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Two kinds of sulfonium salt s as photo-acid generator possess high thermo-decomposition temperature and good solubility in some organic solvents.
对合成的两种新型锍鎓盐光生酸剂进行了基本物性考察,表明它们有较高的热分解温度和在常用有机溶剂中有较好的溶解性,并考察了其在405、365nm 下乙腈中的分解及产酸性能。
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The characteristics of non-azide compositions including high nitrogen compounds such as tetrazoles,guanidine,improved thermites,oxidants,binders and process assistants are discussed.Because of their advantages such as adjustable burning rate,nontoxicity and high gas yield,non-azide gas generant to replace azide gas generant will put into use widely.
对出现的四唑类、胍类、铝热剂类等非叠氮配方的高氮化合物燃料、氧化剂、黏合剂、工艺助剂等特点和发展做了总结和讨论,指出非叠氮高氮化合物有无毒、燃速范围宽、产气量大、燃温低等优点,正在取代叠氮配方燃气发生剂,得到广泛应用。
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Study result suggest: The change of stock in RFCCU directly affect gasoline content. Gasoline content can be reduced through increasing the equilibrium activity of catalyst, controlling reaction level, increasing recirculating rate of gasoline and stability of gasoline level. Conclusions drawn from experiment is that optimization of operating condition has great effect on lowering olefine content of gasoline which can be reduced from 60% to 50%.Reducing reaction temperature is useful for lowering olefine content of gasoline, when the reaction temperature is raised, thermal cracking rate is higher than catalytic cracking rate, so that olefine content is increased. Raising catalyst-to-oil ratio is good for lowering olefine content. With conversion rate increased, the yield of LPG and coke is raised, the yield of gasoline is increased firstly and then decreased slightly, hydrogen transfer index is increased, so the olefine content is decreased.
研究结果表明:催化裂化装置的原料的变化直接影响到催化汽油的烯烃含量;可以通过优化催化装置的操作条件来降低催化汽油中的烯烃含量,其中通过提高催化剂平衡活性、控制反应深度、增加汽油回炼量、汽油深度稳定可以降低催化汽油烯烃含量,优化工艺条件对降低催化汽油烯烃含量有较大作用,汽油烯烃含量由60%降至50%左右;降低反应温度有利于降低催化汽油的烯烃含量,当反应温度的提高,热裂化反应速度提高的幅度大于催化裂化反应速度提高的幅度,汽油烯烃含量增加;剂油比的提高有利于降低催化汽油的烯烃含量,转化率提高,液化气产率提高,汽油收率先增加后略有下降,焦炭产率增加,氢转移反应指数提高,汽油烯烃含量下降;反应时间对产品分布及汽油烯烃含量有影响,增加提升管反应时间,液化汽、汽油产率提高,干气和焦炭产率增加。
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There are a few defects in existing processes of biomass gasification, for example using air as gasifying medium, N2 and tar content of the gas is high, and the calorific value is as low as 5000kJ/N in3. The technology of a circulating fluidized bed is still tentative at laboratory level. Through direct pyrolyze biomass, we can get product gas with high heating value (l4000kJINm3), but gas yield ratio is low (O.35m3/kg).
目前的生物质热解气化技术的现状是:以空气为气化剂的气化方式,得到的气体N_2和焦油含量高,热值一般在5000kJ/Nm~3左右;流化床气化工艺操作复杂,推广应用存在较多困难;直接干馏热解,虽气体的热值高(14000kJ/Nm~3),但产气率低(0.35m~3/kg)。
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The high activity can be attributed to the following factors: 1 Because of the perovskite structure of the host materials, the positive and negative electric charge center is not superposable, and there is a electric field which can separate the photo generated electrons and holes efficiently in the microscopic field.
以层状基质热稳定性分析为依据,经过对制备方法的优化,在不同温度下进行硫化处理,在对催化剂进行产氢性能研究时发现,在以硫化钠和亚硫酸钠为牺牲剂的产氢体系中,插入硫化镉的复合层状催化剂负载一定量铂以后,具有较高的连续的光催化分解水的能力。
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The thermal property studies indicate that the mass loss of compound B was 54.39% at 242.2~750℃, and when the temperature was 1000℃, there was 25.11% char residue left, which showed that the title compound has a good thermal stability and char forming capability. Using acetonitrile as the solvent instead of trichloromethane or 1, 2-dichloethane gave higher yield. During the synthesis, the yield was very low when triethylamine was used as acid acceptor alone, and when a little amount of 4-dimethylaminopyridine was added at the same time, the yield could be 81%.
结果表明,所合成的化合物B的结构与预期的结构一致;热性能研究表明,化合物B在242.2~750℃质量损失为54.39%,1000℃时仍有25.11%的炭残渣,显示出优异的热稳定性和成炭性;在相同反应条件下,用乙腈作为溶剂的反应产率比使用氯仿和二氯乙烷为溶剂的高,并且在合成过程中,单独使用三乙胺作为缚酸剂时产率很低,而当同时加入少量4-二甲氨基吡啶时,产率可达81%。
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febrifacient:引起发热的病原, 产热剂 <单词词性>产热的
photoheliograph [天]太阳( 全色) 照相仪 | febrifacient 引起发热的病原, 产热剂 产热的 | althiomycin 异硫霉素
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photoheliograph:[天]太阳( 全色) 照相仪
sarpagine 蛇根精 | photoheliograph [天]太阳( 全色) 照相仪 | febrifacient 引起发热的病原, 产热剂 产热的