- 更多网络例句与二原子金属的相关的网络例句 [注：此内容来源于网络，仅供参考]
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In the same central heteroatom systems, the redox reactivity of the systems substituted by the trivalent metal is higher than the systems substituted by bivalent metal.
在中心原子相同的体系中，三价金属取代的体系比二价金属取代的体系氧化还原能力强。
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We have studied the transition metal complexes catalyzed sequential cross coupling reactions of these new difunctional group reagents with electrophiles and nucleophiles, respectively; developed some convenient and practical new methods for the stereoselective synthesis of disubstituted alkenes, trisubstituted alkenes, conjugated dienes containing heteroatom, conjugated enyne containing heteroatom etc., enriching methodologies for organic synthesis.
继而研究了这些新型双官能试剂在过渡金属配合物催化下分别与亲电试剂、亲核试剂的顺序交叉偶联反应，为双取代烯烃、三取代烯烃、杂原子取代的共轭二烯烃、杂原子取代的共轭烯炔烃等的立体选择合成提供了方便实用的新方法，丰富了烯烃立体选择合成的方法学。
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In addition, by using bondtype and polyhedron cluster type index methods to analyze the transformation of the microstructure, not only the key role of icosahedron in amorphous formation and stability can be explained, but also the solidification processes and the configuration characteristic of amorphous metals understood deeply.
此外采用键对及原子多面体类型指数法对凝固过程中微观结构组态变化的分析，不但能说明二十面体结构在非晶态合金形成和稳定性中所起的关键作用，又有助于对液态金属的凝固过程、非晶态结构特征的深入理解。
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A catalyst composition for the polymerization of propylene comprising one or more Ziegler-Natta procatalyst compositions comprising one or more transition metal compounds and one or more esters of aromatic dicarboxylic acid internal electron donors; one or more aluminum containing cocatalysts; a selectivity control agent comprising at least one silicon containing compound containing at least one C1-10 alkoxy group bonded to a silicon atom, and one or more activity limiting agent compounds comprising one or more aliphatic or cycloaliphatic carboxylic acids; alkyl-, cycloalkyl- or alkyl-ester derivatives thereof; or inertly substituted derivatives of the foregoing.
一种用于丙烯聚合的催化剂组合物，所述催化剂组合物包括：一种或多种齐格勒-纳塔主催化剂组合物，该主催化剂组合物包括一种或多种过渡金属化合物和一种或多种芳族二羧酸酯内部电子给体；一种或多种包含铝的助催化剂；选择性控制剂，该选择性控制剂包括至少一种包含硅的化合物，该化合物包括至少一种与硅原子连接的C 1-10 烷氧基；和一种或多种活性限制剂化合物，该活性限制剂包括一种或多种脂族或脂环族的单或聚羧酸类、其烷基-、环烷基-或烷基-衍生物、或上述惰性取代的衍生物。
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In particular they discovered that the electrons in graphene behave like relativistic particles that have no rest mass and travel at about 106 metres per second.
石墨烯（Graphene，见 http：//www.wiki.cn/wiki/Graphene ）是由单一层碳原子构成的二维晶体，是一种结合了半导体和金属属性的新材料。
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The chapter two was focused on the samarium diiodide promoted organic reactions and their applications in organic synthesis, firstly, a new synthesis of highly substituted cyclopentadienes from a,β-alkynone promoted by samarium diiodide was investigated and the highly substituted cyclopentadienes were prepared in moderate to good yields under mild conditions. Secondly, the Michael addition and Michael-aldol tandem reaction of diorganyl diselenides or diorganyl disulfides with α,β-alkynones mediated by samarium diiodide were studied and a series of alkenylsulfides and alkenylselenides were prepared in good yields. Then the highly regioselecfive nucleophilic addition of the allylsamarium bromide to α,β-alkynones were explored. We found that the allylsamarium bromide reacts with α,β-alkynones to afford regiospecificly 1. 2-nucleophilic addition products in good yields under mild condition. At last we studied the coupling reaction of aryl halides promoted by NiCl〓/PPh〓/Sm〓.
