英语人>词典>汉英 : 喹喔啉基 的英文翻译,例句
喹喔啉基 的英文翻译、例句

喹喔啉基

基本解释 (translations)
quinoxalyl  ·  quinoxalinyl

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A serial of novel thiophene-based main chain conjugated compound with varieties of aromatic rings and heterocycle, such as acenaphtenequinoxaline phenanthrenequinoxaline ,have been synthesized on the base of looking for lots of references and summarized others research work.

在查阅大量文献和综合前人所作工作的基础上,我们选择卤代芳烃与Sn金属有机试剂在Pd催化下合成了以萘基喹喔啉和菲基喹喔啉为主的一系列噻吩与杂环构成的交叉共轭化合物。

Because of fluoride substitutions and quinoxaline structures, two new compounds are electron deficient. With alkyl substituted fluorenes, the two new compounds both have good solubility.

新的化合物因为含有氟取代基和喹喔啉结构使得整个分子呈缺电子状态,同时烷基取代的芴使得材料具有良好的溶解性。

Methods Using 4-chloro-2-nitroaniline as a starting compound, followed by substitution, reductive cyclization, oxidation, and chlorination, to give the key intermediate 2,7-dichloroquinoxaline (7), which reacted with different phenolic compounds to afford quinoxaline derivatives.

方法以4氯2硝基苯胺为起始原料经取代、还原关环、氧化、和氯代合成了中间体2,7二氯喹喔啉(7),再在喹喔啉的2位引入不同的取代酚结构单元,合成了一系列共9个新喹喔啉衍生物。

We focused the study on the synthesis methods of quinoxaline, nitration of its aromatic ring and chlorination of its heterocycle. In this paper, we thought about environmental protection, the cost of material, the feasibility of industrialization, workup easily, and obtained 2,3(1H,4H)-quinoxalinedion, 6-nitro-2,3(1H,4H)-quinoxalinedion, 6,7-dinitro-2,3(1H,4H)–quinoxalinedion, 2,3-dichlo- roquinoxaline, 6–nitro-2,3-dichloroquinoxaline,and 6,7- initro-2,3-dichloro-quinoxaline. A more reasonable, easily, efficient and simple reactive route to synthesize above-mentioned compounds was developed by systematically investigating the yield, the purity and physical character of intermediates.

本文针对喹喔啉及其芳环硝化、杂环氯代的合成进行研究,主要考虑了环保性、原料成本、产业化的可行性、反应操作的简便性等问题,获得了2,3(1H,4H)-喹喔啉二酮、6-硝基-2,3(1H,4H)-喹喔啉二酮、6,7-二硝基-2,3(1H,4H)-喹喔啉二酮、2,3-二氯喹喔啉、6-硝基-2,3-二氯喹喔啉和6,7-二硝基-2,3-二氯喹喔啉等六个中间体,考察了反应产物的产率、纯度和性状等因素,得到了更为合理、方便、实用、简洁的可供产业化的合成路线。

Benzyloxy benzoyldimethylsulfoxide was prepared by the reaction of ethyl 4-benzyloxybenzoate and dimethyl sulfoxide in the presence of sodium hydride, followed by Pummerer reaction with concentrated hydrochloric acid to afford eo-hydroxy-co-thio-methyl-(4/-benzyloxy) acetophenone, which reacted with urea, thiosemicarbazide, semicarbazide hydrochloride and o-phenylenediamine to give imidazolidine-2,4-dione, l,2,4-triazine-3- one and quinoxaline derivatives, respectively.

本文用4-苄氧基苯甲酸乙酯和二甲亚砜为原料,在氢化钠存在下反应,合成了(4′-苄氧基)-苯甲酰基-二甲亚砜。研究了该亚砜在浓盐酸的存在下发生的Pummerer重排反应,用重排产物ω-羟基-ω-甲硫基-(4′-苄氧基)-苯乙酮分别与尿素、氨基脲、氨基硫脲和邻苯二胺反应合成了2,4-咪唑啉-二酮、1,2,4-三嗪-3-酮、喹喔啉等含氮杂环化合物。