- 更多网络例句与双六面体相关的网络例句 [注:此内容来源于网络,仅供参考]
-
In complex 1,Cucan be described as a four-coordinated square planar geometry.Compound 8 is the sodium salt of plumbagin and exists as ionic compound.Compounds 9-16 are the rare earth complexes of plumbagin with La,Y,Dy,Sm,Gd,Nd,Erand Eu.Compound 17 is binuclear Y complex.18 is mononuclear Ycomplex with plumbagin and another ligand from Plumbago Zeylanica.Compounds 19-21 are the ternary complexes with plumbagin and 2,2\'-bpy and phen as assistant ligand.In 19, the geometry of Cucan be described as five-coordinated distorted square pyramid that exists in a dimer through the weak bonding,and 1-D chain structure is formed by intermolecular hydrogen bonds.
化合物1的单晶结构分析表明1具有四配位平面四边形结构,化合物8是白花丹素的Na盐,以离子化合物形式存在;化合物9~16为白花丹素的La,Y,Dy,Sm,Gd,Nd,Er,Eu的稀土金属配合物;化合物17是白花丹素的双核钇结构;化合物18为白花丹素的单核钇结构,该配合物除了含白花丹素外,还有来自白花丹植物中的另一个单体化合物也参与配位;化合物19~21是以2,2\'-联吡啶和邻菲咯啉等含N配体为辅助配体,具有白花丹素—含N配体—金属离子的三元配合物,化合物19是白花丹素和2,2\'-联吡啶与Cu的配合物,具有五配位的四方锥构型,通过Cu…O弱的成键作用形成二聚体,再通过分子间的氢键作用进一步形成一维链状结构,化合物20和化合物21是白花丹素分别与2,2\'-联吡啶和邻菲咯啉的Zn配合物,都具有六配位八面体构型的双核锌配合物,呈一维链状结构,化合物20中链与链之间的大量氢键将一维链扩展成二维层,分子间的π-π堆积作用进一步形成三维结构。
-
The crystal structures have been determined by single-crystal X-ray diffraction.Cadmium atoms in compounds 1 and 2 show an eight-coordinated distorted square-antiprismatic geometry and a seven-coordinated distorted pentagonal bipyramidal geometryrespectively. Copper atoms in compounds 3 and 4 show a six-coordinated distorted threeprismatic geometry and a four-coordinated distorted tetrahedral geometry respectively.
所有配合物的晶体结构都通过单晶X-射线衍射确定:配合物1中的镉离子周围显示八配位的扭曲四方反棱柱构型;而配合物2中的镉离子周围显示七配位的扭曲五角双锥构型;配合物3中的铜离子周围显示六配位的扭曲三棱柱构型;配合物4中的铜离子周围显示四配位的扭曲四面体构型;配合物5中的锌离子周围显示六配位的扭曲八面体构型。
-
Specifically, itcontains 8 chapters.In chapter 1, the formation, structures, properties and the futureprospect of liposome were thoroughly reviewed;In chapter 2, the stibility and permeability of phopholipid -eleostericacid liposome were studied together with the effect of polymerizationof eleostearic acid. This membrane system was very sensitive to 〓,the effect of 〓 was clarified to increase the aggregation/fusion ofliposomes and made the permeability of mixed liposomes much higher;In chapter 3, two polymerizable conjugated diyne bolaamphiphiles were synthesized. They could form very stable mixed liposome, andthe diyne could be polymerized by UV light in bilayer liposomes, as aresult, the stability of mixed liposome against solvent or surfactantafter polymerization were enhanced. In chapter 4, two kinds of amphiphilic amino acids were synthesized andstable liposomes were formed therefrom After the condensationpolymerization of amino acid in bilayer liposomes, stable polypeptide liposomes were obtained, which had lower phase transition temperatureand higher permeability.In chapter 5, four kinds of glycolipids were synthesized and theiraggregation behavior in water was comparied. When incorporated intophospholipid bilayer membranes, they could increase the phase transitiontemperatures and inhibit the aggregation and fusion of mixedliposomesat lower temperature.In chapter 6 and 7, three kinds of steroidal bolaamphiphiles withdifferent chain lengths were synthesized. Incorporation of steroidalmoiety to the center of lipid bilayer membrane obviously increased themobility of lipid membrane and shifted Tc to lower temperature side incomparasion with cholesterol. The bolaamphiphile which was shorter thanthe hosted lipid bilayer membrane thickness influenced the lipid packingmore obviously.
