卟啉基

基本解释 (translations)

porphyryl

与卟啉基相关的网络例句 [注：此内容来源于网络，仅供参考]

Chapter two: Using 5-(4-aminophenyl)-10,15,20-triphenylporphyrin as thestarting compound, the classical diazotization of aniline and the resulting reaction ofdiazo salts were applied to porphyrin for the first time, and a series of asymmetriclysubstituted meso-tetraarylporphyrins including 5-(4-chlorophenyl)-10,15,20-triphenylporphyrin, 5-(4-iodinphenyl)-10,15,20-triphenylporphyrin, 5-(4-cyanophenyl)-10,15,20-triphenylporphyrin, 5-(4-bisphenyl)-10,15,20-triphenylporphyrin and 5-(4-hydroxylphenyl)-10,15,20-triphenylporphyrin were synthesized.

第二章：在已合成的5-(4-氨基苯基)-10，15，20-三苯基卟啉基础上，首次将芳胺的重氮化及重氮盐反应应用于卟啉，合成了5-(4-氯苯基)-10，15，20-三苯基卟啉、5-(4-碘基苯基)-10，15，20-三苯基卟啉、5-(4-氰基苯基)-10，15，20-三苯基卟啉、5-(4-联苯基)-10，15，20-三苯基卟啉和5-(4-羟基苯基)-10，15，20-三苯基卟啉等一系列不对称取代的meso-四芳基卟啉。

The metalloproteins which are widely distributed in vivo are very important target molecules of NO. A new Y/〓 reaction system which can form Y-NO bond has been established and has been used to measure the NO affinity of metalloporphyrins as metalloprotein models. Three kind of bond energies of the Co-NO bonds in series of cobalt nitrosyl tetraphenylporphyrins have been determined by thermodynamic cycles combined with calorimetric measurements and relevant electrochemical data.

本文以金属卟啉模拟体内重要的NO靶分子金属蛋白，通过确立新的适于量热和电化学测定的Y／〓成Y-NO键反应体系，利用合适的热力学循环，建立了新的适于金属卟啉体系的NO亲合势的测定方法，得到了苯腈中系列亚硝基四苯基钴卟啉Co-NO键的键能，即钴卟啉NO亲合势的定量标度，以表征钴卟啉的NO结合能力。

Three kind of bond energies of the Co-NO bonds in series of cobalt nitrosyl tetraphenylporphyrins have been determined by thermodynamic cycles combined with calorimetric measurements and relevant electrochemical data.

本文以金属卟啉模拟体内重要的NO靶分子金属蛋白，通过确立新的适于量热和电化学测定的Y／〓成Y-NO键反应体系，利用合适的热力学循环，建立了新的适于金属卟啉体系的NO亲合势的测定方法，得到了苯腈中系列亚硝基四苯基钴卟啉Co-NO键的键能，即钴卟啉NO亲合势的定量标度，以表征钴卟啉的NO结合能力。

Chromatographic behaviors of six cationic thulium porphyrin complexes have been firstly investigated in different mobile phase.

2首次以六个不同的铥卟啉配合物（四（4-羟基苯基）卟啉铥、四（4-甲氧基苯基）卟啉铥、四苯基卟啉铥、四（4-甲基苯基）卟啉铥、四（4-氯苯基）卟啉铥和四（4-异丙基苯基）卟啉铥）为研究对象进行HPLC分离。

The pure isomers 3-(1-hydroxyethyl)-8-vinyldeuteroporphyrin Ⅸ and 3-vinyl-8-(1-hydroxyethyl)deuteroporphyrin Ⅸ were obtained from protoporphyrin Ⅸ dimethyl ester.Starting from these two acetylating compounds,eight new porphyrin derivatives were synthesized through an alkyloxy fission reaction.

