- 更多网络例句与使成环相关的网络例句 [注：此内容来源于网络，仅供参考]
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The Diels-Alder cycloadditions of [60] fullerene for preparation of optical limitingmaterials are discussed in chapter 3 and 6. Soluble cycloaddition derivatives of 〓aresynthesized by the reaction of 〓 with indene,1,1'-biindene andcyclopentadiene derivatives.〓Particular, the Diels-Alder cycloaddition of 〓 with1,1'-biindene under controlled conditions affords the stable monoadduct 〓〓of novel structure, which was confirmed by HPLC, FTIR, FD-MS,〓NMR,〓 NMR, HMQC and HMBC spectra, Its two bridgehead cage carbons resonate at70.91ppm, The 〓 NMR spectra showed 38 lines consistent with the 〓 symmetryassociated with [6,6] addition. The 〓 shows similar optical limitingproperties to that of 〓 in toluene for 8ns laser at wave length 532nm. Moreover, thehigh solubility of this adduct in polar solvents such as THF, acetone enables itsincorporation into sol-gel glass matrix. The thin films prepared via the sol-gel methodshow improved OL behaviour compared to those of 〓. The langmuir-Blodgett filmformation and uv-visible absorption of 〓 are also investigated. LBmonolayer of this compound is prepared on the air-water interface at 〓 mol/l. In chapter 4, three water-soluble derivatives of [60] fullerene: fullerol(1), theaddition product (2)of fullerol (1)with polyvinylpyrrolidone and fumaric acidderivative of 〓(3) are synthesized and characterized.
通过Diels-Alder环加成反应，用茚〓和1，1'-联茚〓及取代茂合成了一系列可溶性的〓环加成衍生物，发现可控制反应条件，使1，1'-联茚与〓反应，并高产率地得到具有新颖结构的单加成物，用HPLC、FTIR、FD-MS 及〓、HMQC、HMBC等多种波谱技术对其结构进行表征，测得它的两个〓杂化的桥头碳的化学位移为〓ppm，证明生成的衍生物为6∶6闭式环加成，〓NMR谱中共给出38个信号，表明〓联茚衍生物分子具有〓对称性；在波长532nm，脉冲宽度8ns的激光下，〓联茚衍生物的甲苯溶液的光限幅性能与〓的甲苯溶液相近，由于〓联茚单加成衍生物熱稳定性好，在四氢呋喃，丙酮等极性溶剂中溶解性好，能分别均匀地掺入溶胶-凝胶中，已发现它的溶胶(so1)光限幅性能优于纯〓的光限幅性能；使用Langmuir-Blodgett技术将〓联茚衍生物在空气和水的界面进行了LB单层膜和多层膜实验以及UV-Vis吸收谱研究，通过等温压缩曲线测试，证明浓度为〓〓时，〓联茚衍生物能够形成单层膜。
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Loop, a quasigroup with an identity elementLoop, an edge that begins and ends on the same vertexLoop, a path that starts and ends at the same pointProgram loop, a sequence of commands that is executed repeatedlyAn infinite loop is a sequence of instructions in a computer program which loops endlessly.
使成环， quasigroup 与身分元素圈，边缘，道路起动和结束在开始和结束在同样端点圈的同样点节目圈，命令序列一再被执行一个死循环是说明顺序在计算机程序不尽地使成环。
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Now, of course, looping or ADR is recorded using computer software.
现在， 当然，使成环或ADR 被记录使用计算机软件。
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The results showed that the amorphous iron oxide has highly catalytic activity. The intermediate products are pyrocatechin, hydroquinone, benzoquinone and low-grade fatty acid. The mechanism of catalyst oxidation is assumed that the free radical OH attacks benzene cycle at the adjacent position and para-position of OH on phenol so that the benzene cycle is opened and low-grade fatty acid is produced and transformed into CO2 and H2O.
结果表明，非晶铁氧化物催化剂在催化氧化降解苯酚时具有较高的催化活性，苯酚降解的中间产物有：对苯二酚、邻苯二酚、苯醌和低级脂肪酸，其降解机理是羟基自由基攻击苯环上OH的部位或对位而使苯环开环，生成低级脂肪酸，并最终转化成二氧化碳和水，从而使苯酚得以降解。
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Loop dying machines feed a rope of cotton yarn through vats of indigo dye and then back out.
通过大桶靛蓝染料使死的机器饲料成环棉纱品绳索然后取消。
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Being combining with products distribution in styrene oxidation, we propose the styrene epoxidation carry out with Ti metallacyclo intermediates, And at the same time Ti-ZSM-5 have properties both catalytic epoxidation and acid-catalysis, namely the skeletal Ti can catalyze styrene epoxidation to styrene oxide and the skeletal Ti and Al can provide Lewis acid site to cause the rearrangement of styrene oxide to phenylacetaldehyde rapidly, the solvolysis to glycols and the cleavage of C=C double bond. Ti-ZSM-5 can also provide Bronsted acid site simultaneously, which is also catalytic center for the solvolysis to glycols.
同时结合Ti-ZSM-5催化选择性氧化苯乙烯反应的产物分布结果，提出苯乙烯环氧化反应可能是通过金属有机环机理进行；Ti-ZSM-5同时具有催化环氧化和酸催化两种功能，其骨架钛可催化苯乙烯环氧化生成环氧苯乙烷，而骨架钛和骨架铝等可提供Lewis酸位使环氧苯乙烷迅速发生重排生成苯乙醛从而使其成为反应的主要产物，同时还可发生加成以及碳碳键的裂解等副反应：Ti-ZSM-5也提供Bronsted酸位，它也是生成加成产物的活性中心。
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Moreover,the selective oxidation of primary and secondary alcohols to corresponding carbonyl compounds with the multinuclear copper complexes Cul-Cu4 as catalysts have been conducted using TBHP and O_2/TEMPO,respectively.Among them,the copper complex Cu3 showed the best performance.On the performances of the two classes of oxidants,benzylic and heterocyclic alcohols could be effectively oxidized to carbonyl compounds.Specifically,the secondary alcohols could be effectively oxidized to ketones with excellent selectivity up to 100%in the presence of TBHP and the allylic alcohols could be effectively oxidized to aldehydes in the presence of O_2/TEMPO system.
