- 更多网络例句与二分子的相关的网络例句 [注:此内容来源于网络,仅供参考]
-
The macro conjugated molecule fluorene derivative has 2, 3, 6, 7-tetraamino-9, 9'-dialkyl fluorene as a raw material which is added to an organic solvent respectively together with phenanthrenequinone, acenaphthene quinone or bis-carbonyl pyrene derivatives and strong base; under the protection of inert gas, reflux reaction is carried out to the materials, so as to prepare a series of trapezoidal conjugated molecules containing fluorine structures.
本发明涉及一类含大共轭分子的芴衍生物及其制备方法,大共轭分子芴衍生物是将原料2,3,6,7-四氨基-9,9'-二烷基芴,分别与菲醌、苊醌或二羰基芘的衍生物以及强碱加入到有机溶剂中,在惰性气体的保护下,回流反应制得一系列含有芴结构的梯形共轭分子。
-
It is found that the dihedral angle in the two kinds of molecules were affected by the formation of the nanotubes, as a result, the CD spectra are different.
制备了手性分子二—2—萘基吡咯醇及--2,2'-甲氧基-1,1'-联二萘的纳米管,发现纳米管结构的形成对手性分子的二面角产生一定影响,进而影响其圆二色谱。
-
It was found that the process of the dimerization of ethene can be divided into three steps: the chemical adsorption of first ethene molecule, the physical adsorption of second ethene molecule and the dimerization reaction.
研究表明,乙烯在分子筛上的二聚反应分三步进行:单个乙烯分子化学吸附→第二个乙烯分子的物理吸附→两乙烯分子二聚反应。
-
The preliminary stiochiometric analysis showed that when the enzyme metabolized EDDA, two acetyl groups were removed and ethylenediamine and two glyoxylates were produced in the presence of oxygen.
然后对该酶促反应进行了定量分析:结果显示在IDA氧化酶的作用下每代谢一分子的EDDA将生成二分子的乙醛酸及一分子的乙二胺,同时也检测到过氧化氢的生成。
-
Kinetics of methanol dehydration to dimethyl ether on modified kaolin catalyst was studied in an integral reactor under normal pressure. It is deduced that the surface reaction of methanol molecule adsorbed on the active site of catalyst with methanol molecule in gas phase is the rate determining step. The hyperbolic type kinetic equation r=ksbMpM2/(1+bMpM+bpE) is obtained according to the theory of langmuir even adsorption and using the R-E mechanism.
采用积分反应器,考察了常压下在改性高岭土催化剂上甲醇脱水生成二甲醚的反应动力学,根据Langmuir均匀吸附理论,采用R-E机理,推断吸附的甲醇分子与气相主体中的甲醇分子发生的表面反应为速率控制步骤,得到双曲线型动力学方程为: r= ksbMpM2 /(1+bMpM+bpE)(r为反应速率, ks为反应速率常数, bM为甲醇的吸附平衡常数, b为二甲醚和水的吸附平衡常数之和, pM、 pE分别为甲醇、二甲醚的分压)。
-
The conclusions were as follows: theνO-H andνC=O IR absorption maxima shifted towards higher wave numbers after imprinting 17β-estradiol on TFMAA-co-TRIM copolymer with the red shift of theνO-H groups being apparent after precipitation polymerization for 16h while that forνC=O groups being observed after polymerization for 24h. A strong interaction between TFMAA and 17β-estradiol was confirmed by the high selectivity for 17β-estradiol, as indicted by the values of the separation factor of isomers of 17β-estradiol/17α-estradiol (2.28) and the imprinted factor (3.01). Particle diameter of TFMAA-co-TRIM polymer was between 300 nm and 1.5μm, which suited well for solid phase sorbent throughout at low column pressure. The recognition of imprinting TFMAA-co-TRIM polymer for sterol molecules was driven by enthalpy eluted with acetronitile, and low temperature was in favor of the separation of sterol structure analogues on imprinting column. TFMAA-co-TRIM polymer possessed of determinate anti-heat stability, with melting point beginning at 255.84℃, Tp=257.40℃, control TFMAA-co-TRIM polymer and imprinting TFMAA-co-TRIM polymer were respectively decompounded at 267.79℃and 343.11℃, and solid micro-extraction noddle prepared by the special polymerization also showed definite recognition for 17β-estradiol by GC/MS detecting at 270℃. By selection of various washing and elution solvents, elution reagents of close polymerization system were of more advantage in template molecules retention and recognition on molecularly imprinted solid phase extraction column. At a certain extent, progesterone, 17α-estradiol, 17β-estradiol and 4-androstene-3, 17-dione could be intercepted on the MISPE column. Especially, MISPE had high selectivity for progesterone, and imprinting TFMAA-co-TRIM polymer could achieve adsorption balance within 50 min by absorption kinetics test for 17β-estradiol. However, MISPE column showed better selectivity and enrichment property for 17β-estradiol than C18 and CSPE columns according to the data from HPLC and GC/MS analyses. Recovery of 17β-estradiol on MISPE column was up to 85.5% while when prime extracting solution of milk powder was sampled, the recovery of CSPE and C18 columns were 43.7% and 30.7%, respectively.