以原卟啉Ⅸ二甲酯为起始原料，合成并分离得到3-(1-羟乙基)-8-乙烯基次卟啉Ⅸ（Ⅱ1）和3-乙烯基-8-(1-羟乙基)次卟啉Ⅸ（Ⅱ2）二个异构体，两者分别经酰化后与醇进行烷氧裂解反应合成了8个全新的卟啉衍生物。

The behaviors of supramolecular self-assembly of cabboxyl porphyrin-anthraquinone systems, carboxyl porphyrin zinc-copper systems, porphyrinatozinc-imidazolyl tailed porphyrinatomanganese systems, porphyrinatozinc-anthraquinone hybrids/imidazolyl tailed porphyrinatomanganese systems and porphyrinatozinc-fluorescein hybrids/imidazolyl tailed porphyrinatomanganese systems driven by hydrogen-bonding or coordination-bonding have been studied.

设计、合成了多种新型羧基卟啉、卟啉-蒽醌二元化合物和卟啉-荧光素二元化合物，研究了氢键或配位键驱动的羧基卟啉-蒽醌、羧基卟啉锌-羧基卟啉铜、锌卟啉-咪唑基尾式卟啉锰二元超分子，卟啉-蒽醌二元化合物与咪唑基尾式卟啉锰三元超分子的构建和光诱导电子转移性质。

Eight porphyrin compounds, meso-5, 10, 15, 20-Tetra [4-aminophenyl] porphine (TAPPH〓, 1), meso-5, 10, 15, 20-Tetra [4-(N-pyrrolidinyl) phenyl] porphine (TBPPH〓, 2), meso-5, 10, 15, 20-Tetra [4-(4'-ethylpiperazinyl) phenyl] porphine (TEPPH〓, 3), meso-5, 10, 15, 20-Tetra [4-(4'-butylpiperazinyl) phenyl] porphine (TUPPH〓, 4), meso-5, 10, 15, 20-Tetra [4-(4'-heptylpiperazinyl) phenyl] porphine (TEPPH〓, 5), 5- [4-(4'-ethylpiperazinyl) phenyl] -10, 15, 20-triphenylporphine (MEPPH〓, 6), 5- [4-(4'-buthylpiperazinyl) phenyl] -10, 15, 20-triphenylporphine (MUPPH〓, 7) and N, N'-di (meso-5, 10, 15, 20-tetraphenylporphinato) piperazine (DiPPH〓, 8) have been designed and synthesized. These porphyrins are never reported except TAPPH〓.

设计并合成了8种卟啉化合物，分别为meso-5，10，15，20-四（4-氨基苯基）卟啉（TAPPH〓，1），meso-5，10，15，20-四卟啉（TBPPH〓，2），meso-5，10，15，20-四[4-（4'-乙基哌嗪基）苯基]卟啉（TEPPH〓，3），meso-5，10，15，20-四[4-（4'-丁基哌嗪基）苯基]卟啉（TUPPH〓，4），meso-5，10，15，20-四[4-（4'-庚基哌嗪基）苯基]卟啉（THPPH〓，5），5，10，15-三苯基-20-[4-（4'-乙基哌嗪基）苯基]卟啉（MEPPH〓，6），5，10，15-三苯基-20-[4-（4'-丁基哌嗪基）苯基]卟啉（MUPPH〓，7）和N，N'-二（meso-5，10，15，20-四苯基卟啉基）哌嗪（DiPPH〓，8）。

Using classical diazotisation of anilines, 5-(4-aminophenyl)-10,15,20-triphenyl-porphyrin was converted to a series of meso-tetraarylporphyrins with different substituents, including 5-(4-hydroxylphenyl)-10,15,20-triphenylporphyrin (80%), 5-(4-chlorophenyl)-10,15,20-triphenylporphyrin (74%), 5-(4-iodinphenyl)-10,15,20-triphenylporphyrin (76%), 5-(4-hydrazinephenyl)-10,15,20-triphenylporphyrin (67%) and 5-(4-bisphenyl)-10,15,20-triphenylporphyrin (32%). Therefore an efficient way of synthesizing unsymmetrically substituted TAPs was developed.