全文共分8章:第一章对脂质体的形成、结构、性质及展望进行了较为详细的文献综述;第二章研究了磷脂-桐酸脂质体的稳定性,通透能力及桐酸的聚合对这些性质的影响;磷脂-桐酸混合脂质体为一类对〓灵敏的脂质体,〓的作用首先是使脂质体集聚然后使脂质体融合,并加速内包荧光物的释放;第三章通过合成两种可聚合共轭双炔双极性双亲分子DDCA,DDOL,研究了共双炔分子在双分子层脂质体膜上的聚合及对脂质体性质的影响,聚合可以提高脂质体相对于溶剂及表面活性剂的稳定性;第四章合成了两类氨基酸为极性基团的双亲分子,它们均可以在超声下形成稳定的脂质体结构;氨基酸基团可以在脂质体上进行缩聚反应,若聚合后脂质体表面仍有足够的亲水能力,则可得到稳定的多肽型脂质体;聚合后脂质体的相变温度降低,通透能力增加;第五章合成了四种亲水基团为单糖基的双亲分子GL-l,GL-2,GL-3, GL-4,研究了它们在水中的分散情况、集合体形态与分子结构的关系;在DMPC双分子层膜中加入糖脂分子可以使脂质体的相变温度提高,阻止脂质体在低温放置时的集聚与融合;第六章-第七章合成了三种不同碳链长度的双极性含胆甾环双亲分子 CL-1,CL-2,CL-3;它们可以象胆固醇一样与磷脂混合形成稳定脂质体,胆甾环基团位于脂质体双分子层膜的中间;与胆固醇的作用相反,它们可以增加磷脂双分子层膜的流动性,降低混合脂质体的相变温度;三种分子的作用与其碳链长度和磷脂双分子层膜的厚度有关,比膜厚度短的分子影响最大。
- 更多网络解释与双六面体相关的网络解释 [注:此内容来源于网络,仅供参考]
-
dihedral group:正二面体群
正二面体群 dihedral group | 复六方双锥 dihexagonal bipyramids | 复六方双锥类 dihexagonal bipyramids class
-
dihedron:二面体,双面体
二面角,双面角 dihedral angle | 二面体,双面体 dihedron | 复六方双锥 dihexagonal bipyramid
-
parallel hexahedron:平行六面体
平行连晶 parallel grouping,parallel | 平行六面体 parallel hexahedron | 平行双晶 parallel twin
-
dihexagonal:双六角棱镜
dihedron 二面体 | dihexagonal 双六角棱镜 | dihexagonal 复六方的
-
dihexagonal:复六方的/双六角棱镜
dihedron /二面体/ | dihexagonal /复六方的/双六角棱镜/ | dihexahedron /复六方面体/双六面体/
-
dihexagonal prism:双六方形棱镜
dihexahedron 双六面体 | dihexagonal prism 双六方形棱镜 | dihedral group 二面群
-
dihexahedron:双六面体
dihydrate 二水盐;二水合物 | dihexahedron 双六面体 | dihexagonal prism 双六方形棱镜
-
dihexahedron:复六方面体/双六面体
dihexagonal /复六方的/双六角棱镜/ | dihexahedron /复六方面体/双六面体/ | dihybrid /二因子杂种/双因子杂种/
-
dihydrate:二水盐;二水合物
dihydrazone 二腙 | dihydrate 二水盐;二水合物 | dihexahedron 双六面体
-
double chain silicate, double band silicate:双链硅酸盐
双晶轴||twin axis | 双链硅酸盐||double chain silicate, double band silicate | 双六面体||dihexahedron