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In this work, we also presented some methods to determine kinetic parameters for the different systems and examplified by the reduction of thionyl chloride in dimethyl formamide.
根据我们提出的判定反应可逆性的方法,系统地对EE反应机理进行了探讨,从中可方便地判定EE反应的不同反应机理;对不同的反应机理,相应地又提出了测定其电极反应动力学参数的方法,并以亚硫酰氯的还原为例进行了研究及测定。
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The main research work and its results are: 1Empirical results are analysed for the relations of fault displacement and earthquake magnitude, and difference between permanent ground deformation and maxium dynamic relative displacement on the two sides of fault; 2An analytic method is proposed for resopnse of a buried pipeline due to earthquake fault movement; 3A new shell model with an equivalent boundary and relted finite element analysis method are proposed for estimating response of a buried pipeline under large fault movement; 4By the proposed method, damage performance of water supply steel pipelines with large diameter is simulated to the real cases in Kocaeli Earthquake and Ji-Ji Earthquake, and simulating results show the real failure mode of pipes is revealed; 5Effects of overlying soil and soft/hard interlayers are analyzed on ground rupture mode and degree due to earthquake fault, and some earthquake rupture phenomena in soil layers are theoretically described for the first time; 6Pipeline response characters are discussed for the case of considering effects of soil layers on ground rupture mode; 7Research results and proposed method are applied in seismic analysis of pipline acrossing fault in the Gas Tansportation Project from West to East in China.
主要工作和成果包括:1)分析了不同断层位错形式下地表破裂位错量与震级之间的经验关系,并基于集集地震近断层记录分析了断层两侧永久地面变形和地震动相对位移幅值之间的差别,为合理地考虑地震断层位错地面变形动态影响提供了依据;2)发展了断层位错地面大变形下管线反应分析模型并给出物理概念明确、简单实用的解析分析方法;3)建立了断层位错下埋地管线反应分析的等效边界壳模型有限元方法,方法中引入了以非线性弹簧形式模拟离断层较远处管段影响的等效边界,简化了计算模型并突出了近断层处管体反应;4)利用等效边界壳模型方法,对土耳其地震和集集地震中大口径埋地管线震害进行了模拟,结果表明所提方法可以更清地解释震害所表现的管体破坏特征;5)研究了覆盖土层和软硬夹层的存在对断层位错地面破裂形式和程度的影响,首次从理论上解释了某些地震地表破裂现象;6)探讨了考虑土层对断层位错地面变形影响的管体反应特征;7)本项目成果已在西气东输工程的管道跨断层抗震问题分析中得到了应用。
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Therefore,a series studies of ice-pier vibration are performed from different aspects in this paper.The main work of this his thesis is summarized as follows:(1) Ice response spectra is proposed based on the idea of a seismic response spectra analysis of str .. uctures.Firstly,ice response spectra on the basis of power spectra density function is established;Secondly,based on the assumption of quadratic parabolic interpolation method,the nonlinear interpolation analysis method of ice response spectra is studied from both theoretical and practical points of view,and the successive computation formulas including ice displacement,velocity and acceleration response spectrum are deduced by Duhamel integral.Furthermore,to analyze the effectivity and applicability of the method, the real temporal curves of ice pressure are used to be studied.The results show that the presented method is more convenient and accurate to study the structural response induced by ice force,also it can be effectively applied in the design of ice resistance.
鉴于此,本文针对冰激桥墩结构振动问题从不同方面展开了一系列与之相关的研究,主要研究内容如下:(1)根据结构抗震反应分析思想提出了冰振反应谱,首先建立了基于功率谱密度函数的冰振反应谱;其次借鉴地震反应谱内插法的思想从理论和实际观点出发,假定在等距离微小时间间隔内冰荷载按二次抛物线规律变化,由Duhamel积分推导出冰振位移、速度以及加速度反应谱的一系列连锁公式,建立了基于非线性内插法的冰振反应谱,并利用实际冰压力时程曲线进行了冰振反应谱数值分析,为以后冰激结构振动的研究提供一种方便、简捷、精确的分析方法,也能够将其有效地应用到结构的抗冰计算中。
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Those at the top are the noble ,reactively in aqueous solutions.
那些在上面是贵族,易反应地在水溶液。
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Theoretical analysis reveals that the reaction of the immobilized enzyme of low substrate concentration may be approximated to be of first order, while that of high substrate concentration to be of zero order.
