- 更多网络例句与变构性相关的网络例句 [注:此内容来源于网络,仅供参考]
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Complete chiral induction from enantiopure-DPEN to achiral bisphosphine ligand 3a was observed in solution, with the complex adopting a single, stable and non-fluxional (even at 70 ℃) configuration.
光学纯-DPEN在溶液中对非手性双膦配体3a产生完全的手性诱导,形成构型单一的稳定RuII络合物,即使在70°C下构型仍保持不变。
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A nonlinear creep constitutive model is given to represent the process of salt rock creep using correspondence principle based on mesomechanics .
在对盐岩在蠕变试验中所表现的损伤特征认识基础上,利用对应性原理建立了基于细观力学的盐岩蠕变损伤本构模型。
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When surface pressures are lower than the turnover(5~30mN/m),intermolecularhydrogen bonds were formed with keto form and phase transition was higher ca.60℃;most of SBC18 formed intramolecular hydrogen bonds companied withzwitterion form and phase transition was lower ca.48℃ while at surface pressurehigher than the turnover(≥45mN/m),which is caused by the different interchaininteraction arising from various hydrogen bonds for SBC18 LB film deposited atdifferent surface pressures.
低于相应π-A等温线转折(5~30mN/m)时,以分子间氢键为主,头基主要以醌式构型存在,相变温度较高(≈60℃);高于转折(≥40mN/m)时,以分子内氢键为主,头基主要以双性离子构型存在,相变温度较低(≈48℃)。
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But it is very difficult to design and implement query optimization because of the distribution and heterogeneity of the computing environment and the autonomy of multiple local data sources.
查询优化是异构数据集成中需要解决的关键问题之一,但环境的分布性、异构性以及局部数据源的自治性使得异构数据集成中的查询优化变得非常困难。
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The conclusions are as follows:(1) Neologisms in each Huayu region can be classified into two major categories:self-originated and others-originated,among which the new-born words are "absolute new words" and the inherited word are "relative new words",and there are also others-originated elements in the morphemic and sense systems of new words;(2) Variation can be seen in the morpheme,formation,building and sense of new words in Huayu regions,besides individuals of new words;(3) Aggregation of current new words and compound words with one common morpheme and a same construction,together with the aggregation of synonyms and that of different senses in polysemies,reflect the relevance of the systems of new words in Huayu regions in their variation;(4) Regular participation of hinting sense of a formation element in forming and building new words is an important way of producing new sense of morpheme,and an important reason for the current emergence of words with more than one new senses;(5) Compared with ordinary words,the productivity of ways of word formation in forming new words both in general and of a particular class will change and new ways of word formation appear in Huayu regions;(6) The semantic collocation of the verbal morpheme of new verbs in a phrase has a great influence on the location of its structural center,and the complex syntactic behaviors of new verbs are related to the different processes of argument integration;(7) The processes of building new words with the same meaning differ in levels of approaches to motivation cognition,perspectives of motivation cognition,morpheme motivation and morpheme expression,etc.;(8) The lexical interaction in Huayu regions results in lexical subsystem intersections of current new words across two,three and four regions.
