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P28 紫色 Formation of a peptide bond 肽键形成–4侧链具有的反应–形成二硫键-其它反应 Tyr,His,Arg Review Isoelectric Point Titration滴定 of an amino acid 滴定 Gly幻灯片 18 His Lys Glu Reaction of amino acids Section 4 Protein isolation and purification 蛋白质分离及提纯 Working With Proteins Experimental techniques for protein analysis and characterization Purification steps A cell contains many types of proteins In the lab we want to isolate a single protein for experiments Purification steps We first grow cells or isolate tissues that contain the protein of interest We break open the cells to produce a crude extract Use centrifugation离心 to separate soluble from insoluble material We fractionate 分离 the protein mixture based on properties of such as size, charge affinity or solubility.
丹磺酰氯与氨基酸反应生成荧光性质强和稳定的磺胺衍生物,用于多肽链NH 用于多肽链 3末端氨基酸的标记烃基化反应(1) 2,4-二硝基氟苯2,4-dinitrofluorobenzene,二硝基氟苯(二硝基氟苯 DNFB也叫做试剂。DNFB在弱碱性溶液也叫做Sanger试剂试剂中与氨基酸发生取代反应,生成黄色化合物二硝基二硝基苯基氨基酸(dinitro phenyl amino acid, DNP氨基酸氨基酸)苯基氨基酸氨基酸(2)苯异硫氰酸酯(phenylisothiocyanate, PITC)在弱碱性条件下,与氨基酸反应在弱碱性条件下,生成苯乙内酰硫脲 PTH衍生物,(phenylthiohydantoin, PTH)衍生物,即PTH-氨基酸,此反应又称之Edman反应,该反应是蛋白质或多肽氨基酸序列测定常用的反应。
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A cyanide-free silver electroplating process with 5,5-dimethyl hydantoin as coordination agent is studied.
研究了5,5-二甲基乙内酰脲为配位剂的无氰镀银工艺。
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Technical characteristics and existing problems of cyanide-free silver plating technology were summarized through the analysis of cyanide-free silver plating systems of thiosulfate,succinimide,iodide,hydantoin,sulfite and others.
通过对硫代硫酸盐、丁二酰亚胺、碘化物、乙内酰脲、亚硫酸盐以及其它无氰镀银体系的分析,总结了当前无氰镀银工艺的技术特点及存在的问题,并阐述了无氰镀银技术的发展历程和研究现状。
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Analytical results showed that the upper clear liquid of pyrolysis oils was mainly consisted of water-soluble substances,such as phenol,cresol,xylenol,sugars,hydantoins,morpholines,pyranones and pyridine derivatives compounds,etc.,while the lower sediment was mainly insoluble or hardly water-soluble substances,such as the big substituent phenolics(the number of substituent carbon atoms of which is greater than or equal to 2),aryl phosphate esters,fatty acid esters and nitrile compounds,and so on.
研究表明,热解油上层清液主要是一些较易溶于水的物质,如苯酚、甲酚、二甲酚、糖类、乙内酰脲类、吗啉类、吡喃酮类和吡啶类化合物等;而下层沉淀则主要为不溶或难溶于水的物质,如大取代基酚类(取代基碳原子数≥2)、磷酸三芳基酯类、脂肪酸酯类和腈类化合物等。
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In this thesis, two series compounds of thiadiazole (2a~2f) and benzothiazole (5a~5f) were synthesized by using the reagent of iodobenzene diacetate. We also bound the iodobenzene diacetate reagent to the resin and applied it to synthesize thiadiazole and benzothiazole compounds.
本文利用二醋酸碘苯试剂分别与1-芳甲酰基-5-芳基-2-硫代缩二脲及1-芳甲酰基-3-芳基硫脲反应合成了噻二唑(2a~2f)和苯并噻唑(5a~5i)两个系列的杂环衍生物,并通过把二醋酸碘苯负载在高分子上合成了一类新型的固相氧化剂,同时考查了该固相氧化剂在噻二唑,苯并噻唑类化合物合成中的应用以及该固相氧化剂的循环使用。
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A series of 2-oxocyclododecyl sulfonylurea s have been synthesized from 2-oxocyclododecylsulfonamide via acylation of phenyl chloroformate and amination.
