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The results show: the strongest bond is the Al-Al bond in the segregated cell without containing vacancy, where the Al atomic covalence radius is greater than that of Li atom in the cell; while the strongest bond is the Al-Li bond in the segregated cell containing vacancy, and the Al atomic covalence radius in the cell is less than that of Li atom. Since the difference of electronagativity between the Al and Li atoms is obvious, it is inclined to formed the Al-Li segregated cell of short range order structure in the condition of vacancy present. The short range order structure containing vacancy is probably the embryo or precursor structure of the metastable phase δ′(Al3Li). Because the strongest covalent bond in the Al-Li-vacancy segregated cell in alloy formed in quenching is the main strength reason for supersaturated solid solution of alloy. The bond net of succeeding precipitation of δ′(Al3Li) has the picture of anisotropic Al-Al bonding and the bond intensity enhanced. Since the δ′(Al3Li) is coherence with matrix, the bond net strength is enhanced by the precipitation of δ′(Al3Li) and so strengthen the alloy.
计算结果表明:不包含空位的偏聚晶胞的键络最强键为Al—Al键,其中Al原子的共价半径较Li原子的共价半径要大;而含空位的偏聚晶胞的最强键为Al—Li键, Al原子的共价半径要比Li原子的共价半径要小;在空位存在的情况下,由于Al原子与Li原子的电负性相差明显,促使Al和Li原子结合,倾向形成Al-Li短程序结构偏聚区,这种含空位的短程序结构很可能就是δ′(Al3Li)亚稳相的前兆结构和生长胚胎;由于Al-Li-空位有序偏聚晶胞的Al—Li键络比基体键络要强许多,因此,淬火过程中合金生成的Al-Li-空位偏聚晶胞对合金过饱和固溶体起主要强化作用;后续析出的δ′(Al3Li)亚稳相键络各项异性显著,键络强度明显提高;由于Al3Li与基体共格,其大量均匀弥散析出起到提升基体整体键络强度,同样对合金产生强化作用。
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The results show: the strongest bond is the Al-Al bond in the segregated cell without containing vacancy, where the Al atomic covalence radius is greater than that of Li atom in the cell; while the strongest bond is the Al-Li bond in the segregated cell containing vacancy, and the Al atomic covalence radius in the cell is less than that of Li atom. Since the difference of electronagativity between the Al and Li atoms is obvious, it is inclined to formed the Al-Li segregated cell of short range order structure in the condition of vacancy present. The short range order structure containing vacancy is probably the embryo or precursor structure of the metastable phase δ'(Al3Li). Because the strongest covalent bond in the Al-Li-vacancy segregated cell in alloy formed in quenching is the main strength reason for supersaturated solid solution of alloy. The bond net of succeeding precipitation of δ'(Al3Li) has the picture of anisotropic Al-Al bonding and the bond intensity enhanced. Since the δ'(Al3Li) is coherence with matrix, the bond net strength is enhanced by the precipitation of δ'(Al3Li) and so strengthen the alloy.
计算结果表明:不包含空位的偏聚晶胞的键络最强键为Al-Al键,其中Al原子的共价半径较Li原子的共价半径要大;而含空位的偏聚晶胞的最强键为Al-Li键,Al原子的共价半径要比Li原子的共价半径要小;在空位存在的情况下,由於Al原子与Li原子的电负性相差明显,促使Al和Li原子结合,倾向形成Al-Li短程序结构偏聚区,这种含空位的短程序结构很可能就是δ'(Al3Li)亚稳相的前兆结构和生长胚胎;由於Al-Li-空位有序偏聚晶胞的Al-Li键络比基体键络要强许多,因此,淬火过程中合金生成的Al-Li-空位偏聚晶胞对合金过饱和固溶体起主要强化作用;后续析出的δ'(Al3Li)亚稳相键络各项异性显著,键络强度明显提高;由於Al3Li与基体共格,其大量均匀弥散析出起到提升基体整体键络强度,同样对合金产生强化作用。
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In thepreparation of nickel sulfides, nanocrystalline NiS〓 was prepared by solvent-thermaltechnology. By adding a reductive atmosphere in the system, hexagonal phase NiS,which is a metaphase and stable at high temperature, was formed. TEM shows that theparticles are in nanorod shape.
在甲苯中合成了球形的NiS〓纳米粉,并通过还原气氛的调节制备出NiS亚稳相的纳米棒(1000x15nm),通过前驱物的改变,我们在还原性气氛中还制备出Ni〓S〓纳米粉;同时我们在实验中还发现溶剂对产物的形貌有很大的影响,在乙二胺中作溶剂,分别得到立方形CoS〓和NiS〓及FeS〓纳米棒。
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Both the parent and martensite phases of Cu-based shape memory alloys are metastable phases whose metastability or aging effects are one of the key problems to be solved in applications of the alloys.
