium carbonate, DMC, formic acid, sodium chloride medicinal, oxalate, protopine, acetone, alcohol, acetic acid, vinegar Ethyl, butyl acetate, methanol, ethanol (anhydrous, industrial, medicinal), formaldehyde, Ye Jian (30%), hydrochloride (industrial-grade, refined grade, reagent level), sulfate (98%), Ammonia, calcium carbonate, chlorine dioxide, 6 - APA ,7-ACA ,7-ADCA ,7-ANCA, sulbactam, ceftazidime activity ester, Deng salt (hydroxymethyl-K, acid precursors Potassium, sodium dihydrogen methyl), resin, the enzyme, water treatment agent, Xiao Mo agent, demulsifier, flocculants, activated carbon, all kinds of medicinal materials, All kinds of additives
三甲基一氯硅烷、二氯甲烷、AE活性酯、三甲基碘硅烷、特戊酸、特戊酰氯、三乙胺、噻二唑、四氮唑乙酸、二甲基乙酰胺、四氢呋喃、四甲基胍、异丙醇、五氯化磷、异辛酸钠、苯乙酸、苯乙酸钠、六甲基二硅胺烷、乙酰乙酸乙酯、甲基异丁酮、磷酸二氢钾、三氧化二铝、DL蛋氨酸、N,N-二甲基苯胺、NN-二乙基苯胺、乙二胺四乙酸四钠、无水硫酸钠、硫酸铵、硫酸钾、醋酸钠、碳酸钠、碳酸二甲酯、甲酸、药用氯化钠、草酸、片碱、丙酮、正丁醇、冰醋酸、醋酸乙酯、醋酸丁酯、甲醇、乙醇、甲醛、液碱(30%)、盐酸(工业级、精制级、试剂级)、硫酸(98%)、氨水、碳酸钙、二氧化氯、6-APA、7-ACA、7-ADCA 、7-ANCA、舒巴坦、头孢他啶活性酯、邓盐(羟甲基钾、前体酸钾、二氢甲基钠)、树脂、生物酶、水处理剂、消沫剂、破乳剂、絮凝剂、活性碳、各种药用辅料、各种添加剂
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The result indicated that the reacting mixture containing dioxane 11.3mL/g HDCA which had been added ethyl chloroformate drop wise should be keep at 10℃ for 30min, then, rising to 15℃ for another 20min in the step of forming mixed anhydride ,and 1.5mol/L NaOH was used to dissolve taurine before aminolysis, and crude product was recrystalled by acetone in purifying process.
结果表明,形成混酐时,二氧六环用量为11.3ml/g HDCA,滴加氯甲酸乙酯后先在10℃反应30min,再在15℃下反应20min;用1.5mol/L的NaOH水溶液溶解牛磺酸后再进行氨解;粗产品用丙酮重结晶。
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The taurohyodeoxycholic acid was synthesized by aminolysis of sodium taurine with carboxy-carbonate mixed anhydride prepared by reacting hyodeoxycholic acid with ethyl chloroformate at the present of triethylamine.
猪去氧胆酸与氯甲酸乙酯在三乙胺存在下反应生成羟酸-碳酸乙酯混合酐,而后将其与牛磺酸钠进行氨解反应,合成猪磺去氧胆酸。
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The present work extends the obserwtion of an earlier report and Shows that the conduction block in nerve produced by cocaine, procaine, urethane, isotonic choline chloride, TEPP and DFP, though not accompanied by any lowering of membrane potential, can be relieved by anodal current.
本文研究可卡因、普鲁卡因、氨甲酸乙酯、氯化胆碱、依色林、TEPP及DFP在两栖类神经所产生的传导阻遏。
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N-Carbobenzoxy-L-homoserinelactone was prepared via N-alkylation reaction of L-methionine and iodoacetamide with benzyl chloroformate as amino protecting agent.
