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For excluding poorly preserved shells, a shell alteration index is suggested to estimate the state of preservation of brachiopod shells through examination under cathodoluminescence and scanning electron microscopes. This study shows brachiopod taxa e.
基于壳体保存程度的详细分析,以阴极发光程度、壳体显微结构为参数建立了壳体成岩作用改造程度的量化模式,经化石壳体氧、碳同位素值的验证,这一模式基本可以用来对不同保存环境下的样品进行筛选。
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By use of the Fischer-Tropsch reaction in a C-H-O system, we discussed the relationships between inorganic CO〓 and some physical chemistry conditions, such as Oxygen flee degree , temperature, pressure, other objects consistency and catalyzer. a when T=200K~2000K, if f〓>0, the reaction of generating CO〓 will be dominant, CH〓 hardily exists; b when T>1000K, CH〓 is not propitious to exist, carbon in system almost exists in form of CO〓; c the more pressure, the more CO〓 is propitious to exist; d the more consistency of CO, O〓 and H〓O, the more CO〓 is propitious to exist, the more consistency of H〓, the more CH〓 is propitious to exist.
依据C-H-O体系费托反应的简化模型,讨论了氧逸度、温度、压强、其它物质浓度、催化剂等物理化学条件对无机成因CO〓生成的影响,从理论上讨论了在地质环境中,无机成因CO〓存在的物理化学条件:1在T=200K~2000K的温度范围内,体系中一旦氧逸度>0,生成CO〓的反应将占绝对优势,CH〓几乎不可能存在;2T>1000K时,不利于CH〓形成,使体系中的碳主要以CO〓的形式存在;3体系压强越大,越有利于CO〓的形成;4反应物CO、O〓、H〓O的浓度越高,越有利与CO〓的存在,H〓的浓度高有利于CH〓的形成。5地质成藏作用可以经历很长的地质年代,这足以补偿矿物岩石中的Ni、Mo、Fe、Co、Ru等催化性能的降低及其它动力学条件的不足,使得费托反应可能发生,从而生成无机成因的CO〓和烃类。
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Apparent correlations of low δ13C between widely separated sections may relate simply to eustatic sea-level drops where phreatic lenses intrude simultaneously during lithification.
较低的碳同位素比值出现在了很长期的并且相对独立的沉积其内,表示了这个时期曾经发生过普遍的海水沉降,同时不断出现了潜水区的透镜体的入侵,从而定义为成岩作用。
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Therelationship of the amount of catalyst and the ee% of product was seen to be negative nonlin-ear. Catalyst 3 was used in the enantioselective addition of diethylzinc to aromatic aldehydesand gave good results. The configuration of products was determined by the configuration ofthe catalysts' chiral carbon linked with hydroxy group. Using β- amino alcohols bearing only one chiral center as catalysts for the enantiose-lective addition were studied. D-N, N-dialkyl-2-amino butanol gave poor catalytic effect be-cause of their structure. The configuration of the product is the same as the catalyst. Anotherkind of β- amino alcohols - phenylglycine derivatives and valine derivatives have chiralcenter on the carbon linked with amino group. Catalyzed by-phenylglycine derivatives 6,7, 9, 10, the reactions gave satisfied results. The optical yields exceeded 80%.
在探讨了含有两个手性中心的β-氨基醇之后,选择了只有一个手性中心的β-氨基醇,一是手性中心为连羟基的手性碳原子:D-N,N-二烷基-2-氨基丁醇;二是手性中心为连氨基的手性碳原子:D-苯基甘氨酸衍生物和L-缬氨酸衍生物。D-2-氨基丁醇的催化效果不太好,这与其结构的空间位阻较小有关系,反应产物与连羟基手性碳构型一致;由苯基甘氨酸和缬氨酸出发合成五种β-氨基醇6-10,研究了不同ee%的-6作用下的二乙基锌-苯甲醛加成反应,发现该催化剂具有不对称放大效应;-7,9,lO的催化效果也比较令人满意,光学产率80%以上,所得产物构型与催化剂构型一致。
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Template-confined growth is a very powerful method for obtaining aligned 1D nanomaterials with adjustable diameter, length and morphology. Porous anodic aluminum oxide templates with different channel structures have been synthesized in our lab, with which the aligned CNT arrays, Y-branching and novel dendriform CNTs have been obtained. Based on the structural characterization of the products, a space-limited and self-catalytic growth mechanism has been proposed accordingly. Roughly speaking, the catalyst particles at the bottom of template channels initiate the nucleation of carbon species, which acts as the seed for subsequent CNT growth.