铜基形状记忆合金的母相和马氏体均为有序亚稳相,其亚稳性或时效效应是影响合金应用的关键问题之一。
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Both the parent and martensite phases of Cu-based shape memory alloys are metastable phases whose metastability or aging effects a...
铜基形状记忆合金的母相和马氏体均为有序亚稳相,其亚稳性或时效效应是影响合金应用的关键问题之一。
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Our double-potential well model explains the fact that the grain size affects the barrier height and therefore changes the relaxation characteristics and the structural metastability.
我们利用双势阱模型解释了这样一个事实:晶粒尺寸影响了势垒高度,这样改变了弛豫特征和结构亚稳性。
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This article discusses the causes of metastable problems in PLDs and presents a reliable and convenient test scheme of PLDs'metastable performance. Metastability ; MTBF ; Test ; PLD
但是,在用PLD实现系统芯片(SoC,SystemOnChip)设计时,不可避免会出现多时钟域情况和异步输入情况,这将导致器件的亚稳态问题,成为影响芯片性
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To investigate the pitting and metastable pitting rules of type 304 stainless steel, potentiodynamic polarization method was employed to study the behavior of metastable pitting and stable pitting on 304 stainless steel in sodium bromide solution and borate/phosphate buffered bromide solutions. The influence of the concentration of Br-、the pH value、the buffer capacity and general environmental factor to pitting potential and metastable pitting was studied as well.
为了更深入地了解304不锈钢的稳态及亚稳态孔蚀规律,本文采用动电位慢扫描法测得了304不锈钢的阳极极化曲线,研究了不锈钢在纯溴化钠溶液及含溴化钠的硼酸盐或磷酸盐缓冲溶液中的亚稳态孔蚀以及稳态孔蚀行为,分析了溴离子浓度、pH值、缓蚀性阴离子、以及缓冲容量和综合环境因子对孔蚀电位以及亚稳态孔蚀特征参数中的形核数目、峰值电流、生长寿命的影响。
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In addition, molecular orientation behaviors induced by shearing, electric field and magnetic field were investigated. The space group of the monomers A3EO7 and A9EO7 were determined as P2〓2〓2 and P112/m by means of electron diffraction and X-ray diffraction. Liquid crystalline properties of the monomer and the polymer were studied using DSC, variable X-ray diffraction, TEM and polarized optical microscope. Both monomers exhibit monotropic liquid crystalline behavior, and they also give a metastable phase on the cooling process. The polymer PA9EO7 shows enantiotropic liquid crystalline properties. Thus the rigid polymer backbone is not a fatal defect that completely distorts the packing arrangement of the mesogenic moiety in the side chain liquid crystalline polyacetylene.
结合电子衍射倾转方法和粉末X射线衍射技术,确定了两个液晶小分子A3EO7和A9EO7的晶胞参数和空间群,采用Cerius〓模拟软件,运用分子模拟的方法给出了小分子在晶胞中的排列方式;利用DSC、变温X射线衍射技术和透射电子显微镜研究了小分子和聚合物的液晶态,单体A3EO7和A9EO7表现出单向液晶性质,并且在降温过程中都表现出一个亚稳液晶相或亚稳结晶相,聚合物PA9EO7具有双向液晶性;采用偏光显微镜和X射线平板照相技术,研究了剪切和电场对聚合物分子取向的影响,在不同的液晶态,剪切作用对聚合物PA9EO7具有不同的诱导取向结果,直流电场可以诱导聚合物联苯液晶基元沿施加电场方向取向。
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Following the theoretical analysis, binary and ternary miscibility gap have been systemaiically calculated by the CVM. In particular the critical temperatures were deduced in the CV-pair approximation; A method for deriving energy of atomic pair from the mixing enthalpy or the excess Gibbs energy in the Subregular Solution Model was developed.
通过巨势几何性质的分析,明确了开系中巨势、有效化学势和偏摩尔Gibbs自由能的定量关系,建立了一种以巨势以及有效化学势相等为判据计算两相平衡的新方法,使开系与闭系中任意模型描述的稳态与亚稳态相平衡计算均可以通过求巨势—有效化学势曲线的交叉点来实现,从而避免了相平衡最优化计算方法中的收敛性问题。
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allelotropism:互引性
allelotrope 稳变异构体 | allelotropism 互引性 | alleluia 哈利路亚赞美词
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menopausal syndrome:更年期综合征
Meniere's Syndrome 耳源性眩晕症 | Menopausal Syndrome 更年期综合征 | Metastable Energy Level 亚稳能级