以L-蛋氨酸为原料,氯甲酸苄酯为氨基保护试剂,与碘乙酰胺(I2微量)内酯化反应,合成N-苄氧羰基-L-高丝氨酸内酯。
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By the polycondensation of amino acid 5-fluorouracil -1, 3-dipropyl esters with bis (2-chloroethyl) phos- phoramidic dichloride in the presence of 〓 or in vacuo, ten new polymers containing 5- fluorouracil, nitrogen mustard and amino acid were synthesized.
将1,3-双-5-氟尿嘧啶与二氯膦甲酸乙酯或二氯膦乙酸乙酯在DMF中反应制备得到20个三元共聚物,体外抗肿瘤试验表明:含有甘氨酸、缬氨酸、苯丙氨酸和酪氨酸的聚合加显示了一定的选择性,并且分析讨论了生物活性与结构之间的关系。
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Bezaldehyde was used as protective agent in first method.S-Epichloeohydrin was aminated and acidulated to give(2S)-1-Amino-3-chloro-propanol Salts.The acetylation of (2S)-1-Amino-3-chloro-propanol by acetic anhydride produced the intermediate-N-[2--3-chloropropyl]acetamide.And then at 20℃,in the presence of lithium tert-butoxide,benzyl 3-fluoro-4-morpholinophenyl carbamate react with-N-[2--3-chloropropyl]acetamide to give linezolid in total yield of 43.6%.
路线一采用苯甲醛作保护剂,使S-环氧氯丙烷氨解、酸化生成S-1-氨基-3-氯-2-丙醇盐酸盐,然后经乙酰化反应后,生成中间体-N-[2-乙酰氧基-3-氯丙基]乙酰胺,再用N-(3-氟-4-吗啉苯基)氨基甲酸苄酯和中间体在催化剂叔丁醇锂存在下25℃反应生成利奈唑酮,总产率达到43.6%。
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It is mainly formed by the reaction between urea (produced by the breakdown of arginine by the yeast) and citrulline (produced by the degradation of arginine by malolactic bacteria and ethanol).
葡萄酒中氨基甲酸乙酯主要由酵母降解精氨酸产生的尿素和苹果酸-乳酸菌降解精氨酸产生的瓜氨酸与乙醇自发反应产生。
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In metabolizing argine, there had no obvious difference among three strains and the control 3 1 DH. Thus, three selected strains had better characters of degrading argininc that they couldn"t over-degrade arginine to produce large numbers" precursors of carcinogenic ethyl carbamate as citrulline, etc.
分析表明,精氨酸分解代谢方面,三个菌株与对照31DH没有明显差异,由此说明,三个优选菌株精氨酸代谢特性良好,不会过多降解精氨酸、代谢产生瓜氨酸等前体物质,从而不会导致致癌物质——氨基甲酸乙酯的大量合成。
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Ethyl carbamate:氨甲酸乙酯
氨甲环酸 Tranexamic Acid | 氨甲酸乙酯 Ethyl Carbamate | 氨甲酸酯类 Carbamates
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diol:二醇
聚氨甲基酸乙酯或氨基甲酸乙酯(URETHANE)它的主杆是二醇(DIOL). 二醇和二异氰酸(DIISOCYNATE)产生作用形成氨基甲酸乙酯键合. 但最常用的是(TDI)异氰酸甲基. 当二异氰酸和二醇在一个过程中就能形成固体橡胶. 这个过程称为"一段法"(ONE SHOT).
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urethane foam:聚氨脂泡沫(塑料),氨基甲酸乙酯泡沫,聚氨酯泡沫体塑料,聚氨酯泡沫体塑料
urethane elastomer 氨基甲酸乙酯人造橡胶 | urethane foam 聚氨脂泡沫(塑料),氨基甲酸乙酯泡沫,聚氨酯泡沫体塑料,聚氨酯泡沫体塑料 | urethral abscess 尿道脓肿
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carbamates:氨甲酸酯类
氨甲酸乙酯 Ethyl Carbamate | 氨甲酸酯类 Carbamates | 氨甲酰胆碱 Carbamylcholine