本文采用近年发展起来的模板控制生长法,以多孔氧化铝模板控制CVD生长的方法调控了碳纳米管有序阵列、γ-分叉及树枝状分叉结构,在对产物进行详尽结构表征和分析的基础上阐述了氧化铝模板控制生长碳纳米管的生长机制:孔道内催化剂仅在生长初始阶段催化碳物种的成核,起&种子&作用,随后模板孔道自身的催化及限域作用使碳纳米管紧贴着孔道内壁生长。
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According to the distribution of the positive charges inthe surface of the cage, it can be expected that two -OH groups finally adding at two sites which arewithin one hexacyclic ring and in different sides of equator, which is accord with the conclusion resultedfrom thermodynamics
通过寻找并分析过度态的结构,发现酸化阳离子中处于赤道带6-6类碳原子上的羟基和两极区域5-5类碳原子上的羟基都有朝邻近赤道带碳原子上迁移的可能,结合碳笼上正电荷的分布特征,预计亲核水解作用将发生在赤道异侧六员环的对位,说明考虑动力学因素,最终获得1,4-加成富勒醇的可能性最大,该结论与热力学的结果一致。
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Dihydrojasmone was synthesized from2-hexyl-5-methyl-1,2-oxaborolane,prepared frommethyl vinyl ketone and hexene,via the homologationwith 〓 followed by PCC oxidation and intra-molecular condensation.In stead of the oxidation ofthe C-B bond of 1,2-oxaborolane,fluoride inducedhalogenation of 2-alkoxy-1,2-oxaborolane was found togive 3-halopropanol.
硼氢化甲基乙烯基酮和已烯得到的2-已基-5-甲基-1,2-氧硼杂环戊烷与〓反应,再经PCC氧化,分子内缩合得到二氢茉莉酮。1,2-氧硼杂环戊烷的C-B键除氧化断裂之外,也能够在〓或KF作用下卤化断裂成碳卤键。
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The biometallogenesis system of Jinya gold deposits consists of the following procedure: pre-concentration of gold and metallogenic matter in living organisms in Luodian-Danchi rift depositional basin; solution, absorption and concentration of metallogenic matter in organic matter and organic thermal fluid generated from organisms during lithogenesis; migration of gold and metallogenic matter in organic fluid from basin to Lingyun underwater carbonate platform and concentration at its boundary convex (palaeo-blind-mountain) during basin compaction ; metallization due to depth thermal fluid making organic fluid thermal degradation and forming new fluid which riches in gold and sulfur, and the fluid migrating upward and depositing in upside ore-controlling structures because of absorptions by organic carbon and atc.
通过研究金牙金矿作用的生物成矿系统内容为:在早、中三叠世罗甸—丹池裂谷盆地接受沉积时,生物对金等成矿物质就存在预富集作用;在成岩过程中,生物转化为有机质及有机热流体,对生物及沉积物中的金等成矿物质存在溶解、萃取、富集作用;在盆地压实成岩作用中,盆地中有机热流体向凌云水下碳酸盐台地运移,并在台地边缘外凸部位集中,此过程流体携带大量成矿物质,对金等成矿物质存在迁移集中作用;深部热流上侵使有机流体发生降解和释放金的热作用、形成高含金的有机热液,含金热液上移在构造通道中沉积并被有机碳再次吸附,最终形成金矿床,对金存在成矿作用。
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Two series of polyurethane acrylate grafted acrylic resins (Acr-g-TPU-PETA and Acr-gPPU-PETA) self-emulsifying systems are obtained by grafting -NCO group modified polyurethane acrylates with acrylic copolymer prepared from n-butyl acrylate, styrene,βhydroxyethyl methacrylate and acrylic acid The self-emulsifying systems showed Newtonian fluidity with viscosity closed to that of water, the solid contents were around 30% The T〓 of 15~4℃ for dried film before photocuring favored film formation at room temperature DSC and DMA results showed that PU-PETA is compatible with acrylic resin in the grafted resin The TG and dTG curves for Acr-g-PU-PETA samples were substantially different from the corresponding blends, and the brodened dTG peaks for photocured grafted resin suggest that there might be multiple interactions among chain segments The photocued film of the grafted resins self-emulsifying system exhibited good overall properties with polyurethane acrylate grafts ranging from 30% to 50%, and Acr-g-TPU-PETA series showed better properties than Acr-gPPU-PETA series The adhesion of the photocured film was 1~2 grade, impact strength was 50kg-cm and flexibility was 1mm The Shore hardness and the adhesion of the film decreased markedly if PETA was replaced by HEMA as photoactive group due to the lower C=C double bond content in the grafted resin The polyhydroxy amine-linked thioxanthones photoinitiators can be evenly dispersed in self-emulsifying system without color spot appearing in the dried film The films photocured with IV〓~IV〓 generally exhibited higher Shore hardness, gloss and solventresistance than that cured with Irgacure 2959 and did not induce the rusting of the iron substrate Pigmenting with titanium oxide had no effect on the photocuring The polyhydroxy amine-linked thioxanthone IV〓 and IV〓 can be new candidates for the formulation of titanium oxide pigmented photocurable water-borne coatings for their pale-yellow appearance and slight interference with the color of the coatings WB 4759 with high water-solubility coalesced and separated from the dried resin film, and even induced the rusting of iron substrate.