第二章 研究了二碘化钐、金属钐促进的有机反应：1、二碘化钐促进下α，β-炔基酮的偶联环化反应，提供了一种制备多取代环戊二烯的新方法；2、二碘化钐促进下的二硫醚、二硒醚与α，β-炔基酮的Michael加成反应，为高产率地制备多取代的烯基硫或烯基硒化合物提供了方便可靠的新方法；3、二碘化钐促进下的二硫醚、二硒醚与α，β-炔基酮和醛、酮的Michael—aldol串联反应，提供了一种一锅法高产率地制备多取代的含硫的烯丙基醇或含硒的烯丙基醇类化合物的方便可靠的原子经济性的新方法；4、烯丙基溴化钐与α，β-炔基酮的高度区域选择性的1，2-亲核加成反应；5、NiCl〓/PPh〓/Sm〓促进的卤代芳烃的偶联反应-一种从各种卤代芳烃制备联苯类化合物的有效方法。
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Five of their single crystals were obtained and their structures were determined by X-ray diffraction. By comparison, it was found that dithiocabamate complexes often formed an exactly planar MS4 unit, such as [Mo(R2dtc)2]; and also formed a special MS 5 unit, such as [Cu2(R2dtc)4], the copper atom lies in a distorted square-pyramidal environment.Four kinds of heteropoly acids were prepared and characterized; a series of solid superacid catalyst of supported heteropoly acid were prepared and characterized; regioselectivites of chlorobenzene mononitration with nitric acid with different heteropoly acid on different supports and reaction conditions have been investigated.
培养并解析了5个该类配合物的单晶结构，通过比较，发现二硫代氨基甲酸盐与过渡金属容易形成四配位结构，金属原子与4个硫原子共平面，比如二乙基二硫代氨基甲酸钼；也能形成比较特殊的五配位结构，比如二乙基二硫代氨基甲酸双核铜，Cu原子与5个S原子相连，处于一个变形的四方锥结构的配位环境。
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Several novel structures have been determined: Unique ninenuclear complexesincorporating 3d, 4f metals with a sodium ion center, the sodium ion may be serve as atemplate in the formation of these novel complexes; Novel tetranuclear 〓complexes with channels formed by intermolecular weak interactions; First 〓type tetranuclear complex; Peculiar "dimer of dimers" complexes derived frombinuclear complex; Unusual one-dimensional wave chain formed by weakcoordination bonds and hydrogen bonds and two dimensional coordination polymerconstructed through coordination bonds and hydrogen bonds.
1获得了多个文献首报和罕见的特殊结构的配合物：两个同时含有碱金属-过渡-稀土金属的独特的九核配合物；两个具有孔道的稀土-过渡金属异四核配合物；草酰胺类〓四核配合物；两个由双核配合物通过叠氮和单个氯原子连成的四核配合物，尤其是以单个氯桥相连的化合物非常少见；一个由弱配键和氢键连成的具有一维波浪形结构的配合物；一个通过配位键和氢键连成的二维配位聚合物。
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The 3d transition metal monoxides coordinate one noble gasatom in forming the linear NgMO(M=Cr, Mn, Fe, Co, Ni; Ng=Ar, Kr, Xe) complexes.(3) The group VB metal oxides MO_2 and MO_4 coordinate two and one noble gasatoms in forming the MO_2_2 and MO_4(M=V, Nb, Ta; Ng=Ar, Kr, Xe)complexes.
3第VB族金属二氧化物与两个稀有气体原子形成的MO_2_2(M=V，Nb，Ta；Ng=Ar，Kr，Xe)络合物，其四氧化物与一个稀有气体原子形成的MO_4(M=V，Nb，Ta；Ng=Ar，Kr，Xe)络合物。
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For the calculations of Mon (n= 2-55) clusters, the linear and planar clusters have a strong tendency to form diatomic pairs to assemble short-long bonds alternation structures which makes them like non-metallic clusters, the short bonds are characterized as covalent non-metallic bonds and the long ones are much like weak metal bonds.
本文首先计算了各种不同结构的Mon（n=2-55）原子簇，发现一维和二维Mo原子簇表现出了一定的非金属原子簇的性质，簇中原子有明显的成双原子对趋势，致使原子簇具有短-长键交替的几何结构，短键和长键分别呈现强共价键和弱金属键的特性。
- 更多网络解释与二原子金属的相关的网络解释 [注：此内容来源于网络，仅供参考]
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charge density wave：电荷密度波
比如说,在铂(100)的重构表面上,我们发现表面电子有很强地形成电荷密度波(charge density wave)的倾向(10). 原因是当重构发生时,表层的原子密度远高过下层,导致表层浮起来,使其近似於一个二维系统. 造成金属或半导体的表面重构或结构相变的原因很多,
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dimerous：由两部分组成的
dimerous 双器官的 | dimerous 由两部分组成的 | dimetallic 二原子金属的
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icosahedron：正二十面体
用分子动力学方法,模拟了三种具有壳对称构型,含309个原子的钯金属团簇的熔化行为.钯原子间作用势采用Sutton-Chen多体作用势能.三种壳对称构型分别为正八面体(Cubooctahedron),正十面体(Decahedron)和正二十面体(Icosahedron).通过对升温过程中的热力学性质的分析,
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dimetallic：二原子金属的
dimetalation 二金属取代作用 | dimetallic 二原子金属的 | dimetamfetamine 二甲非他明