利用芳胺的重氮化及重氮盐反应，研究了5-(4-氨基苯基)-10，15，20-三苯基卟啉上氨基官能团的转化反应，以较高产率合成了5-(4-羟基苯基)-10，15，20-三苯基卟啉(80%)、5-(4-氯苯基)-10，15，20-三苯基卟啉(74%)、5-(4-碘基苯基)-10，15，20-三苯基卟啉(76%)、5-(4-肼基苯基)-10，15，20-三苯基卟啉(67%)和5-(4-联苯基)-10，15，20-三苯基卟啉(32%)等一系列含单个para-取代基的meso-四芳基卟啉，为合成不对称取代的芳基卟啉提供一条有效途径。

First, by using p-methoxybenzaldehyde , p-hydroxybenzaldehyde and pyrrole as raw materials, 5-(p-hydroxyphenyl)-10,15,20-tri(p-methoxyphyenyl)porpyrin was prepares under acidity condition and the let reacted with benzoyl chloride, o-nitrobenzoyl chloride, m- nitrobenzoyl chloride and p- nitrobenzoyl chloride respectively under alkalinity condition with DMF as solvent.

以对-甲氧基苯甲醛、对-羟基苯甲醛和吡咯为原料，在酸性条件下合成了5-对羟苯基10，15，20-三对甲氧苯基卟啉，再以该化合物为原料分别与苯甲酰氯、邻-硝基苯甲酰氯、间-硝基苯甲酰氯和对-硝基苯甲酰氯反应，在碱性条件下以DMF为溶剂合成了四种目前尚未见文献报道的对-甲氧基卟啉硝基苯甲酸酯类化合物。

We use AOT/iso-octane/water reverse micelles as a biological model to mimic the properties of triplet-excited-state porphyrin in the interfacial region. The amphiphilic property of compound is difficult to evaluate for different system.

用AOT／异辛烷／水反相胶束体系营造了一个多相、多界面的环境，通过对卟啉化合物三重态寿命的测量，研究了以亲水基团为端基的具有不同侧链链长的两亲卟啉化合物的界面行为，探讨了卟啉化合物的亲水疏水性质与界面环境间的相互作用，这对卟啉类光疗药物的结构优化具有帮助。

与卟啉基相关的网络解释 [注：此内容来源于网络，仅供参考]

Hematoporphyrin monomethyl ether：血卟啉单甲醚

苄基缩水甘油醚:Benzyl glycidyl ether | 血卟啉单甲醚:Hematoporphyrin monomethyl ether | 甲基叔丁基醚:methyl tertiary-butyl ether

porphyrin：卟啉

'''血红素'''('''Heme''')是一种含铁[[辅基]],铁原子位于被称为[[卟啉]] (porphyrin) 的大[[杂环化合物]]中心. 并非所有的卟啉分子中都含有铁,但含有卟啉的[[金属蛋白]]都以血红素为辅基,这些[[蛋白质]]即[[血红蛋白]].

nickelage：镀镍

nickel-porphyrin 镍卟啉 | nickelage 镀镍 | Nickeline 锡基密封合金

porphine：卟吩

卟啉(Porphyrins)是卟吩(Porphine)外环带有取代基的同系物和衍生物的总称. 卟啉化合物在自然界广泛存在,由于卟啉化合物具有独特的结构及性能和特殊的生理活性,使得卟啉化合物在医学、生物化学、材料化学、合成化学、能源利用等很多方面具有良好的应用前景,

chlorin：二氢卟酚

叶绿素是二氢卟酚(chlorin)色素,结构上和卟啉(porphyrin)色素例如血红素类似. 在二氢卟酚环的中央有一个镁原子. 叶绿素有多个侧链,通常包括一个长的植基(phytyl chain). 分子立体模型绿色植物是利用空气中的二氧化碳、阳光、泥土中的水份及矿物质来为自己制造食物,