二苄基

基本解释 (translations)

dibenzyl

与二苄基相关的网络例句 [注：此内容来源于网络，仅供参考]

In part one, the reactions of some active fluorine-containing compounds such as 2, 2-dihydropolyfluoroalkanoic acids and ethyl 2-hydropolyfluoroalkenoates were studied and various fluorine-containing heterocyclic compounds were synthesized. Using 2, 2-dihydropolyfluoroalkanoic acids as the starting material, 4-fluoroalkyl quinolin-2-ols, 2- [ -1-hydropolyfluoro-1-alkenyl] -4H-3, 1-benzoxazin-4-ones, 1-aryl -4, 9-dihydro-3-fluoro-alkyl-1H-pyrazo [3, 4-b] quinolin-4-ones, 5-fluoroalkyl-12H-quin olino [2, 1-b] quinazolin-12-ones, 4-fluoroalkyl-1, 3-dihydro-1, 5-benzodiazepin-2-ones and 4-fluoroalkyl-2H-pyrido [1, 2-a] pyrimidin-2-ones were synthesized through its condensation reaction with anilines, anthranilic acid, N'-aryl-o-aminobenzamides, o-nitro aniline, o-amino pyridine and their derivatives and the subsequent transformations. 5-Fluoroalkyl isoxazolidines, 3-fluoro-3-fluoroalkylisoxazolidino [4, 3-c] quinolin-4-ones, 3-fluoroalkylisoxazolino [4, 3-c] quinolin-4-ones and 2-aryl-3per fluoroacylindoles were synthesized by inter-and intramolecular 1, 3-dipolar cycloaddition of fluorine-containing olefins and nitrones.

第二部分，我们研究了α，α-二氟苄基卤类化合物的亚磺化脱卤反应、产物的转化及全氟烷基亚磺酸盐与芳环化合物的全氟烷基化反应，发现全氟苄基碘或溴及α，α一二氟苄基溴在保险粉等亚磺化脱卤试剂引发下可生成相应的亚磺酸盐；全氟苄基亚磺酸盐与氯气或溴反应可生成全氟苄基磺酰氯或磺酰溴；在烯烃存在下，全氟苄基碘则与烯烃发生加成反应，生成相应的1：1加成产物；在三价醋酸锰的作用下，部分芳香化合物如茴香醚，二甲氧基苯，吡啶，喹啉等可以和过量的全氟烷基亚磺酸盐发生双全氟烷基化反应，反应表现出一定的区域选择性，产率良好。

Five Butenafine's analogues were designed and synthesized according to the structure-activity relationship and operating mechanism of benzylamine antimycotics.

根据苄胺类抗真菌化合物的构效关系、作用机理，设计合成了 5个布替萘芬类似物，N (2 氯 5 吡啶甲基) N 甲基 1 萘甲胺，N ，N 二(4 叔丁基苄基) 1 萘甲胺，N (4 叔丁基苄基) N (2 氯 5 吡啶甲基) 1 萘甲胺，N ，N 二苄基 4 叔丁基苯甲胺，N (2 氯 5 吡啶甲基) N 苄基 4 叔丁基苯甲胺。

In the second part of the thesis, we discussed a L-proline-catalyzed direct Aldol reaction between L-amino acid-derived N,N-dibenzyl -amino aldehydes 15 and acetone, cyclopentanone or hydroxyacetone, which afforded (-amino--hydroxy- or (-amino-,(-dihydroxy-ketones in good to excellent yields (up to 94%) and diastereoseletivities (up to 94.9%).

发现许多情况下，反应的产率和de值超过90%。接着，在碱性条件下，我们将L-亮氨酸衍生的N，N-二苄基--氨基醛15g与羟基丙酮反应得到的主要产物(，-二羟基-γ-氨基酮171d与次溴酸钠反应，得到了具有抗肿瘤活性的天然产物PM-94128的氨基酸片断184。

The photodegradation of dibenzyl sulfone catalyzed by semiconductor TiO2 particles under UV irradiation was investigated.

以半导体TiO2为催化剂，对二苄基砜（ASO2A）进行光催化降解，研究降解二苄基砜的反应条件，讨论了TiO2为催化剂降解ASO2A的实质，初步确定反应机理。

Dibenzyl sulfoxide and dibenzyl sulfone were synthesized from dibenzyl sulfide oxidated with H 2O 2 without catalyst.

在无催化剂条件下利用过氧化氢氧化二苄基硫醚合成了二苄基亚砜和二苄基砜。

For the smelting slags of exhausted automobile catalyst, a method for determination of trace amounts of platinum and palladium by plus-dual-wavelength overlapping spectrophotometry in dibenzyl dithiooxamide-SnCl2 system was developed.

针对失效汽车催化剂火法熔炼渣，研究了采用正峰双波长叠加，二苄基二硫代乙二酰胺-SnCl2体系萃取光度法测定渣中痕量铂钯的方法。

This work, concentrated on the asymmetric allylation of aldehydes controlled by different chiral auxiliaries prepared from rotational pure tartaric acid, can be divided into three parts.The first part aims to review the developments of chiral drugs and asymmetric synthesis, from which derived the present research topic backgrounds and works.Synthesis and applications of allylation from aldehydes are the second part of the thesis. By optimizing the reaction conditions, such as solvents, temperature, time and chiral auxiliaries like N,N\'-dibenzyl tartamide, N,N\'-p-dimethylphenyl tartamide, N,N\'-o-dimethylphenyl tartamide, N,N\'-o-dichlorophenyl tartamide, N,N\'-a-dinaphyl tartamide, N,N\'-dicyclohexyl tartamide and N,N\'-diphenyl tartamide, ideal experimenttal conditions are obtained according to HPLC monitoring, as well as the auxiliaries\' recoveries experiments. Starting from benzaldehyde and 3-bromopropaldehyde, N,N\'-dibenzyl tartamide is considered the best auxiliary in this reaction.

