- 更多网络例句与壳聚糖相关的网络例句 [注:此内容来源于网络,仅供参考]
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The results showed that the N atom in amidogen of CTS coordinates with Cd in the coordination compounds of Cd-CTS,while in the coordination com...
结果表明:在壳聚糖-Cd配合物中的配位原子是壳聚糖—NH2上的N原子,而在壳聚糖-Ce、壳聚糖-Zr、壳聚糖-Pb配合物中不仅壳聚糖—NH2上的N原子参与了配位,同时OH上的O原子也参与了配位。
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CA-CTSs including N,O-carboxymethyl chitosan,N,O-1-carboxyethyl chitosan (N,O-1-CEC),N,O-2-carboxyethyl chltosan(N,O-2-CEC),N-carboxymethyl chitosan and N-1-carboxyethyl chitosan(N-1-CEC) are quaternized using active quaternary salts prepared in laboratory.5 series including 25 kinds amphoteric chitosans characterized with polymeric ampholyte,in which 24 kinds are synthesized firstly,are obtained, 2-Hydroxypropyl dimethylbenzyl ammonium N,O-(1-carboxyethyl) chitosan chloride (GDMBA-N,O-1-CEC) is hydrolyzed into serial low molecular weight GDMBA-N, O-1-CEC with acid as catalyst and microwave as assistant instrumentality innovately.
以合成的活性季铵盐改性了N,O-羧甲基壳聚糖、N,O-1-羧乙基壳聚糖(N,O-1-CEC)、N,O-2-羧乙基壳聚糖(N,O-2-CEC)、N-羧甲基壳聚糖和N-1-羧乙基壳聚糖(N-1-CEC)等羧烷基壳聚糖,得到5个系列25种具有两性高分子电解质特征的新季铵化羧烷基壳聚糖,其中24种为首次合成;创新提出以微波辅助酸催化的方法催化2-羟丙基二甲基苄基-N,O-(1-羧乙基)壳聚糖氯化铵(GDMBA-N,O-1-CEC)水解,得到了低分子量的GDMBA-N,O-1-CEC。
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Themain contents of this dissertation are as follows:(1) The quality analytiedal results of chitosan are as follows: water for 15.205%;degree of deacetylation 92.671%; the weight average relative molecular weight ofchitosan 195900; the viscosity average relative molecular weight of chitosan 194100;and the decomposing temperature 298℃. The infrared ray IR spectra of chitosanshows that the feature-absorbing band of chitosan amido was 1601cm~(-1), that ofβ-indican bond was 986cm~(-1). The results of the X-ray diffraction of chitosan indicatesthat its degree of deacetylation and degree of crystal are both big.
本文的主要内容如下:(1)对壳聚糖的质量进行分析,其水份为15.205%,脱乙酰度为92.671%,重均分子量为195900,黏均分子量为194100,分解温度为298℃,壳聚糖的红外光谱表明,壳聚糖—NH_2的特征吸收峰为1601cm~(-1),β-糖苷键的特征吸收峰为986cm~(-1),壳聚糖的X-衍射图表明壳聚糖原料的脱乙酰度和结晶度均较大。
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Coordination compounds of chistosan with Ce,Zr,Pb and Cd were prepared,which were synthesized by the reaction of CTS with cerium nitrate,zirconium nitrate,cadmium sulfate,and lead nitrate in acid systems.
用壳聚糖分别与硝酸亚铈,硝酸锆,硫酸镉和硝酸铅在酸性介质中反应,制备了壳聚糖-Ce、壳聚糖-Zr、壳聚糖-Cd、壳聚糖-Pb四种壳聚糖-重金属离子配合物。
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The analysis of 1H NMR showed that the succinyl group was successfully conjugated to the amino group of chitosan molecule, and the degree of substitution of Suc-Chi values increased with increasing succinic anhydride/amino mole ratio or reducing the molecular weight of chitosan.
利用壳聚糖和琥珀酰酐反应合成了N-琥珀酰壳聚糖,1H NMR分析表明通过反应可在壳聚糖的侧氨基引入亲水性的羧基,增加琥珀酰酐/氨基的摩尔投料比或者选择分子质量较小的壳聚糖,有利于提高N-琥珀酰壳聚糖的琥珀酰化度。
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The specific properties of materials, such as the palate adhesion, dynamic cruor, anti-bacterial and the degradability of lysozyme, were studied, which provide valuable data for further application. The main creative ideas are listed as follows:(1) The water-retention chitosan/poly vinyl alcohol blend fiber was obtained by coagulating in 10% NaOH/ethanol solution, and the blend and crosslink due to GA can enhance the mechanical properties of fiber;(2) The controlled degradable chitosan/gelatin blend fiber was obtained by solution filature, and the mechanical properties were improved;(3) The N-acylchitosan with the different degree of substitution were successfully prepared, and the relationship between structure and properties was estabilished;(4) By a new solvent system of 6% NaOH/4% urea for cellulose, the blood anti-coagulant function films were prepared by blending cellulose with chitin;(5) In the same solvent system above mentioned, the anti-bacterial blend films based on cellulose and carboxymethyl-chitosan were prepared, and the relationship of DS and the anti-bacterial property was concluded;(6) The controlled degradable chitosan films was obtained by the chemical crosslink.