以丙烯酸丁酯,甲基丙烯酸-β-羟乙酯,丙烯酸及苯乙烯合成厂丙烯酸共聚树脂,并与含-NCO端基的聚氨酯丙烯酸酯接枝反应,经水性化后,得到两个系列(Acr-g-TPU-PETA和Acr-g-PPU-PETA)各5个不同配比的丙烯酸树脂接枝聚氨酯丙烯酸酯自乳化体系,粘度与水相近,为牛顿流体,固含量30%左右。光固化前干燥涂膜的玻璃化转变温度在-15℃~4℃之间,有利于室温下成膜。DSC及DMA谱表明两种树脂基本相容。Acr-g-PU-PETA的热失重行为明显不同于共混材料,接枝样dTG峰明显宽化,表明接枝样中链段之间的相互作刚有多重性,丙烯酸树脂与聚氨酯之间有一定的相容性。接枝树脂自乳化体系光固化涂层的综合性能以聚氨酯丙烯酸酯成分为50%~30%者相对较好,且以Acr-g-TPU-PETA系列更理想。光固化膜的附着力为1~2级,冲击强度为50kg·cm,柔软性多为1mm。以HEMA代替PETA作为接枝树脂的活性基团,碳—碳双键密度太低,光固化膜交联点太少,硬度和附着力均较差。多羟基胺连硫杂蒽酮光引发剂能均匀分散于树脂自乳化体系和接枝树脂干膜中,不出现色斑,光固化膜肖氏硬度一般高于以Irgacure 2959为光引发剂的光固化膜,光泽度及耐丁酮溶剂性能均有所提高,不会诱导铁基生锈,钛白着色对光固化结果几乎没有影响。本论文所合成的多羟基胺连硫杂蒽酮光引发剂IV〓与IV〓为浅黄色,对光固化涂层的颜色干扰较小,为配制钛白着色光固化水性涂料提供了新的光引发剂。水溶性太强的WB 4759在干膜中易聚结析出,且对所附着的铁基有诱导锈蚀作用。
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The Raman spectra of the deposited species did not exhibit thespectral feature of buckminsterfullerene, but the hexagonal graphite and the amorphouscarbon in 〓 hybridization instead. The deposited species were desorbed and mass analyzed.
7经质量选择后的直链碳原子簇沉积在HOPG单晶面后改变了其本身的构型,主要以纯碳簇的形成存在,另外也发现相当一部分碳聚集而成芳香环,由于环状构型存在较多悬挂键,氢原子起到了饱和悬挂键的作用。
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brightening agent:增白剂; 增艳剂; 增亮剂; 光亮剂(电镀)
brightening addition | 亮度增强剂carbanionadditions 阴碳离子加成作用 | brightening agent | 增白剂 增艳剂 增亮剂 光亮剂(电镀) | brightening impulse | 照明脉冲, 亮冲击
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incarcerated:钳闭的
incarbonization 成碳作用 | incarcerated 钳闭的 | incarcerateincarceration 幽闭
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must:葡萄汁
此时那些称为"葡萄汁"(MUST)的液体,转入一个发酵用的巨大容器里等待发酵,在葡萄汁内所含的天然糖份,经过酵酶菌的发酵作用,转化而成酒精及碳气,排去碳气后,新葡萄酒就产生了.
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zirconium dioxide:二氧化锆
作为电化学陶瓷反应器来说,在作为氧离子传导体的二氧化锆(Zirconium Dioxide)底板上形成了具有催化剂作用的陶瓷电极. 这种电极是把作为固态碳燃料催化剂的铝酸钙和作为NOx还原催化剂的氧化镍(Nickel Oxide)等物质与二氧化锆混合而成.
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carbanilic acid:苯氨基甲酸
carbamylcholine chloride 氨甲酰胆硷,卡巴可,氯化氨基甲酰胆碱 | carbanilic acid 苯氨基甲酸 | carbanion addition 阴碳离子加成作用
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carbanion addition:碳阴离子加成<作用>;碳阴离子加合<作用>
carbanion 碳阴离子 | carbanion addition 碳阴离子加成<作用>;碳阴离子加合<作用> | carbazole dye 咔唑染料
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carbanion addition:阴碳离子加成作用
binary addition 二进制加法 | carbanion addition 阴碳离子加成作用 | chain addition program 链加程序; 链式添加程序
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gluconeogenesis:糖(原)异生作用
3.节约蛋白质作用 当体内碳水化合物供给不足时,机体为了满足自身对葡萄糖的需要,则通过糖原异生作用(gluconeogenesis)产生葡萄糖. 由于脂肪一般不能转变成葡萄糖,所以主要动用体内蛋白质,甚至是器官中的蛋白质,如肌肉、肝、肾、心脏中的蛋白质,