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The main object of this research is to investigate synthesis of Cu23Cl Cu and CuO nanoparticles through electrospinning and heat-treated method The research is mainly focused on preparative parameter and the change of heat-treated temperature to form the nanoparticles inlaid in silicon fibers the shape and color change are dicussed First of all to prepare the Polyvinyl butyral and silica dioxide complex nanofiber by electrospinning and then to investigate different heat-treated temperature and reactive time to being an influence on the products The results detected by SEM XRD TEM EDS FTIR combined sol-gel process and electrospinning can prepare Polyvinyl butyral and silica complex nanofiber The experimental result is found when heat-treated temperature is 100~4750C it can produce Cu23Cl nanoparticles; Above 4750C~ 4900C it can produce Cu nanoparticles; Above 450~7000C it can produce CuO nanoparticles And the viscosity is lain between 20~40cp and the sol-gel process time is 3hr it can produce the thinner fibers The average diameter of the fibers are 107 88±21 01nm;Due to the nanoparticles inlaid in the silica fibers the thinner fibers can be inlaid the smaller nanoparticles so this is the result that the experiment is expected To calcine the complex fibers is to produce surface silica fibers contain Cu23Cl Cu and CuO nanoparticles due to surface plasma resonance it make the color of the fibers become yellowish green from light white green turn into the red nuclear finally As the experimental result to utilize sol-gel process combine electrospinning can produce porous silica fibers contain Cu23Cl Cu and CuO nanoparticles
本研究旨在探讨「利用放电纺丝和热处理法来合成Cu23Cl、Cu和CuO奈米粒」之研究,实验著重在制备参数与热处理温度变化对所形成的奈米粒镶嵌在二氧化矽纤维中的形态与颜色变化探讨。首先,利用放电纺丝法制备出聚乙烯醇缩丁醛及二氧化矽之奈米纤维,比较不同的热处理温度与反应时间的改变对产物生成产生影响,进而研究不同热处理温度和时间对生成奈米粒的影响。产物经由SEM、XRD、TEM、EDS和FTIR等仪器分析结果显示,结合溶胶-凝胶法(sol-gel process)和放电纺丝法可产生聚乙烯醇缩丁醛及二氧化矽复合奈米纤维。实验结果发现,若热处理温度在100~4750C下可得到Cu23Cl奈米粒,475~4900C 可得Cu奈米粒,450~7000C以上可得 CuO奈米粒。而黏度介於20~40cp间和溶胶-凝胶时间为3hr时,可产生直径比较细的纤维,纤维直径为107 88±21 01nm;且由於奈米金属颗粒镶嵌在二氧化矽纤维中,直径比较细的纤维,可以得到比较小的奈米金属颗粒,这与实验预期相符。而锻烧此复合物产生多孔的二氧化矽纤维并包含Cu23Cl、Cu和CuO奈米微粒时,由於表面电浆子共震关系,而使纤维颜色由淡白黄绿色变成黄绿色,再变红褐色。由实验结果得知,利用溶胶-凝胶法(sol-gel process)结合放电纺丝法和不同热处理温度,可产生Cu23Cl、Cu和CuO奈米粒镶嵌在二氧化矽纤维。
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In the last chapter, on the basis of theories in paper [4, 5], the notions of strong mixing, weak mixing, generator and expansion of the variable-parametric dynamical system are introduced, it turns out that in variable-parametric dynamical system strong mixing implies weak mixing and then implies transitivity; it is proved that if and both are variable-parametric dynamical system, F conjugates with G , the members of F are communicate with each other and the members of G are also communicate with each other, what's more, they are both homeomorphism, then F is strong mixing implies G has the same properties; futhermore, we prove that F is strong mixing implies F Devaney chaos in the sense of modification in variable-parametric dynamical system and that F Devaney chaos in the sense of modification if and only if G Devaney chaos in the sense of modification when semi-conjugate with and they both are communicate and homeomorphism; at last, we illustrate that F has generator if and only if it has weak generator, and we also prove that if F is expansion, then F has generator.