本文介绍了醛的不对称烯丙基化反应，以光学纯酒石酸为原料，研究了不同构型手性配体在醛的烯丙基化反应中的立体选择性，全文共分三部分十个章节：第一部分对当前手性药物和手性技术进行了概述，并由此展开了本文的研究背景和任务；第二部分为有机合成部分，对醛的不对称烯丙基化反应进行了深入探讨，以苯甲醛为原料对反应条件进行优化，在优化的反应条件下对制备的七种可回收手性酰胺配体(N-苄基酒石酸二酰胺、N-对甲苯基酒石酸二酰胺、N-邻甲苯基酒石酸二酰胺、N-邻氯苯基酒石酸二酰胺、N-a-萘基酒石酸二酰胺、N-环己基酒石酸二酰胺和N-苯基酒石酸二酰胺)进行筛选，优化配体回收实验条件，最终确定出N-苄基酒石酸二酰胺在苯甲醛的不对称烯丙基化反应中具有较大优越性，结晶回收的手性配体光学纯度保持不变。

In 1903, D. Vorlander and co-workers found that treatment of dibenzylideneacetone with concentrated sulfuric acid and acetic anhydride followed by hydrolysis by sodium hydroxide yielded a cyclic ketol, the structure of which was unknown at the time.

1903年，D。 Vorlander和合作者发现，二苄基丙酮与浓硫酸及醋酸酐经过氢氧化钠水解后产生了当时还不知结构的环状酮醇。

The present dissertation reviews the total synthesis of biotin, particularly on Hoffmann-La Roche\'s Lactone-Thiolactone approach. The Lactone-Thiolactone approach is presently the most competitive commercial route, which gives an excellent illustration of the gradual construction of the functionalized skeleton with the simultaneous solution of the stereochemical issues in a minimal number of steps.In 1970, Gerecke etc. of Roche Corp.

论文对生物素全合成的文献进行了综述，重点讨论了目前工业上最有竞争力的内酯—硫代内酯路线，展示了生物素是如何以最少的步骤去逐步构建目标产物的官能团骨架并同时解决立体化学问题的。1970年，Roche公司的Gerecke等报道了一条通过手性内酯，以较高收率并保持构型得到手性硫代内酯，从而直接合成d-生物素的方法后，该中间体内酯(3aS，6aR)-1，3-二苄基。

Fungicide DDSCwas synthesized from tin powder,benzyl chloride and N,N-dimethyldodecylamine via two steps reaction.

以锡、氯化苄和二甲基十二烷基叔胺为原料，经过两步反应，合成了新型杀生剂二苄基二氯化锡。

与二苄基相关的网络解释 [注：此内容来源于网络，仅供参考]

benzal chloride：亚苄基二氯 二氯甲基苯

benzal bromide | 亚苄基二溴 二溴甲基苯 | benzal chloride | 亚苄基二氯 二氯甲基苯 | benzal chloroaniline | 亚苄基氯苯胺 苯甲醛缩氯苯胺

dibenzyl：二苄基

dibazol 地巴唑 | dibenzyl 二苄基 | diborane 乙硼烷

dibenzyl disulfide：二苄二硫

dibenzoyl 联苯酰 | dibenzyl disulfide 二苄二硫 | dibenzyl dithiooxamide 二苄基二硫代草酰胺

dibenzyl disulfide：二硫二苄基

联苄 dibenzyl | 二硫二苄基 dibenzyl disulfide | [二]苄醚 dibenzyl ether; benzyl ether

dibenzyl phthalate：邻苯二甲酸二苄酯

dibenzyl ketone 二苄基甲酮 | dibenzyl phthalate 邻苯二甲酸二苄酯 | dibenzyl sulfide 二苄硫醚

dibenzyl ketone：二苄基甲酮

dibenzyl ehter 二苄醚 | dibenzyl ketone 二苄基甲酮 | dibenzyl phthalate 邻苯二甲酸二苄酯

dibenzyl ketone：二苄[基]酮

反丁烯二酸二苄酯 dibenzyl fumarate | 二苄[基]酮 dibenzyl ketone | 顺丁烯二酸二苄酯 dibenzyl maleate

dibenzyl sulfide：二苄硫

dibenzyl ketone 二苄基甲酮 | dibenzyl phthalate 邻苯二甲酸二苄酯 | dibenzyl sulfide 二苄硫

benzal chloride：亚苄基二氯 二氯甲基苯

benzal bromide || 亚苄基二溴 二溴甲基苯 | benzal chloride || 亚苄基二氯 二氯甲基苯 | benzal chloroaniline || 亚苄基氯苯胺 苯甲醛缩氯苯胺

stearyl dimethyl benzyl ammonium chloride：硬脂基二甲基苄基氯化铵

硬脂基二甲基苄基氯化铵和水辉石的反应产物 steaalkonium chloride hectorite | 硬脂基二甲基苄基氯化铵 stearyl dimethyl benzyl ammonium chloride | 硬脂基二甲基胺 dimethyl stearamine