本论文的主要创新点:(1)以NaOH水溶液/无水乙醇为凝固液,采用溶液纺丝法制备出保水性壳聚糖/聚乙烯醇纤维,共混和戊二醛交联极大提高了壳聚糖纤维力学性能;(2)用壳聚糖和明胶共混,以溶液纺丝法制备出可控降解的壳聚糖/明胶纤维,并大幅度提高了壳聚糖共混纤维的干、湿态抗张强度;(3)确立了不同取代度N-酰基壳聚糖的合成方法及其膜的结构与性能的关系;(4)利用纤维素新溶剂6%NaOH/4%尿素制备出抗凝血性纤维素/甲壳素共混膜;(5)利用上述纤维素新溶剂制备出抗菌性纤维素/羧甲基壳聚糖共混膜,揭示了羧甲基壳聚糖取代度与抗菌性能的关系;(6)制备出可控降解壳聚糖交联膜。
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The results show that a little amount of heteropolymolybdovanadophosphate can remarkably speed the degradation, the best conditions of the oxidative degradation of chitosan with hydrogen peroxide catalized by heteropolymolybdovanadophosphate in homogeneous condition are as follows: the ratio of catalyst and chitosan is 1 to 10, concentration of hydrogen peroxide is 0.15%, the temperature is 80℃, reaction time is 2h. 0.2g chitosan was degraded under the best condition and the molecular weight by viscometry was degraded from 1460000 to 7812. then water-soluble chitosan was obtained by this method; The heterogeneous method is a high efficient way, the best condition of this method are as follows: the ratio of catalyst and chitosan is 2 to 100, the volume of 30% hydrogen peroxide is about 3mL, the temperature is 90℃, reaction time is 5min~30min.
研究结果表明,适量磷钼钒的存在可显著加速壳聚糖的降解,磷钼钒催化过氧化氢均相氧化降解壳聚糖的适宜反应条件是:催化剂与壳聚糖的质量比为1∶10、过氧化氢百分浓度为0.15%、反应温度为80℃、反应时间为2h,在此条件下对0.2g溶解在100 mL 0.5%稀醋酸中的壳聚糖进行降解,可使壳聚糖的粘均分子量由原来的146万下降到七千多(7812),成为水溶性低分子量壳聚糖,从而达到应用的要求;在异相条件下以磷钼钒为催化剂催化过氧化氢氧化降解壳聚糖是一种高效快速的方法,此法降解壳聚糖的最佳反应条件是:催化剂与壳聚糖的质量比为2∶100;30%过氧化氢的用量为3mL左右;反应温度为90℃、反应时间为5min~30min。
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objective:with the local lobster shell as the raw material,we inquire into the abstraction and preparation of chitin and chitosan to develop a new raw material resources for chitosan.methods:use methods such as take off protein,calcium,colour,deacetylate and purification to prepare chitosan to study deacetylate degree,molecular weight and other characters of chitosan,then compare with infrared spectrum of bio-chemical chitosan on market.results:the chitin and chitosan obtained from lobster shell are 14.8% and 8.9%, respectively.
目的:以地产龙虾壳为原料,探讨其甲壳素的提取和壳聚糖的制备方法,以开发壳聚糖制备的新原料资源。方法:用脱蛋白、除钙、脱色、脱乙酰基、纯化等方法制备壳聚糖,研究其壳聚糖的脱乙酰度、分子量等性质,并与市售生化级壳聚糖的红外光谱进行比较。
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Chitosan had been modified by polyacrylate sodium, glularaldehyde, and NaBH4, respectively, which afforded three kinds modified chitosan: polyacrylate sodium modified chitosan (CIS- PA4) chitosan bead and pentamethylene diamido crosslinked chitosan bead (CTSB- G- Hy). The adsorption properties of CTS-CTSB and CTSB-G-Hy were studied by L25(56) orthogonal experimental design. They show high adsorption activities for Pb2+ in solution. The highest removal efficiency of Pb2+ for CTS-PA4, CTSB and CTSB-G-Hy is 94%, 96% and 93%, respectively. The results showed the adsorption property of CTSB is the highest. The CTSB- G- Hy has good mechanical property, acid-resistance and alkali-resistance.