在第三章中,我们在文[4,5]的基础上,提出了变参数动力系统拓扑强混合、拓扑弱混合以及变参数动力系统的生成子、扩张的概念;证明了变参数动力系统拓扑强混合蕴含拓扑弱混合,进而蕴含拓扑传递;证明了:如果,为两个变参数动力系统,F与G拓扑半共轭,且F两两可交换,G两两可交换,它们均为同胚映射,那么F拓扑强混合,则G也有同样的性质;本章还证明了变参数动力系统拓扑强混合蕴含F在修改的意义下Devaney混沌;在此基础上得出了:如果变参数动力系统与变参数动力系统拓扑半共轭,它们都两两可交换,并且它们均为同胚映射,那么F在修改的意义下Devaney混沌当且仅当G在修改的意义下Devaney混沌;得出了F有生成子当且仅当F有弱生成子;如果F是扩张的,则F有生成子。
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The second chapter analyzed its phylogeny, contrasted and classified the conformation in terms of the ancient period of external and internal and the modern times. The third chapter concluded the mainstream trend of transformation in contemporary days and sum up the character. Proceed with the basic patterns, the fourth chapter discussed the skills and technique of entrance space design concretely and practically. From the point of environment theory, the last chapter studied its meaning and function to surrounding quality, further advanced the ingression from a architectural element to a broad conception in city design.Combined with excellent examples of famous architect home and abroad, this thesis push forward its research to the skills and techniques of entrance space design.
全文共分五章,第一章阐述开展研究的背景,界定相关概念,提出研究方法与意义;第二章对于入口的沿革历程进行研究,并按外国古代建筑时期、中国古代建筑时期以及近现代建筑时期的分类方式对入口空间形态的发展衍变进行分析与对比;第三章对当代主流建筑现象进行分析,总结其特征,从类型学的角度分析其界定原型,从纷繁芜杂的建筑现象中归纳出当代建筑入口空间形态的发展变化趋势;第四章从入口形态的基本模式入手,具体而实际的探讨了入口形态的设计手法与技巧;第五章从建筑环境理论的角度,将入口空间这一建筑构成语素提升到城市设计领域,研究了其对于城市环境品质的作用与意义,以期在具体实践过程中激发设计者拓宽思路,创造宜人的可持续发展的环境。
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NH4+ when heated with sodium hydroxide solution, a colorless gas is given out which can turn wet red litmus paper to blue.
铵盐和氢氧化钠溶液共热时会放出一种无色气体,它可把湿的红色石蕊试纸变蓝。
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The results show that AREEC liquid crystal enables the flow behavior of PC to change from quasi-Newtonian type to pseudo-plastic type, and it can act as heterogeneous nuclei to accelerate greatly crystallization of PET, and then to improve evidently their injection moldability.
将AREEC液晶与PC、PET熔体共混,研究了共混体系的流变行为、结晶特性和可模塑性,证明AREEC液晶能使PC流变行为由准牛顿型变为假塑性幂律型,能对PET起异相成核和显著加速结晶作用,从而大大改善它们的注塑可塑模性。
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According to the characteristics that Trypanosome can produce different variations, 5 New Zealand rabbits were infected in sequence with a monoclonal strain of Trypanosome evansi isolated from Yunnan buffalo. 50 monoclonal strains were isolated and showed by indirect immune fluorescent test that the first parasitemia peak of variation in following 4 rabbits exist in 9 predominant variations of first rabbit. The 50 variations subordinate to 20 antigen types.