以环十二酮为起始原料,经磺化反应制备得到2-氧代环十二烷基磺酸盐B,B经过氯化和胺解反应制备得到2-氧代环十二烷基磺酰胺C,C经过苯氧酰化与胺解反应后合成了10个新的2-氧代环十二烷基磺酰脲类化合物D,它们的结构通过了1HNMR和IR的确证。
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Ingredients: Water,Lauric Acid,Myristic Acid,Stearic Acid,Propylene Glocol,Potassium Hydroxide,Cocamidopropyl Betaine,Starch Hydroxypropyltrimnium Chloride,Sodium Laureth Sulfate,Glycol Distearate,Lavandula Angustifolia Oil,Creatine,Tetrasodium Edta,Perfume,Dmdm Hydantoin.
成分: 去离子水,月桂酸,肉豆蔻酸,硬脂酸,丙二醇,氢氧化钾,椰油酰胺丙基甜菜碱,淀粉羟丙基三甲基氯化铵,月桂醇聚醚硫酸钠,乙二醇双硬脂酸酯,薰衣草精油,肌酸,乙二胺四乙酸四钠,香精,DMDM 乙内酰脲。
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The preliminary bioassays indicated that, at 500 g/mL, 1-(o-tolyl-4-(4-chloro-3-ethyl-1-methylpyrazol-5-ylcarbonyl)semicarbazide (4g) and 1-(2,4-dimethyl- phenyl)-4-(4-chloro-3-ethyl-1-methylpyrazol-5-ylcarbonyl)semicarbazide (4k) showed inhibitory activities 90% and 80% against Blumeria graminis, respectively; and at 25 g/mL, 4-phenyl-4-(4-chloro-3-ethyl-1- methylpyrazol-5-ylcarbonylsemicarbazide (4c) showed inhibitory activity 70.1% against Botrytis cinerea and 1-2-nitro-phenyl-4-(4-chloro-3-ethyl-1-methylpyrazol-5-ylcarbonylsemicarbazide (4d) showed inhibi-tory activitiy 51.3% against Pyricularia oryzae.
初步生物活性实验结果表明,在500 mg/mL浓度下,化合物1-(4-氯-3-乙基-1-甲基-1H-吡唑-5-甲酰基)-4-(2-甲基苯基)氨基脲(4g), 1-(4-氯-3-乙基-1-甲基-1H-吡唑-5-甲酰基)-4-(2,4-二甲基苯基)氨基脲(4k)对小麦白粉病菌的抑制率分别达到90%和80%;在25 mg/mL浓度下,化合物1-(4-氯-3-乙基-1-甲基-1H-吡唑-5-甲酰基)-4-苯基氨基脲(4c)对黄瓜灰霉病菌的抑制率达到70.1%;化合物1-(4-氯-3-乙基-1-甲基-1H-吡唑-5-甲酰基)-4-苯基氨基脲(4c)和1-(4-氯-3-乙基-1-甲基-1H-吡唑-5-甲酰基)-4-(2-硝基苯基)氨基脲(4d)对稻瘟病菌的抑制率均达到51.3%。
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The results of biological tests indicated that, at 25 g/mL, 1-(4-bromo-3-ethyl-1-methyl-pyrazol-5'-ylcarbonyl-4-(2-nitrophenyl) semicarbazide (4d) showed inhibitory activities (52.6%) against Pyricularia oryzae. 1-(4-bromo-3-ethyl-1-methyl-pyrazol-5'-ylcarbonyl)-4-(3-chlorophenyl) semicarbazide (4j), 1-(4-bromo-3-ethyl-1-methyl-pyrazol-5'-ylcarbonyl)-4-(2,4-dimethylphenyl) semicarbazide (4k), 1-(4-bromo-3-ethyl-1-methyl-pyrazol-5'-ylcarbonyl)-4-(3,4-dimethyiphenyl) semicarbazide (41) and 1-(4-bromo-3-ethy-1-methyl-pyrazo1-5'-ylcarbonyl)-4-(2,4-difluorophenyl) semicarbazide (4m) showed inhibitory activities (45.6%) against Pyricularia oryzae, repestively.