经过对固定化酶反应动力学理论分析可知,实验条件下的低基质浓度区内测定的固定化酶反应可近似地作为一级反应,而在高基质浓度区内测定的固定化酶反应可近似地作为零级反应。
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The chapter two was focused on the samarium diiodide promoted organic reactions and their applications in organic synthesis, firstly, a new synthesis of highly substituted cyclopentadienes from a,β-alkynone promoted by samarium diiodide was investigated and the highly substituted cyclopentadienes were prepared in moderate to good yields under mild conditions. Secondly, the Michael addition and Michael-aldol tandem reaction of diorganyl diselenides or diorganyl disulfides with α,β-alkynones mediated by samarium diiodide were studied and a series of alkenylsulfides and alkenylselenides were prepared in good yields. Then the highly regioselecfive nucleophilic addition of the allylsamarium bromide to α,β-alkynones were explored. We found that the allylsamarium bromide reacts with α,β-alkynones to afford regiospecificly 1. 2-nucleophilic addition products in good yields under mild condition. At last we studied the coupling reaction of aryl halides promoted by NiCl〓/PPh〓/Sm〓.
第二章 研究了二碘化钐、金属钐促进的有机反应:1、二碘化钐促进下α,β-炔基酮的偶联环化反应,提供了一种制备多取代环戊二烯的新方法;2、二碘化钐促进下的二硫醚、二硒醚与α,β-炔基酮的Michael加成反应,为高产率地制备多取代的烯基硫或烯基硒化合物提供了方便可靠的新方法;3、二碘化钐促进下的二硫醚、二硒醚与α,β-炔基酮和醛、酮的Michael—aldol串联反应,提供了一种一锅法高产率地制备多取代的含硫的烯丙基醇或含硒的烯丙基醇类化合物的方便可靠的原子经济性的新方法;4、烯丙基溴化钐与α,β-炔基酮的高度区域选择性的1,2-亲核加成反应;5、NiCl〓/PPh〓/Sm〓促进的卤代芳烃的偶联反应-一种从各种卤代芳烃制备联苯类化合物的有效方法。
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The results show that:First, concentration of hydrogen peroxide have the most obvious influence to oil yield and carbon black yield,with the increase of concentration of hydrogen peroxide the oil yield first increase then decrease,when concentration of hydrogen peroxide is 8.19% or so,the oil yield reach to the biggest value, and with the increase of concentration of hydrogen peroxide carbon black yield decrese;Then,reaction time have more obvious influence to oil yield and carbon black yield,oil yield increase but carbon black yield decrease with the increase of reaction time;Thirdly,reaction tempreture have some influence to oil yield and carbon black yield,samely,oil yield increase but carbon black yield decrease with the increase of reaction tempreture;Finally,reaction pressure does almost no influence on oil yield and carbon black yield.
研究结果表明:过氧化氢质量浓度对产油率和炭黑产率的影响最为显著,产油率随过氧化氢质量浓度的提高先提高后降低,在过氧化氢质量浓度为8.19%左右时达到最大值,炭黑产率随过氧化氢质量浓度的提高而降低;反应时间对产油率和炭黑产率的影响也比较显著,产油率随反应时间的增加而提高,炭黑产率随反应时间的增加而降低;反应温度对产油率和炭黑产率也有一定的影响,产油率随反应温度的提高而相应地提高,炭黑产率随反应温度的提高而降低;在本文实验范围内,反应压力对产油率和炭黑产率基本上没有影响。
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A one-step method for the synthesis of aromatic indolizine derivatives byintramolecular 1,5-dipolar cyclization reaction of 2-(2-arylethenyl)pyridinium N-ylidesin the presence of an oxidant has been studied for the first time. In the presence ofelectron-deficient olefins, however, 2-(2-phenylethenyl)pyridinium N-ylides underwent1,3-dipolar cycloadditions and then aromatized in situ by TPCD to produce indolizinederivatives, indicating 1,3-dipolar cycloaddition proceed more readily than 1 ,5-dipolarcyclization in these conditions. Pyridinium disubstituted N-ylides, readily obtainedfrom corresponding pridinium and β-chlorovinyl ketone, underwent thermalintramolecular 1,5-dipolar cyclization to give indolizine derivatives easily.Indolizinecarbaldehyde derivatives were synthesized starting from 2-pyridinecarbaldehyde in four-steps involving 1,3-dipolar cycloaddition reaction.
