光催化剂

基本解释 (translations)

photocatalyst  ·  photocatalyzer  ·  pholocatalyst  ·  phstocatalyzer

与光催化剂相关的网络例句 [注：此内容来源于网络，仅供参考]

In a static photocatalytic reactor,the gas-phase adsorption and photocatalytic degradation of benzene and butyraldehyde over the two photocatalysts were studied,and the intermediates and products were detected by gas chromatography.

利用溶胶-凝胶并水热处理法制备了TiO2光催化剂和TiO2/AC复合光催化剂，在静态光催化反应器中研究了苯和丁醛的气相吸附和光催化降解，利气相色谱分析确定了生成的中间体。

Recent progress on surface modifications of TiO2 doped by metal cation and metalloid anion has been summarized,based on the findings reported in the present literatures.

早期的研究主要集中在悬浮体系即TIO：粉末上，但目前悬浮相TIO：光催化剂在水中易凝聚、易失活、且使光的穿透力受阻，尤其是处理后的光催化剂分离与回收的难题已成为该项技术能否工业化的关键。

SO〓〓/M〓O〓 solid superacid was applied to the photocatalytic oxidation of organic pollutants for the first time. Porous SO〓〓/TiO〓 solid superacid catalysts with high specific surface area were prepared by sol-gel method. The photocatalytic degradation of bromomethane was used as model reaction. The influence of impregnation with H〓SO〓 solution on the structure of catalysts and their photocatalytic performance was systematically studied by using X-ray diffraction, X-ray photoelectron spectroscopy, N〓 sorption analysis applying BET method, UV-Vis diffuse reflectance spectroscopy, FTIR spectroscopy, O〓-TPD and photocatalytic activity measurement. The acidity of TiO〓-based catalysts was investigated by Hammett indicator method, NH〓-TPD and IR spectra of pyridine adsorbtion. The mechanism of superacidifing effects on photocatalytic performances such as the photocatalytic degradation rate of bromomethane, apparent kinetic constant and apparent quantum efficiency was discussed.The results indicated that SO〓〓 is combined with metal ions of TiO〓 in a chelating bidentate mode.

本文首次将SO〓〓/MxOy型固体超强酸催化剂用于光催化氧化有机污染物研究，采用溶胶-凝胶法制备了具有多孔性和大比表面结构的二氧化钛基固体超强酸光催化剂SO〓〓/TiO〓，以光催化降解溴代甲烷为模型反应，系统地研究了H〓SO〓浸渍处理对催化剂表面酸性及其气相光催化性能的影响，结合XRD、BET、XPS、FTIR、Hammett指示剂法、吡啶吸附红外光谱、NH〓-TPD、O〓-TPD、紫外可见漫反射光谱等多种表征手段，深入地讨论了超强酸化对TiO〓的改性机理，阐明了引起SO〓〓/TiO〓超强酸催化剂光催化降解溴代甲烷的转化率、表观反应速率常数和表观量子效率变化的本质原因。

The structural and photocatalytic properties of TiO〓 as well as surface acidity were greatly improved by sulfation. SO〓〓/TiO〓 solid superacid with Hammett constant Ho less than -12.14 was prepared by treating the TiO〓 with 1.0mol. L〓 sulfuric acid solution and then calcining at 450℃ for 3h. When compared to unmodified TiO〓, the SO〓〓/TiO〓 superacid catalyst exhibited higher anatase content, smaller crystal size, higher specific surface area, centralized pore size distribution, and the blue-shifted band edge of uv-vis adsorption spectra. Furthermore, the SO〓〓/TiO〓 superacid also showed excellent reaction activity and stability for CH〓Br photocatalytic decomposition even under the moist reaction conditions. The apparent quantum efficiency of SO〓〓/TiO〓 was 10 times of that of TiO〓 catalyst for the photocatalytic degradation of bromomethane. Therefore, the SO〓〓/TiO〓 superacid catalyst is promising for practical application in environmental remediation.It was found that both L and B acid sites exist on SO〓〓/TiO〓 photocatalyst while only L acid sites on TiO〓 photocatalyst. On the basis of experimental results, the synergistic model of superacidic centers was proposed for SO〓〓/TiO〓 photocatalyst to explain the photocatalytic behavior and the mechanism of superacidifing effects, assuming that the adjacent L and B acid sites induced by SO〓〓 comprise cooperatively the superacidic center on superacid photocatalyst. The group cooperation of the superacidic center could strengthen the surface acidity, increase surface acid sites and the adsorbtion of O〓, promote separation of photogenerated electron-hole pair, enhance the interfacial transfer of charges and reversibility of water adsorption. Consequently the excellent photocatalytic activity, reaction stability and resistibility to humidity of SO〓〓/TiO〓 superacid photocatalyst may attributed to the group cooperated effect of the superacidic center on the photocatalyst.

