- 更多网络例句与吖啶相关的网络例句 [注:此内容来源于网络,仅供参考]
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The addition of F-/AcO- to 2 was further confirmed by monitoring the changes in its 1H NMR spectra in the presence of either F- or AcO-(Figure 3). Four peaks of acridinium of 2 showed pronounced upfield shifts due to the conversion of acridinium to acridane in 5 equiv of either F-(Figure 3b) or AcO-(Figure 3c).
F-/AcO-添加到2中通过监测其在存在F-或AcO-时H NMR谱的变化进一步得到确认(图3)。2的吖啶盐的四个峰值证明了由于在5个当量F-(图3b)或AcO-(图3c)中吖啶盐转化成吖啶而引起的明显的高场位移。
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The disappearance of the three characteristic absorption peaks corresponding to the acridinium salts and the newly formed peaks at 280 nm for 1 and 288 nm for 2 strongly suggested transformation of the acridinium moiety into the corresponding acridane via anionic addition to the C9 position of the former (Figure 2b).
与吖啶盐相应的三个特性吸收峰的消失以及新形成的峰值(1为280nm,2为288nm),强烈表明了吖啶盐分子部分通过阴离子加入到前者的C9位置而转化成了相应的吖啶(图2b)。
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These chemical shifts in the aromatic region of the resulting nucleophilic adduct 2-F were consistent with the counterparts of 9,10-dihydro-9-methoxy-9-(4-methoxyphenyl)-10-methylacridine, 17b which was proven to be the adduct of the 9-phenyl acridinium salt formed with an excess of MeOH (Figure S7 in Supporting Information).
在最终的亲核加成化合物2-F的芳香族区中的这些化学位移与9,10二氢-9-甲氧基-9-(4甲氧基苯基)-10-甲基吖啶的对应物是一致的,17b 这被证明是与过量的MeOH形成的9-苯基吖啶盐的加成化合物(支持信息中的图S7)。
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N butyl 2 ethoxy thioacridone ; acridone ; electron transfer ; fluorescence
N-丁基-2-乙氧基硫代吖啶酮;吖啶酮;电子转移;荧光
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The results showed that upon Xe lamp irradiation,N butyl 2 ethoxy thioacridone was transformed into corresponding acridone and the presence of the lattter was confirmed by UV visible absorbtion spectrum and mass spectrum.
结果表明:在Xe灯光照下,N 丁基 2 乙氧基硫代吖啶酮转变成了相应的吖啶酮,用紫外可见光谱和质谱证实了吖啶酮的存在;生成的吖啶酮可被二苯基碘盐猝灭,它们之间的荧光猝灭遵循电子转移的反应机理。
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Acridone 1 reacted with benzyl chlorides 2 in NaH/DMF/KI to give 10-benzyl-9-acridones 3 in high yields. Subsequent reduction of 3 with NaBH4 gave 10-benzy1-9,10-dihydroacridine derivatives 4 with yields of 88%~96%.
吖啶酮1与氯化苄及其衍生物2在氢化钠/N,N-二甲基甲酰胺/碘化钾中反应高产率生成10-苄基吖啶酮类化合物3; 3经硼氢化钠氢化还原生成10-苄基-9,10-二氢吖啶类化合物4,产率88%~96%。
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Aniline compounds are used as raw material and reacted with anthranilic acid and then phenyl iodide as alkylating agents to give alkylating products followed by cyclizing with concentrated sulphuric acid to give a N-phenyl-acridone(or 3-ethoxyl-N-phenylacridone).The structure of intermediate and target compound are determined by IR and MS.