本文的主要结论是:(1)各华语区新词均可分为"自源新词"和"他源新词"两大类,其中的新生词和传承词分属"绝对新词"和"相对新词",新词语的词素、词义系统中也含有他源成分;(2)除词语个体外,华语区新词在词素、构词、造词、词义等方面均体现了某种程度的变异:(3)通用词语聚合、同素同构词聚合、同义异形词聚合与一词多义聚合集中反映了各华语区新词语系统在变异中的关联;(4)构词单位经常提示词义参与构造新词是产生新语素义的重要途径,也是当代多新义词现象的重要成因;(5)相对于一般词语,构词方式在新词语中的总能产性和在某一词类中所体现的能产性都有所变化,华语区也产生了新的构词方式;(6)新动词的动素在短语中的语义搭配对结构核心的位置有很大影响,新动词的复杂句法表现与不同的论元整合过程有关;(7)同义新词造词过程的差异包括理据认知途径、理据认知角度、词素理据和词素表达等不同层面;(8)华语区的词汇互动形成了双区、三区和四区通用新词等词汇子系统交集,作为华语核心,普通话所含纳的通用词语多于各区域变体。
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This work, concentrated on the asymmetric allylation of aldehydes controlled by different chiral auxiliaries prepared from rotational pure tartaric acid, can be divided into three parts.The first part aims to review the developments of chiral drugs and asymmetric synthesis, from which derived the present research topic backgrounds and works.Synthesis and applications of allylation from aldehydes are the second part of the thesis. By optimizing the reaction conditions, such as solvents, temperature, time and chiral auxiliaries like N,N\'-dibenzyl tartamide, N,N\'-p-dimethylphenyl tartamide, N,N\'-o-dimethylphenyl tartamide, N,N\'-o-dichlorophenyl tartamide, N,N\'-a-dinaphyl tartamide, N,N\'-dicyclohexyl tartamide and N,N\'-diphenyl tartamide, ideal experimenttal conditions are obtained according to HPLC monitoring, as well as the auxiliaries\' recoveries experiments. Starting from benzaldehyde and 3-bromopropaldehyde, N,N\'-dibenzyl tartamide is considered the best auxiliary in this reaction.
本文介绍了醛的不对称烯丙基化反应,以光学纯酒石酸为原料,研究了不同构型手性配体在醛的烯丙基化反应中的立体选择性,全文共分三部分十个章节:第一部分对当前手性药物和手性技术进行了概述,并由此展开了本文的研究背景和任务;第二部分为有机合成部分,对醛的不对称烯丙基化反应进行了深入探讨,以苯甲醛为原料对反应条件进行优化,在优化的反应条件下对制备的七种可回收手性酰胺配体(N-苄基酒石酸二酰胺、N-对甲苯基酒石酸二酰胺、N-邻甲苯基酒石酸二酰胺、N-邻氯苯基酒石酸二酰胺、N-a-萘基酒石酸二酰胺、N-环己基酒石酸二酰胺和N-苯基酒石酸二酰胺)进行筛选,优化配体回收实验条件,最终确定出N-苄基酒石酸二酰胺在苯甲醛的不对称烯丙基化反应中具有较大优越性,结晶回收的手性配体光学纯度保持不变。
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Fromthese facts,It could be deduced that 8 to 14 pairs of chromosomes possessed a certaindegree of hetorology,which was directly groved to be hybrid origin of P.tomentosaaccording to the good chromosome homology and fertility of P.bolleana and thehybrids of P.tomentosa×P.bolleana,it could be further deduced that the original parentsof P.tomentosa involved probably P.bolleana or P.alba.
从终变期、中期I的染色体构型看,有数目不等的联会程度较差的单价体和棒状二价体出现,在后期I,甚至末期I亦可见到含落后染色体分裂相的细胞,由此推断可能有8~14对染色体表现出一定程度的异源性,鉴于新疆杨以及毛白杨与新疆杨杂交产生的杂种毛新杨的染色体同源性较强、育性较好等现象,进一步推断毛白杨起源亲本可能包括新疆杨或银白杨。
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The conclusions are as follows:(1) Neologisms in each Huayu region can be classified into two major categories:self-originated and others-originated,among which the new-born words are "absolute new words" and the inherited word are "relative new words",and there are also others-originated elements in the morphemic and sense systems of new words;(2) Variation can be seen in the morpheme,formation,building and sense of new words in Huayu regions,besides individuals of new words;(3) Aggregation of current new words and compound words with one common morpheme and a same construction,together with the aggregation of synonyms and that of different senses in polysemies,reflect the relevance of the systems of new words in Huayu regions in their variation;(4) Regular participation of hinting sense of a formation element in forming and building new words is an important way of producing new sense of morpheme,and an important reason for the current emergence of words with more than one new senses;(5) Compared with ordinary words,the productivity of ways of word formation in forming new words both in general and of a particular class will change and new ways of word formation appear in Huayu regions;(6) The semantic collocation of the verbal morpheme of new verbs in a phrase has a great influence on the location of its structural center,and the complex syntactic behaviors of new verbs are related to the different processes of argument integration;(7) The processes of building new words with the same meaning differ in levels of approaches to motivation cognition,perspectives of motivation cognition,morpheme motivation and morpheme expression,etc.;(8) The lexical interaction in Huayu regions results in lexical subsystem intersections of current new words across two,three and four regions.