第二部分壳聚糖的改性及其对水溶液中铅离子的吸附性能研究以壳聚糖为原料制备了三种改性吸附剂——聚丙烯酸钠改性壳聚糖(CTS——PA_4)、珠状壳聚糖凝胶树脂和戊二氨交联珠状壳聚糖凝胶树脂,着重考察了CTSB—G—Hy的制备条件,并考察了三种吸附剂吸附6.3mg/L铅离子水溶液中铅的最佳使用条件,结果表明对CTS—PA_4而言当pb~(2+)溶液的pH在4~6.5之间,吸附剂用量为5g/L,吸附时间为1h时pb~(2+)去除率高于94%,CTS—PA_4可在酸性条件下使用,在碱性条件下依然有效但处理效果较差;CTSB对pb~(2+)具有很好的吸附能力吸附剂用量为5g/L,吸附时间为1h时处理效果极佳,pb~(2+)去除率高于96%;CTSB—G—Hy对pb~(2+)具有一定的吸附能力,吸附剂用量为3g/L,吸附时间为1.5h时处理效果最佳,Pb~(2+)去除率高于93%,而且CTSB—G—Hy的机械强度高,耐酸碱性强,可在较宽的pH范围内使用。
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Its high-capacity and strong-acid-resistance were proved. In the acid condition, the adsorption efficiency to acide green 6B and direct fast yellow RL reached above 90%. Through the adsorption rate curve on adsorption behavior of the three dyes, they were all according with pseudo-secondary adsorption rate curve. The rate constant of adsorption increased with increasing temperature. Through the adsorption isotherm of the three dyes, acide green 6B and direct fast yellow RL were according with Langmuir equation, while disperse blue 56 was according with Freundlich equation. The adsorption behavior was an endothermic process. Entropy was increasing during the adsorption. So raising temperature was in favor of adsorption.
结果表明,甲醛环氧氯丙烷交联壳聚糖对染料具有较强的吸附性能和耐酸性能,在酸性条件下,对酸性绿6B和直接耐晒黄RL的吸附效率达90%以上;拟合甲醛环氧氯丙烷交联壳聚糖对三种染料的吸附速率曲线,发现该吸附行为符合拟二级吸附速率曲线,其吸附速率常数随温度的升高而增大;通过测定不同温度下甲醛环氧氯丙烷交联壳聚糖吸附三种染料的吸附等温线表明,甲醛环氧氯丙烷交联壳聚糖对酸性绿6B和直接耐晒黄RL的吸附符合Langmuir方程,而对分散蓝56的吸附符合Freundlich方程,甲醛环氧氯丙烷交联壳聚糖对染料的吸附是一个吸热过程,吸附后体系熵增加,升温有利于吸附。
- 更多网络解释与壳聚糖相关的网络解释 [注:此内容来源于网络,仅供参考]
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Chitose:甲壳糖 壳糖
chitonitis 包膜炎 | chitosan 壳聚糖 甲壳质 几丁聚糖 脱乙酰壳多糖 | chitose 甲壳糖 壳糖
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APIO CLUB INC:环保产品、环保原料、壳聚糖制品
DAIHO CO.,LTD针织服装 | APIO CLUB INC环保产品、环保原料、壳聚糖制品 | TOHO TRADING CO.,LTD小汽车附件
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chitosamine:壳糖胺
chitinase 壳质酶 | chitosamine 壳糖胺 | chitosan 壳聚糖
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chitosamine:壳糖胺;氨基葡糖;葡糖胺
chitodextrin壳糊精 | chitosamine壳糖胺;氨基葡糖;葡糖胺 | chitosan壳聚糖
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chitosan:壳聚糖
充聚糖(chitosan)是一种由甲壳素脱乙酰基后的产物. 鉴于壳聚糖及其衍生物具有优良的生理活性和功能保健作用. 在食品,医药方面显示出非常诱人的应用价值,近年来在国内外对甲壳素以及完聚糖的开发研究十分活跃. 生产经营脱乙酰甲壳素(壳聚糖)(Chitosan)的是:宁波天然生物制品有限公司;宁波天缘生化厂
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chitosan gum:壳聚糖胶
chitin 壳多糖 | chitosan gum 壳聚糖胶 | chitosan 脱乙酰壳多糖
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chitosan rod:壳聚糖棒材
挤出螺杆:Extruding spiral rod | 壳聚糖棒材:chitosan rod | 抽油杆:oil sucker rod
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chitosan derivatives:壳聚糖
衍生产品:Derivatives | 壳聚糖:chitosan derivatives | 合成:diphenylmethyl piperazine derivatives
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shell polyose:壳聚糖
壳资源:shell resource | 壳聚糖:shell polyose | 曲壳:Shell Deformable adaptive
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Trichoderma sp:木霉
该文研究了该实验室培养的纤维素酶、木霉(Trichoderma sp)所产壳聚糖酶和混合蛋白酶对壳聚糖熔液的酶解条件和效果进行综合评价. 结果表明,该文所产壳聚糖酶对壳聚糖水解效果较差,混合蛋白酶水解速度最慢,纤维素酶的综合性能优良,