实验结果还表明，在TBHP或O_2/TEMPO存在下，各配合物催化剂均能使各种取代芳香伯/仲醇以及杂环醇等以不同程度的转化率和选择性转化成相应的醛或酮，其中，配合物Cu3在O_2/TEMPO存在下可使苯甲醇和烯丙醇等以较高转化率和近100%的选择性转化成相应的醛，而对其它芳香醇和脂肪伯/仲醇等的催化性能则较差；在TBHP存在下，配合物Cu3则可使1-苯乙醇和其它仲醇以较高转化率和近100%的选择性转化为相应的酮，但对各类其它伯醇选择氧化的性能相对较差。
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The dissertation mainly consists of two parts:1. The Reaction Chemistry of Alkynes under Palladium Catalysis Part 1 studies the reaction α,β-unsaturated carbonyl compounds with alkenylpalladium intermediate generated by nucleopalladation, and discovered 1 the Pd-catalyzed tandem addition reaction of halides, alkynes and α,β-unsaturated carbonyls,2 the four-component tandem addition reaction of halides, alkynes and α,β-unsaturated carbonyls, 3 the tandem intramolecular oxypalladation-conjugate additionreaction of alkynoic acids with α,β-enals. These new reactions provide notonly efficient highly stereoselective methods for the synthesis of γ,δ-unsaturated,polyunsaturated carbonyl compounds and γ-lactonic aldehydes, but also thebasic transformations for a number of C-C bond formation reactions which can be usedto design synthesis of many acyclic, cyclic or polycyclic compounds.
本论文的主要工作分为两个部分：一、钯催化下炔烃的反应化学在本小组前人工作的基础上，我们详细研究了炔烃亲核钯化产生的烯基钯中间体与α，β-不饱和羰基化合物的反应，发现两价钯催化下卤离子-炔烃-α，β-不饱和醛酮的串联加成反应、卤离子-炔烃-α，β-不饱和醛酮的西组分串联加成及炔酸分子内氧钯化-串联Michael型加成反应；由此发展了γ，δ-不饱和醛酮、多不饱和羰基化合物和带有醛酮基侧链的γ-丁内酯衍生物的高立体选择性合成方法，这一过量卤离子存在下的烯基钯对α，β-不饱和羰基化合物共轭加成反应的发现，为大量碳-碳键形成反应的实现提供了基础，使我们能够从这一基本反应出发，设计和开发多种分子内、分子间的碳碳成键反应，以好的立体、区域选择性组建开链、环状及多环类型的化合物。
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One valley lied between two peaks(flower beginning period and fruit maturating period).When meeting blood serum,the electron on the ring B-C and A-C of quercetin molecule would move and make -OHs of Ring B and A ionizated and one anion with double negative charge would present.
遇到血清时，槲皮素分子结构中的B环和C环、A环和C环形成的两套共轭体系中的电子，发生转移并使酚羟基解离，形成带双负电荷的阴离子，此阴离子将与人血白蛋白结构中结合位点上的氨基酸残基以离子键的形式结合。
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Changed the two screws on the contact plate of the Halo-Vest to one screw,so that the Halo-Vest can fit extension-flexion movement and adapt the reduction of cervical spinal dislocation.Simultaneously,in order not to reduce the fixed funtion of the contact plate,which was designed in fan-shape.
将传统的Halo-Vest架头环与架子接板的双螺丝改为单螺丝，使不能伸屈的头环变为能够伸屈；将头环与接板的咬合面设计成扇形并且有放射状条纹，使头环能牢固地固定在任何一个伸屈角度上。
- 更多网络解释与使成环相关的网络解释 [注：此内容来源于网络，仅供参考]
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annull：使成无效
annuletroundlet 小环 | annull 使成无效 | annulmentdisestablishdisestablishmentdoffrescissoryvoidance 废除
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annull：使成无效/取消
annulet /小环/轮状环缘/ | annull /使成无效/取消/ | annulment /废除/取消/
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eyebolt：环首螺栓
在塑胶模座 (moldbase) 的各板上设置环首螺栓 (eyebolt) 用的螺攻 (tap) ,使模具加工组立时的移动搬运较为容易. 2. 为了防止小型温调等使用之 o 滑环 (link) 在组立时脱落或断裂,要考虑小型的形状及组立步骤,而设计成容易装设的配置.
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hematein：苏木红
但其溶液放置后,由于氧化作用使其成为一种有色的氧化苏木精,称苏木红(hematein),才成为一种染料. 所谓氧化,就是使苏木精分子结构失去两个氢原子,并在其中的一个苯环转化成具有一个醌型苯环的苏木红,这个过程又称成熟(ripening)醌型苯环是一个发色团,
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epoxy resin：环氧基树脂
此产品专为奥运局的单一距离(70公尺)而生产,其材质最外缘为碳纤维(Carbon)及环氧基树脂(Epoxy resin),中层为使碳纤维与内层的铝合金能粘固由EASTON独自研发的特殊物质,箭杆的形状成樽型,有如田径场上的标枪,头尾较细,中间部份比较粗,
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roundline：大环索
rounding 圆形的;使成圆形 | roundline 大环索 | roundly 迅速地;完全