本文的主要结论是:(1)各华语区新词均可分为&自源新词&和&他源新词&两大类,其中的新生词和传承词分属&绝对新词&和&相对新词&,新词语的词素、词义系统中也含有他源成分;(2)除词语个体外,华语区新词在词素、构词、造词、词义等方面均体现了某种程度的变异:(3)通用词语聚合、同素同构词聚合、同义异形词聚合与一词多义聚合集中反映了各华语区新词语系统在变异中的关联;(4)构词单位经常提示词义参与构造新词是产生新语素义的重要途径,也是当代多新义词现象的重要成因;(5)相对于一般词语,构词方式在新词语中的总能产性和在某一词类中所体现的能产性都有所变化,华语区也产生了新的构词方式;(6)新动词的动素在短语中的语义搭配对结构核心的位置有很大影响,新动词的复杂句法表现与不同的论元整合过程有关;(7)同义新词造词过程的差异包括理据认知途径、理据认知角度、词素理据和词素表达等不同层面;(8)华语区的词汇互动形成了双区、三区和四区通用新词等词汇子系统交集,作为华语核心,普通话所含纳的通用词语多于各区域变体。
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The simultaneous allosteric modulation of ligandgated ion channels by general anesthetics is entirely additive.
同时发生的全麻药对配体门控离子通道的变构调制作用完全是相加性的。
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Firstly, some basic properties of the limit shadowing are given; Secondly, we give the characterization of both lin-ear automorphisms and linear flows on R~ with the limit shadowing property; Thirdly, as applications we prove that the hyperbolic endomorphisms on T~ have the limit shadowing properties, Smale "horseshoes" have the same prop-...
首先,给出了极限跟踪性的一些基本性质;其次,得到了n维欧氏空间上线性自同构及线性流具有极限跟踪性的特征;最后,作为应用证明了双曲环面自同态以及Smale&马蹄&在其不变集上具有极限跟踪性。
- 更多网络解释与变构性相关的网络解释 [注:此内容来源于网络,仅供参考]
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metacryst:次生晶;变晶
metaisomerism 位变异构性;位变异构现象 | metacryst 次生晶;变晶 | metaborate 偏硼酸盐
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anisidine reaction:甲氧苯胺反应
"aniontropy","阴离子离变" | "anisidine reaction","甲氧苯胺反应" | "anisomeric; non-isomeric","非异构性的"
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chronotropic:变时性
是腺体(M3)受体的36倍. 奥腾折帕的(+)-异构体对M2-受体的活性是(-)-异构体的8倍. 临床前研究:静脉给药奥腾折帕剂量依赖性地提高清醒狗的心率. 奥腾折帕的阳性变时性(chronotropic)效应伴随有LVdP/dtmax的提高和SV的降低.
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desmotropism, dexmotropy:稳变异构性,稳变构性现象
链解[作用],解链[作用] desmolysis | 稳变异构性,稳变构性现象 desmotropism, dexmotropy | 去溶剂装置 desolventizer
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enantiomorphous crystal:镜像晶体
enantiotropic change 晶形互变 | enantiomorphous crystal 镜像晶体 | enantiomorphism 镜像异构现象;镜像异构性
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parallelepipedal deformation:平行六面体形变
parallel texture 平行织构 | parallelepipedal deformation 平行六面体形变 | parallelism 平行性
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allosteric transition:变构转变
allosteric enzyme 变构酶 | allosteric transition 变构转变 | allostery 变构性
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allostery:变构性
allosteric transition 变构转变 | allostery 变构性 | allothreonine 别苏氨酸
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allostery:别构性
allosterism别构,变构 | allostery别构性 | allosynapsis异源联会