以苯胺类化合物为原料,先后以邻氯苯甲酸和碘苯为烷基化试剂进行了N 烷基化反应,再用浓硫酸使其环化制得N-苯基吖啶酮和3-乙氧基-N-苯基吖啶酮,并用红外光谱及质谱仪检测了各中间体及目标产物的结构。
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Mol/L. 3 A study on the ECL of acridinum esters including 10--acridinium-9-carboxyl-phenyl-ester iodinate and 10-methyl-9-(p-formylphenyl)-acrdiniumfluorosulphonate in neutral solution was carried out. It was found both CACPEI and MFPA give strong ECL in KNO〓 solution when an appropriate voltage was applied on Pt electrode.
本文研究了碘化10-乙羧基吖啶-9-羧酸苯酯和对甲酰基苯基-10-甲基吖啶-9-羧酸酯氟磺酸盐的ECL行为,发现在中性KNO〓介质中,这两种吖啶酯都能在一定的电位下产生很强的ECL信号,考察了各种影响因素,确定了发光的最佳条件,探讨了可能的发光机理。
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Two new kind of energy transfer donor-acceptor dyads consisting of α-naphthoic acid moiety and 9-aminoacridine units linked by tetraethylene glycol or triethylene glycol flexible chain have been synthesized.
本工作分别用聚三乙二醇及聚四乙二醇柔性链将α-萘甲酸酯与9-氨基吖啶连接起来,合成了两种新型二元发色团分子体系,在两个体系中,选择激发α-萘甲酸酯,都可以发生从α-萘甲酸酯到9-氨基吖啶的高效率的单重态-单重态能量传递。
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The largest chemical shifts were observed for the proton 1.48 ppm adjacent to the central pyridinium ring and para-protons 1.47 ppm with respect to the nitrogen of pyridinium.
在最终的亲核加成化合物2-F的芳香族区中的这些化学位移与9,10二氢-9-甲氧基-9-(4甲氧基苯基)-10-甲基吖啶的对应物是一致的,17b 这被证明是与过量的MeOH形成的9-苯基吖啶盐的加成化合物(支持信息中的图S7)。
- 更多网络解释与吖啶相关的网络解释 [注:此内容来源于网络,仅供参考]
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acridine dye:吖啶染料
acridine 吖啶 | acridine dye 吖啶染料 | acridine orange 吖啶橙
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acridine dye:吖啶燃料
acridine alkaloid吖啶(类)生物碱 | acridine dye吖啶燃料 | acridine orange吖啶橙
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acridine yellow:吖啶黄
acridine orange吖啶橙 | acridine yellow吖啶黄 | acriflavine吖啶黄素
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acridine alkaloid:吖啶(类)生物碱
acridine吖啶 | acridine alkaloid吖啶(类)生物碱 | acridine dye吖啶燃料
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Acriflavine Hvdrochoride:吖啶黄[消毒防腐药]
Acridorex 吖啶雷司[食欲抑制药] | Acriflavine Hvdrochoride 吖啶黄[消毒防腐药] | Acriflavinium Chloride 吖啶黄[消毒防腐药]
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acriflavine neutral:吖啶黄素中性品
吖啶黄素 acriflavine | 吖啶黄素中性品 acriflavine neutral | 吖啶偶氮酚 naphthol AS-LB
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Acriflavine Hvdrochoride;Acriflavinum Chloride;Euflavine:吖啶黄
吖啶黄 Acriflavine Hvdrochoride;Acriflavinum Chloride;Euflavine | 吖啶雷司 Acridorex | 吖啶琐辛 Acrisorcin
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acridic acid;acridine acid:吖啶酸
吖啶染料 acridine dye | 吖啶酸 acridic acid;acridine acid | 吖啶琐辛 acrisorcin
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acridinic acid:吖啶酸
acridine yellow 吖啶黄 | acridinic acid 吖啶酸 | acriflavinium chloride 吖啶黄
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acridinic acid; 2,3-quinolinedicarboxylic acid:吖啶衍酸;2,3-喹啉二甲酸
吖啶衍酸;2,3-喹啉二甲酸 acridinic acid; 2,3-quinolinedicarboxylic acid | 吖啶酮 acridone | 吖啶黄素 acriflavine