根据锥虫在兔体内可产生不同变异体的特性,将伊氏锥虫云南水牛单克隆株顺序感染五只新西兰大白兔,分离到 50 个单克隆群体,经间接免疫荧光实验证明:后四只兔子出现第一次虫血症高峰的变异体,均包含在第一只兔体内分离得到的 9个优势变异体之内;这 50 个变异体分属于 20 个抗原型,即共分离到 20 个优势变异体。
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The plastic deformation induced due to cyclic rotation of principal stress axes alone can be in the same magnitude as that due to shear with fixed principal stress axes. 2 The volumetric strain due to shearing of cyclic rotation of principal stress axes is found to be composed of a reversible dilatancy component and an irreversible dilatancy component. The former is characterized by its reversibility and is independent of past shear history, the latter by its irreversibility increases with the increase of cycle number yet its increase rate decreases with its accumulation. 3 The obvious non-coaxiality between directions of the principal stresses and principal strain increments is found and its degree depends largely on the change of shear stress component. 4 The intermediate principal stress has considerable effects on the deformation behavior of sands in the condition of cyclic rotation of principal stress axes. The accumulation rate of the irreversible dilatancy component increases with the increase of the intermediate principal stress parameter.
具有初始各向异性的砂土在纯应力主轴循环旋转排水条件下的主要变形规律为:①纯应力主轴循环旋转可产生与应力主轴固定单调剪切处于同一数量级的塑性变形;②纯应力主轴循环旋转引起的剪切体变包含可逆性剪切体变分量和不可逆性剪切体变分量两部分,其中可逆性剪切体变分量在一周内可完全恢复,基本与应力历史无关;不可逆性剪切体变分量随循环周数的增加呈单调增加,且增加速率随其自身累积值的增大呈减小趋势;③应变增量主轴与应力主轴之间的非共轴现象显著,且在一周内具有分段性;④中主应力对应力主轴循环旋转条件下砂土的变形特性有重要影响,不可逆性剪切体变分量的累积速率随中主应力系数的增加而增加。
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Specifically, itcontains 8 chapters.In chapter 1, the formation, structures, properties and the futureprospect of liposome were thoroughly reviewed;In chapter 2, the stibility and permeability of phopholipid -eleostericacid liposome were studied together with the effect of polymerizationof eleostearic acid. This membrane system was very sensitive to 〓,the effect of 〓 was clarified to increase the aggregation/fusion ofliposomes and made the permeability of mixed liposomes much higher;In chapter 3, two polymerizable conjugated diyne bolaamphiphiles were synthesized. They could form very stable mixed liposome, andthe diyne could be polymerized by UV light in bilayer liposomes, as aresult, the stability of mixed liposome against solvent or surfactantafter polymerization were enhanced. In chapter 4, two kinds of amphiphilic amino acids were synthesized andstable liposomes were formed therefrom After the condensationpolymerization of amino acid in bilayer liposomes, stable polypeptide liposomes were obtained, which had lower phase transition temperatureand higher permeability.In chapter 5, four kinds of glycolipids were synthesized and theiraggregation behavior in water was comparied. When incorporated intophospholipid bilayer membranes, they could increase the phase transitiontemperatures and inhibit the aggregation and fusion of mixedliposomesat lower temperature.In chapter 6 and 7, three kinds of steroidal bolaamphiphiles withdifferent chain lengths were synthesized. Incorporation of steroidalmoiety to the center of lipid bilayer membrane obviously increased themobility of lipid membrane and shifted Tc to lower temperature side incomparasion with cholesterol. The bolaamphiphile which was shorter thanthe hosted lipid bilayer membrane thickness influenced the lipid packingmore obviously.