研究结果表明：SO〓〓与TiO〓表面的结合为螯合式双配位结构；TiO〓光催化剂表面经H〓SO〓浸渍处理后，提高了表面酸性，改善了催化剂结构和光催化性能，当H〓SO〓浸渍浓度为1.0mol.L〓、烧结温度为450℃时，可制得SO〓〓/TiO〓超强酸催化剂(H〓＜-12.14)，其结构和光催化活性得到明显改善，与TiO〓相比，SO〓〓/TiO〓光催化剂的锐钛矿含量高、晶粒小、BET比表面积大、孔径分布集中、光谱吸收边蓝移，具有优异的光催化氧化活性、稳定性及抗湿性能，光催化降解溴代甲烷的表观量子效率比TiO〓催化剂提高了一个数量级，是一种有实际应用前景的高效光催化剂；由此提出了SO〓〓/TiO〓超强酸催化剂表面集团协同作用的超强酸中心模型，认为在SO〓〓/TiO〓超强酸催化剂表面，由SO〓〓诱导的相邻L酸中心和B酸中心组成了集团协同作用的超强酸中心，其集团协同作用显著地增强了催化剂表面酸性、增大了表面酸量及O〓吸附量、促进了光生电子和空穴的分离及界面电荷转移，具有可逆吸附水的性能，是SO〓〓/TiO〓超强酸催化剂具有优异的光催化氧化活性、很好的活性稳定性及抗湿性能的重要原因。

The apparent quantum efficiency of SO〓〓/TiO〓 was 10 times of that of TiO〓 catalyst for the photocatalytic degradation of bromomethane. Therefore, the SO〓〓/TiO〓 superacid catalyst is promising for practical application in environmental remediation.It was found that both L and B acid sites exist on SO〓〓/TiO〓 photocatalyst while only L acid sites on TiO〓 photocatalyst. On the basis of experimental results, the synergistic model of superacidic centers was proposed for SO〓〓/TiO〓 photocatalyst to explain the photocatalytic behavior and the mechanism of superacidifing effects, assuming that the adjacent L and B acid sites induced by SO〓〓 comprise cooperatively the superacidic center on superacid photocatalyst. The group cooperation of the superacidic center could strengthen the surface acidity, increase surface acid sites and the adsorbtion of O〓, promote separation of photogenerated electron-hole pair, enhance the interfacial transfer of charges and reversibility of water adsorption. Consequently the excellent photocatalytic activity, reaction stability and resistibility to humidity of SO〓〓/TiO〓 superacid photocatalyst may attributed to the group cooperated effect of the superacidic center on the photocatalyst.

研究结果表明：SO〓〓与TiO〓表面的结合为螯合式双配位结构；TiO〓光催化剂表面经H〓SO〓浸渍处理后，提高了表面酸性，改善了催化剂结构和光催化性能，当H〓SO〓浸渍浓度为1.0mol.L〓、烧结温度为450℃时，可制得SO〓〓/TiO〓超强酸催化剂(H〓＜-12.14)，其结构和光催化活性得到明显改善，与TiO〓相比，SO〓〓/TiO〓光催化剂的锐钛矿含量高、晶粒小、BET比表面积大、孔径分布集中、光谱吸收边蓝移，具有优异的光催化氧化活性、稳定性及抗湿性能，光催化降解溴代甲烷的表观量子效率比TiO〓催化剂提高了一个数量级，是一种有实际应用前景的高效光催化剂；由此提出了SO〓〓/TiO〓超强酸催化剂表面集团协同作用的超强酸中心模型，认为在SO〓〓/TiO〓超强酸催化剂表面，由SO〓〓诱导的相邻L酸中心和B酸中心组成了集团协同作用的超强酸中心，其集团协同作用显著地增强了催化剂表面酸性、增大了表面酸量及O〓吸附量、促进了光生电子和空穴的分离及界面电荷转移，具有可逆吸附水的性能，是SO〓〓/TiO〓超强酸催化剂具有优异的光催化氧化活性、很好的活性稳定性及抗湿性能的重要原因。