初步生物活性实验结果表明,在25μg/mL浓度下,1-(1-甲基-3-乙基-4-溴-5-吡唑甲酰基)-4-(2-硝基苯基)氨基脲(4d)对水稻稻瘟病菌Pyricularia oryzae抑制活性达到52.6%;1-1-甲基-3-乙基-4-溴-5-吡唑甲酰基)-4-(3-氯苯基)氨基脲(4j,1-(1-甲基-3-乙基-4-溴-5-吡唑甲酰基)-4-(2,4-二甲基苯基)氨基脲(4k),1-(1-甲基-3-乙基-4-溴-5-比唑甲酰基)-4-(3,4-二甲基苯基)氨基脲(41)和1-(1-甲基-3-乙基-4-溴-5-吡唑甲酰基)-4-(2,4-二氟苯基)氨基服(4m)对水稻稻瘟病菌Pyricularia oryzae抑制活性达到45.6%。
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Firstly, phenyliodine diacetate was immobilized to the 2% cross-linked polystyrene or the liner polystyrene resin. The more iodine the resin had, the lower conversion to phenyliodine diacetate. We made our endeavor to extend the range of useful application of polystyrene supported phenyliodine diacetate in organic synthesis:(1) the reagent was used as an effective reagent of carbonyl regeneration from oximes and semicarbazones of ketones.(2) the reagent was also applied to the synthesis of 1, 3, 4-oxadiazoles, 1, 3-disubstituted-2-pyrazoline, 2-arylbenzoxazole from aldehyde N-acylhydrazones, aldehyde hydoazones and phenolic Schiff's bases respectively.
首先,我们以2%交联的聚苯乙烯和线性的聚苯乙烯树脂为载体,制备了聚合物负载的二醋酸碘苯,通过研究发现:(1)聚苯乙烯二醋酸碘苯是酮肟、缩氨脲有效的去保护试剂,不仅芳香酮,脂肪酮和α,β不饱和酮的肟、缩氨脲也能顺利转化为相应的酮,实现酮基的再生;(2)我们还利用此试剂,分别与醛的N-酰基苯、N-酰基苯腙及邻羟基芳亚胺反应,在温和的条件下发生成环反应,以良好的产率生成1,3,4-噁二唑、吡唑啉和二取代苯并噁唑等杂环化合物;(3)聚苯乙烯二醋酸碘苯还可有效地将邻羟基芳酮的酰腙经氧化、重排成1,2-二酰基苯。
- 更多网络解释与二酰脲相关的网络解释 [注:此内容来源于网络,仅供参考]
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Barbital Sodium:巴比妥钠;二乙基丙二酰脲钠
巴比妥;二乙基丙二酰脲 barbital | 巴比妥钠;二乙基丙二酰脲钠 barbital sodium | 巴比妥酸;丙二酰脲;嘧啶三酮 barbituric acid; malonyl urea
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diethylmalonylurea; barbitone; barbital:二乙基丙二酰脲;巴比妥
二乙基酮醇 diethylketol | 二乙基丙二酰脲;巴比妥 diethylmalonylurea; barbitone; barbital | 二乙亚硝胺 diethylnitrosamine
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malonylurea; barbituric acid:丙二酰脲;巴比妥酸
脲羰乙酸 malonuric acid | 丙二酰脲;巴比妥酸 malonylurea; barbituric acid | 氢化麦芽糖 maltitol
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tartronylurea; dialuric acid; 5-hydroxybarbituric acid:羟丙二酰脲;丙醇二酰脲;5-羟巴比妥酸
羟丙二酸;丙醇二酸 tartronic acid | 羟丙二酰脲;丙醇二酰脲;5-羟巴比妥酸 tartronylurea; dialuric acid; 5-hydroxybarbituric acid | 四甲锡 tatramethyl stannane; tetramethyltin
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malonylurea:丙二酰脲 巴比土酸
malonyl 丙二酰 丙二酰基 | malonylurea 丙二酰脲 巴比土酸 | maloperation 不正确操作 不正确维护
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murexan:氨基丙二酰脲
blower casing 压气机罩壳 | murexan 氨基丙二酰脲 | summer normal [美]暑期师资训练班
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murexan:氮其丙二酰脲
Murex purpurea 紫螺 | murexan 氮其丙二酰脲 | murexin 紫螺毒素
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oxalylurea:乙二酰脲
oxalylchloride 乙二酰氯 | oxalylurea 乙二酰脲 | oxamicacid 草氨酸
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uramil:胺巴比妥酸;胺丙二酰脲
阿大灵 uradal; adalin | 5-胺巴比妥酸;胺丙二酰脲 uramil | 尿甾烷 urane
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barbituric acid; malonyl urea:巴比妥酸;丙二酰脲;嘧啶三酮
巴比妥钠;二乙基丙二酰脲钠 barbital sodium | 巴比妥酸;丙二酰脲;嘧啶三酮 barbituric acid; malonyl urea | 乙酸钡;醋酸钡 barium acetate