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These amine substituted acid may polymenze in an analogous manner to unsubst ituted oxo-anions.
这些氨取代酸可以与未取代的氧络阴离子相类似方式聚合。
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In my opinion, Cu complexes with unsaturated alcohol to form a complex compound; the nitrogenous compound introduced serves as the complex compound's stabilizing agent and reduces activation energy of reaction; TMPO serves as oxygen carrier and displays it's selective oxidation function. This new method and mechanism also demonstrates significance to other similar organic reactions.3 In the chlorohydrin reaction, NaCIO is replaced by Ca2see Chapter4.4.3.4(2 .A, this method hasn't been reported in previous literature,which exerts more buffer action to the react system, the yield increased from 52% to 88.6%; at the same time it solve the problem of poor stability and low percentage composition of NaCIO.
认为:CuD与烯醇形成络合物:含氮有机物的引入起到稳定络合物,降低活化能的作用:而TMPO则充当携氧子起传递氧的作用,并具有选择氧化功能:这种新的方法和理论对类似的反应(不饱和醇类在络合体系下选择性催化氧化为对应的醛也具有重要的指导作用。3在异戊二烯的氯醇化反应中,用次氯酸钙代替次氯酸钠见第4章4.3.4(2.A,本方法未见文献报道,使反应系统更加温和,收率由52%提高到88.6%:并解决了次氯酸钠稳定性差、有效氯含量低的实际问题,具有重要的实用意义。
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Chromic trioxide and chromium hemitrioxide are determined with iodometry, the coefficient of variation of chromic trioxide is 0.056%, and the recovery of marked compound is 99.82-99.83%; the coefficient of variation of chromium hemitrioxide is 1.45%,and the recovery of marked compound is 98.55-99.26%; iron is determined by complexometric titration, the coefficient of variation of iron is 1.73%, and the recovery of marked compound is 99.12-99.23%;sulfate is determined by complexometric titration, the coefficient of variation of sulphate is 0.16%, and the recovery of marked compound is
Analysis Of The Chromium Electroplating Wastewater By Oxidation-reduction And Complexometric Titration-化学工程与工艺-本文采用氧化还原滴定法与络合滴定法对镀六价铬的废水中铬酸酐,三氧化二铬,铁和硫酸根的含量进行了测定:铬酸酐和三氧化二铬用碘量法测定,铬酸酐的变异系数为0.056%,加标回收率为99.82-99.83%,三氧化二铬的变异系数为1.45%,加标回收率为98.55-99.26%;铁用络合滴定法测定,其变异系数为1.73%,加标回收率为99.12-99.23%;硫酸根用络合返滴定法测定,其变异系数为0.16%,加标回收率为
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Large single crystals were also obtained by using pyrocatechol as additive. It was shown by 〓Si-NMR and IR that Sipyrocatechol complex was formed in the reaction system.
在F〓体系中,F〓对铝源和硅源起络合和矿化作用,形成可溶性氟硅酸盐AlF〓〓、SiF〓〓络合物,然后缓慢水解成含氧氟硅酸盐络合物,它们再发生定向缩聚,提供了分子筛晶体生长所需的可溶性结构单元。
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The ether oxygen groups and the carbonyl groups of polyurethane could"solvate"alkali metal cation and play the role of driving force of metal cation transport in the systems.
聚醚型超支化聚氨酯中醚氧和羰基集团,相对线性聚氨酯能更有效地通过"络合"和"解络合"方式,起到"溶解"和推动碱金属阳离子传输的作用。
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A highly sensitive fluorescence quenching method for the determination of iron based on the system of iron-oxfloxacin-SDS has been developed. In NaAc-HAc medium, iron reacts with oxfloxacin and SDS to form a non-fluorescent ternary complex which can quench the fluorescence intensity of oxfloxacin.
在表面活性剂十二烷基硫酸钠存在下,铁能与氧氟沙星形成络合物而猝灭氧氟沙星分子的内源性荧光,使其荧光强度显著降低,据此,提出了铁氧氟沙星SDS体系测定铁的荧光分析新方法。
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This paper contains three parts: 1 Synthesis of novel titanium complexes; 2 Polymerization behaviors of alkoxyl substituted Cp Titanocenes as catalysts for styrene syndiotactic polymerization; 3 Polymerization behaviors of alkenyl substituted Cp Lanthanocenes as Methyl Methacrylate polymerization catalysts.
中文题名新型茂钛、噁唑啉钛络合物的合成、表征以及茂钛、茂稀土络合物催化性能的研究副题名外文题名 Synthesis,characterization of novel Cp,oxazoline titanium complexes and polymerization behaviors of titanocenes and lanthanocenes 论文作者张浩导师钱延龙黄吉玲学科专业应用化学研究领域\研究方向金属有机与均相催化学位级别博士学位授予单位华东理工大学学位授予日期2003 论文页码总数148页关键词金属有机化学稀土络合物噁唑啉类钛络合物茂钛络合物馆藏号BSLW /2003 /O627 /27 本论文包括三部分内容:1)有机金属钛络合物的合成;2)烷氧基取代茂钛络合物催化苯乙烯间规聚合的研究;3)烯基取代茂稀土络合物催化甲基丙烯酸甲酯聚合的研究。
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This article reports a new kind of copolymer, non polar polar terpolymer : poly(styrene-butadiene-methyl methacrylate ) P(S-b-B-b-MMA prepared by anionic polymerization with n BuLi as initiator, 1,1 diphenylethylene as capping agent and lithium 2-(-methoxyethoxy) ethoxide as complex agent.
以正丁基锂为引发剂, 1 ,1-二苯基乙烯为戴帽剂, 2-(2-甲氧基乙氧基)乙氧基锂为络合剂,在环己烷、四氢呋喃混合溶剂中,采用阴离子聚合法,于-70℃~-40℃合成了非极性-极性的三嵌段共聚物聚苯乙烯-聚丁二烯-聚甲基丙烯酸甲酯,并借用GPC、1H-NMR、DSC、TEM、IR等仪器对共聚物进行了表征。
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Using zeolite NaY and ZSM-5 as solid support, the zeolite-encapsulated vanadium picolinic complexes catalyst are synthesized and examined as "ship-in-a-bottle"catalyst.
本文进行了将钒氧吡啶酸络合物负载于NaY分子筛和ZSM-5分子筛中合成&ship-in-a-bottle&型非均相络合物催化剂的研究工作。
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The design, synthesis of crosslinked poly-salenCo complexes and their application in the HKR of terminal epoxides Di-salicylaldehydcs and tri-salicylaldchydes S-3, S-4, S-5 were synthesized from some easily prepared acids. The crosslinked polymeric ligands could be prepared by condensation of -1, 2-cyclohexanediamine stoichiometrically with a mixture of S-3 and S-4 in different proportions, polymeric catalysts were obtained by inserting the Co atoms to the ligands.
四 交联poly-salenCo络合物的设计合成及其在末端环氧化合物的HKR中的应用以几种易得的羧酸为骨架,设计合成出了相应的双水杨醛和三水杨醛S-3、S-4、S-5,将双水杨醛S-3和三水杨醛S-4按不同比例混合后再与手性环己二胺缩合制备出交联聚合物配体,该配体与Co络合后得到交联聚合物催化剂。
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oxyhydrogen gas:氢氧气
oxyhaemoglobin 氧络血红蛋白 | oxyhydrogen gas 氢氧气 | ozone depleting substance 消耗臭氧的物质