The photoactive TiO2 was deposited on the surface of magnetic particles using sol-gel coating technique to prepare a novel nanometer-sized magnetic photocatalyst TiO2/SiO2/Fe3O4,and were characterized by means of XRD and TEM,with analysis of effects of calcining temperature and time,catalyst amount as well as radiant time on papermaking wastewater degradation.

采用溶胶-凝胶法，在磁性颗粒表面包覆TiO2，制备了易于固液分离的磁载光催化剂TiO2/SiO2/Fe3O4，通过XRD和TEM对产物的晶体结构、晶粒大小、形貌进行了表征，讨论了焙烧温度、焙烧时间、催化剂用量和光照时间等对TiO2光催化剂处理造纸废水的影响。

The results indicated that the effect that light catalysis oxidation treated leach was related to the kinds of catalyst, and the result of treatment using autanse-TiO2 is better than rutile. Catalysis capability is improved obviously after autanse-TiO2 was calcined at 600℃, and the way of calcine had large actions for catalysis.Photo-catalytic degradation of organic compound in leaches was carried out with TiO2,-Fe2O3 and ZnO,the following conclusion can be attained.

研究结果表明半导体光催化剂TiO2对垃圾渗滤液的光催化效果和TiO2的晶型有很大的相关性，锐钛型TiO2的光催化效果明显优于金红石型TiO2；高温处理锐钛型TiO2改变其晶型和表面结构，600℃煅烧TiO2的光催化活性有较大提高；光催化剂的活化方式亦影响光催化效果。

The problem in using titanium dioxide as a photocatalyst is recombination of electron and hole. One strategy for inhibiting theirs recombination is to add other electron accepters to the reaction. It can reduce the electron/hole recombination and then produce more ·OH on the surface of titanium dioxide, from which increased the degradation rate of the pesticide.

二氧化钛作为光催化剂进行光催化降解的问题在于电子—空穴对的重新复合，抑制其重新复合的一种办法是加入其他的电子接受体，减少电子—空穴对的复合，从而使光催化剂TiO2表面产生更多的·OH自由基，加强农药的光催化降解。

The result show that the N elements curbed the transition from anatase phase to rutile phase , Doped-N was in the structure of the TiO2 as the form of Ti-O-N and formed a new bond energy level;N-doped changed the paramagnetic of the characteristics. The paramagnetic resonance spectrum of TiO2 showed anisotropic and showed hyperfine splitting, The Lande factor of Ti3 + combined with the N is 1.956. UV-Vis absorption spectra showed that the photocatalytic ability of photocatalyst TiO2-xNx to expand to the visible region, the sample (3.84wt %) has the highest photo catalytic activity, the adsorption edge extend to 520nm and degradation is 55.54% under the visible light for 1.5h.

研究结果显示，N元素抑制了锐钛矿相向金红石相的转变，阻止了晶粒的长大，掺杂的N元素以O-Ti-N的形式存在于光催化剂结构中，形成了新的能级结构；N掺杂改变了催化剂的顺磁特征，使TiO2的顺磁共振谱线呈现各向异性，发生了超精细分裂，其中g2=1.956，是与N结合的Ti3+的朗德因子；紫外可见光吸收谱表明，催化剂TiO2-xNx的光响应能力拓展到可见光区，光吸收带发生红移；光催化测试结果显示，掺杂量为3.84的TiO2-xNx在可见光区的响应能力最高，吸收波长延伸至520nm，其光催化活性最大，1.5h降解率达到55.54%。