本文首次研究了2-(2-芳基乙烯基)吡啶N-叶立德在氧化剂存在下的分子内1,5-偶极环化反应,采用一锅法合成了中氮茚衍生物;研究了这些N-叶立德的1,5-偶极环化和1,3-偶极环加成反应的选择性,发现当有缺电子烯烃存在时,优先进行1,3-偶极环加成反应,而不再发生分子内1,5-偶极环化反应;由β-氯乙烯酮方便地得到了烯丙基N-叶立德,他们在加热时进行分子内1,5-偶极环化反应而得到中氮茚衍生物;由2-吡啶甲醛为起始原料,通过1,3-偶极环加成反应等四步反应,得到了重要的中氮茚甲醛衍生物,这些反应都具有条件温和和操作简便的特点,是合成中氮茚衍生物的新方法。
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The application results from fluorination showed microwave heating could accelerate chemical reactions markedly. The reaction time could be shortened 50% at least than that of conventional heating. The relationship between fluorinating agents\' structure and their activity was studied systematically. In addition, an anhydrous KF with higher activity was prepared by using expansion effect of microwave heating. As we known, solvents were very important to reaction. The comprehensive study showed some less polar aromatic solvents could be used as dipolar solvents. In addition, they had better effect than dipolar solvents in some occasions, such as fluorination of chlorobenzaldehydes and chlorinated diphenyl ketones etc. The primary applications of ionic liquids were also studied which indicated reactions with ionic liquids as solvents were more efficient and simple.
研究表明,微波是一种节能高效的加热方式,在微波作用下的卤素交换氟化反应具有反应速度快、转化率高、选择性好的优点,其反应时间可较常规加热缩短50%以上;同时也系统地研究了氟化剂种类及制备方式对其反应活性的影响,并利用微波加热的膨化作用制备出了一种活性较高的KF,其活性与喷雾干燥KF相差不大;溶剂对反应具有重要的作用,在此系统地研究了强极性非质子溶剂和中等极性非质子溶剂的应用情况,发现一些中等极性的非质子溶剂如硝基芳烃和氯代芳烃类溶剂在氯代苯甲醛类化合物的氟化反应中具有比强极性非质子溶剂更好的使用效果。
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In this project, we have prepared conveniently Si-Mg 1,1-difunctional group reagents-α-silylvinyl Grignard reagents by hydromagnesiation of alkynylsilanes; Se-Br 1,1-difunctional group reagents-α-bromovinylselenides by hydrobromination of alkynylselenides; Sn-Br and Sn-I 1,1-difunctional group reagents by hydrozirconation of alkynylstannanes followed by halogenating reaction.
本项目通过炔基硅烷的镁氢化反应,方便地制得了Si-Mg 1,1-双官能团试剂-α-硅基烯基镁化物;通过炔基硒醚的溴氢化反应,方便地制得了Se-Br 1,1-双官能试剂-α-溴代烯基硒醚;通过炔基锡烷的锆氢化反应,继而卤代方便地制得了Sn-Br和Sn-I 1,1-双官能试剂。
- 更多网络解释与反应地相关的网络解释 [注:此内容来源于网络,仅供参考]
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at a word:(对请求、建议或命令等)反应很快地,立即地
He was a teacher at one time, but now he works for foreign trade. 他... | at a word(对请求、建议或命令等)反应很快地,立即地: | At a word from the teacher, the little girl got up and sang for the visitors....
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irresponsive:无反应的; 无感应的; 无答复的 (形)
irresponsibly 不负责任地; 不可靠地 (副) | irresponsive 无反应的; 无感应的; 无答复的 (形) | irretentive 不能保持的 (形)
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react:做出反应
Weick 更进一步指出,组织并不只是只对环境做出反应(react ),而是可以积极地构建(construct )和参与"制定"(enact )他们的环境. "制定"过程是一个"主体部分地与客体互动并构成客体"的过程(Weick ,1979,p.165). 也就是说,
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reactively:反动地, 反应性地
dactyl 强弱格, 长短格 | reactively 反动地, 反应性地 | stores department 材料处
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reactively:反动地
reactive 反应的 | reactively 反动地 | reactivity 反应
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reactively:反应性地
reactive 反应性的 | reactively 反应性地 | reactivelyretroactively 反动地
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corresponsive:反应的
correspondingly 相对地 | corresponsive 反应的 | corresponsively 反应地
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corresponsive:反应的, 相当的
correspondingly | 相对地, 比照地 | corresponsive | 反应的, 相当的 | corresponsively | 反应地, 相当地
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corresponsively:反应地, 相当地
thermosetting resin 热固树胶 | corresponsively 反应地, 相当地 | waveguide mount 波导管支架
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corresponsively:反应地
corresponsive 反应的 | corresponsively 反应地 | corrida 斗牛