全文共分8章:第一章对脂质体的形成、结构、性质及展望进行了较为详细的文献综述;第二章研究了磷脂-桐酸脂质体的稳定性,通透能力及桐酸的聚合对这些性质的影响;磷脂-桐酸混合脂质体为一类对〓灵敏的脂质体,〓的作用首先是使脂质体集聚然后使脂质体融合,并加速内包荧光物的释放;第三章通过合成两种可聚合共轭双炔双极性双亲分子DDCA,DDOL,研究了共双炔分子在双分子层脂质体膜上的聚合及对脂质体性质的影响,聚合可以提高脂质体相对于溶剂及表面活性剂的稳定性;第四章合成了两类氨基酸为极性基团的双亲分子,它们均可以在超声下形成稳定的脂质体结构;氨基酸基团可以在脂质体上进行缩聚反应,若聚合后脂质体表面仍有足够的亲水能力,则可得到稳定的多肽型脂质体;聚合后脂质体的相变温度降低,通透能力增加;第五章合成了四种亲水基团为单糖基的双亲分子GL-l,GL-2,GL-3, GL-4,研究了它们在水中的分散情况、集合体形态与分子结构的关系;在DMPC双分子层膜中加入糖脂分子可以使脂质体的相变温度提高,阻止脂质体在低温放置时的集聚与融合;第六章-第七章合成了三种不同碳链长度的双极性含胆甾环双亲分子 CL-1,CL-2,CL-3;它们可以象胆固醇一样与磷脂混合形成稳定脂质体,胆甾环基团位于脂质体双分子层膜的中间;与胆固醇的作用相反,它们可以增加磷脂双分子层膜的流动性,降低混合脂质体的相变温度;三种分子的作用与其碳链长度和磷脂双分子层膜的厚度有关,比膜厚度短的分子影响最大。
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Applying the principles and methods of high-resolution sequence stratigraphy, and combining with the data of exploration wells and development wells in encrypted network of wells, the authors identified 41 short-term base-level cycles of 7 types, which were formed under the conditions of deeping upward, shallowing upward, symmetrical in different accommodation space in Fuyu oil layer of Chao 1-Chao gas 3 blocks, and makes detailed analysis on the genesis and characteristics based on the sedimentary dynamics.
运用高分辨率层序地层学原理和方法,结合探井及密井网开发井资料,在朝阳沟油田朝1-朝气3区块扶余油层识别出向上&变深&、向上&变浅&、对称型及其不同可容纳空间条件下的7类共41个短期基准面旋回,并以沉积动力学观点详细剖析了其成因及特征。
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In this work, nanostructure samples of La1-xCaxMnO3(x=0.2、0.3、0.4、0.5)were prepared by hydrothermal-precipitation method . The structural characterization of the powder samples were done by X-ray diffraction. XRD patterns showed that all the samples ate single perovskite-type phase withoutother impurity or secondary phase. The shape and size of samples were performed on Scanning Electron Microscopy. SEM photographs investigated that temperature of hydrothermal effects the phase of samples and alkalinity of the reaction mixture by ΔTad-T curve measurement device at low magnetic fielded
本论文采用水热共沉淀退火法制备了La1-xCaxMnO3(x=0.2、0.3、0.4、0.5)系纳米结构,用X射线衍射仪确定产物为单相钙钛矿结构,无任何杂峰及第二相;用扫描电子显微镜与透射电子显微镜分析了产物的大小和形貌,发现水热温度对产物的形成起决定作用,随着温度的升高,产物由薄膜状向丝状转变,而溶液的碱度可控制产物的形貌和大小,当碱度为6.35mol/L,水热温度为240 C时,La0.6Ca0.4MnO3的主要形貌为纳米丝并有少量纳米颗粒,纳米丝平均直径为40nm;最后测量了粉末样品在低磁场(1.4T)下的磁热效应,发现水热共沉淀退火法制备样品的最大绝热温度明显高于球磨法制备样品的最大绝热温变。
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Dictyophora duplicata:短裙竹荪
长裙竹荪(Dictyophora indusiata)和短裙竹荪(Dictyophora duplicata)的煮沸液可防佳肴变质,若与肉共煮,也能防腐. 浓香乳菇(Lactarius camphoratus)与食物共煮或研成粉拌入食物可防止食物变馊. 在欧洲其粉末用作食品风味添加剂.
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phyletic evolution:种系进化
他在<<物种起源>>中使用'变种'这词共24次,8次指的是变异体,6次指地理种群,还有10次则含糊不清(既可理解为变异体,又可能是指种群);(2)他的形态种概念(与他以前的生物学种概念相反);(3)他经常把物种的增殖过程和种系进化(Phyletic evolution)混淆不分;
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allosteric regulation:变构调节
有些酶除了活性中心外,还有一个或几个部位,当特异性分子非共价地结合到这些部位时,可改变酶的构象,进而改变酶的活性,酶的这种调节作用称为变构调节(allosteric regulation),受变构调节的酶称变构酶(allosteric enzyme),