The following main results are obtained: The TiO_2 photocatalyst with small crystallite size, high surface area, narrow and uniform pore size distribution, and microporous frameworks could be prepared out by applying MW radiation in the preparation process. The microwave-induced fluorescence technique verified for the first time that microwave enhanced the formation rate of hydroxyl radical, leading to the increase in the photocatalytic efficiency. Compared with the conventional catalyst, TiO_2 prepared by MW dielectric heating owns a higher UV absorption ability, and its optical absorption edge and photovoltaic response are shifted toward the short wavelength region, resulting in increase of photooxidation efficiency. The photocatalytic conversion and the mineralization ratio of acetaldehyde are increased respectively by 30% and 40% over the TiO2 prepared by MW radiation when compared to the TiO2 prepared by the conventional heating. For the MW-assisted photocatalytic reaction over the MW-prepared TiO2, production of hydroxyl radicals is enhanced by 22.5%, and the photocatalytic conversion is accordingly increased by 20%. Similarlly, applying MW also increased the photocatalytic conversion and the mineralization ratio of acetaldehyde over TiO2/Al2O3 sample.

论文得到如下主要结果和结论：(1)微波介电加热TiO_2 溶胶可得到晶粒度小、光催化活性高、比表面积大和孔径分布窄而均一，且微孔发达的TiO_2光催化剂；在溶胶干燥处理过程中微波可使催化剂表面缺陷增加，进而导致光催化反应过程有更多的活性羟基自由基产生；(2)微波制备能显著增强TiO_2 样品的紫外光吸收率，并使其光吸收和光伏响应阈值发生蓝移，从而提高TiO_2的氧化还原能力；(3)与常规加热法所制TiO_2比较，微波法制备的TiO_2对乙醛的光催化降解转化率提高30%，CO_2生成率提高40%以上；(4)与未加微波辐射时相比，发现在光催化反应过程中施加微波，TiO_2 的羟基自由基生成速率提高了22.5%，相应CH_3CHO 光催化降解转化率提高了20%；对Al_2O_3/TiO_2催化剂，CH_3CHO 光催化降解转化率甚至提高了33%，同时CO_2 的生成率也都大幅度提高；(5)微波辐射可改变光催化降解乙醛的产物分布，推断施加微波时乙醛光催化降解按照羟基自由基引发的链式反应机理进行，微波&非热效应&起主要作用。

与光催化剂相关的网络解释 [注：此内容来源于网络，仅供参考]

photochemical blooming：光化热弥散

photochemical aerosol 光化学气溶胶 | photochemical blooming 光化热弥散 | photochemical catalyst 光催化剂

photocatalysis：光催化(作用)

photobleaching 光漂白 | photocatalysis 光催化(作用) | photocatalyst 光催化剂

photocatalyst：光触媒

光触媒(photocatalyst)是一类以二氧化钛为代表的具有光催化功能的半导体材料的总称. 以二氧化钛为例,它本身不溶于水,如果受到太阳光,也就是紫外线的照射,此时水再遇到它,水就会被分解为氧和氢. 所以说二氧化钛是一种非常优秀的光催化剂,

photocatalyst：光催化剂

photocatalysis 光催化 | photocatalyst 光催化剂 | photocathode 光 阴极

Coated photocatalyst：负载型光催化剂

镀铜石墨粉:copper coated graphite | 负载型光催化剂:Coated photocatalyst | 涂布系统:system of coated paper

Supported Photocatalyst：负载光催化剂

镍基催化剂:Ni-supported catalyst | 负载光催化剂:Supported Photocatalyst | 负载型金催化剂:supported gold catalyst

Supported Photocatalyst：负载型光催化剂

负载型钯催化剂:Supported palladium catalyst | 负载型光催化剂:supported photocatalyst | 负载型贵金属:Supported noble metal

immobilized photocatalyst：负载型光催化剂

固载化催化剂:immobilized catalyst | 负载型光催化剂:immobilized photocatalyst | 固定态二氧化钛:immobilized titanium dioxide

easily separated photocatalyst：易分离光催化剂

电荷分离态:Charge-separated state | 易分离光催化剂:easily separated photocatalyst | 覆岩离层:separated strata in overlying rock

photocatalyzer：光催化剂

photocatalyst 光催化剂 | photocatalyzer 光催化剂 | photocathode 光电阴极 光阴极