通过研究阐明:紫外聚合产物TFMAA-co-TRIM中的νO-H振动吸收峰在聚合16h后红移,νC=O振动吸收峰在聚合24h后红移;TFMAA-co-TRIM对雌二醇异构体的印迹因子达到了3.01,α为2.28,优于其它功能单体参与得到的聚合物识别特性;TFMAA-co-TRIM聚合物粒径介于300 nm至1.5μm之间,作为色谱固定相具有良好的通量和低的柱压;在乙腈流动相中,TFMAA-co-TRIM分子印迹固定相的分离过程主要被焓驱动,低温有利于分子印迹固定相分离甾醇结构类似物;TFMAA-co-TRIM分子印迹聚合物在255.84℃时开始熔融,Tp=257.40℃,聚合物CP的降解温度在267.79℃,MIP降解温度在343.11℃,制备的固相微萃取头初步经GC/MS 270℃的耐热性测定;不同的洗提溶剂筛选证明了选择接近聚合溶剂的洗脱体系更有利于MISPE发挥识别效应;分子印迹固相萃取柱对孕酮、17α-雌二醇、17β-雌二醇和雄烯二酮都具有不同程度的保留特性,可作为此类化合物的吸附材料,特别对孕酮强保留的富集特性,可作为孕酮的选择性识别吸附剂,其分子印迹聚合物对17β-雌二醇的吸附动力学测定显示在50 min内基本达到吸附平衡,具有作为传感器核心敏感材料的潜力;对比萃取奶粉中17β-雌二醇性能,MISPE柱比非分子印迹固相萃取柱和C18柱具有更高的保留,回收率依次为85.5%,43.7%和30.7%。
-
A series of sulfanilamide group substituted derivatives were optimized on the basis of the semi-empirical quantum chemistry PM3 method.
以量子化学半经验PM3法对含磺胺基的一类有机化合物分子进行了几何构型优化,计算了分子的二阶非线性光学系数和电子转移,讨论了磺胺基在非线性光学材料设计中的特点和作用以及不同的取代基及取代位置对分子二阶非线性光学系数的影响
-
A diacid triglyceride containing two molecules of palmitic acid and one of stearic acid could be named dipalmitostearin or steartodipalmtin.
含有二分子棕榈酸和一分子硬脂酸的二酸式甘油三酸脂可命名为二棕榈酰硬脂酰甘油酯或硬脂酰二棕榈酰甘油酯。
-
A diacid triglyceride containing two molecules of palmiticacid and one of stearic acid could be named dipalmitostearin orsteartodipalmtin.
含有二分子棕榈酸和一分子硬脂酸的二酸式甘油三酸脂可命名为二棕榈酰硬脂酰甘油酯或硬脂酰二棕榈酰甘油酯。
-
The UV and IR spectroscopic studies of the monomer films showed that the photoreaction ratio of monomer (about 50%) was higher than the corresponding photosensitive polymer (about 10%, PVCi). The polarized IR spectra proved that obvious anisotropic absorption was displayed in the irradiated photosensitive film. With polarizing microscopy method, we found that these kinds of photoalignment films exhibited good alignment ability, and the stability of the photoalignment film could reach about 100℃. 2 A photosensitive self-assembled monolayer was fabricated that contained photo-cycloadditable groups, such as, coumarin and cinnamate. The reaction process were detected by contact angle method because the IR absorption of monolayer was very weak. The photosensitive self-assembled monolayer promote uniform alignment of nematic liquid crystals by LPUV, and it thermal stability could reach about 130℃. 3 A cationic bolaform amphiphiles was synthesized that had two photosensitive double bonds, and can be polymerized by ultraviolet. A layer-by-layer self-assembled deposition film was prepared in aqueous solution by using this material and poly (sodium 4-styrenesulfonate). The UV-Vis. spectra proved that the multilayers film was uniform and layer-by-layer. When LPUV irradiated the film, the photopolymerizable double bond underwent [2+2] cycloaddition, and the production of the reaction distributed along the polarized direction of incident LPUV. Polarized UV-Vis. spectra indicated that the irradiated self-assembled multiplayer film was anisotropic, and the dichromic ration is about 0.09, it is higher than the spin-coating method of photosensitive polymer or monomer. We used this anisotropic film as alignment layer of nematic liquid crystals, and obtained a uniform and stability alignment result, the static contrast ratio is about 100, which is very close to application of liquid crystal device. This thesis is an instance that the photochemical material was used in the physics region of liquid crystals, the route that was from photosensitive monomer, self-assembled monolayer film to self-assembled multiplayer film was undergone, by this logical research method photoailgnment of liquid crystal was extended and consummated.
围绕上述思路开展了如下工作:1合成了三种可进行光二聚反应的光敏小分子单体,LPUV 辐照制作了光控取向膜;用紫外-可见光谱法和红外光谱法分析了薄膜中的光化学反应,发现小分子的光反应程度可达到50%以上,至少比光敏高分子高出5倍;薄膜的偏振红外光谱证实,经过LPUV 辐照后薄膜出现了明显的各向异性;将小分子光控取向膜制成液晶器件,在偏光显微镜下观察看到均匀一致的液晶取向;并且热稳定性达到100℃左右,接近实用化要求。2制备了含肉桂酸、香豆素基团的自组装单层膜;采用接触角的方法监测自组装反应的动力学过程;紫外-可见光谱证实了自组装单层膜在石英基板表面形成;自组装单层膜经LPUV 辐照后能诱导液晶均匀取向,而且热稳定性可达130℃,热稳定性进一步提高。3合成了含有光敏双键的双季铵盐,在水溶液状态下将它和聚乙烯基苯磺酸钠沉积生成layer-by-layer 自组装多层膜,紫外-可见光谱证实这是一个逐层均匀的沉积;在LPUV 照射下,自组装膜中的光敏双键按照偏振方向发生[2+2]环加成反应,形成取向膜,用二向色性值评价的分子取向度高于高分子及小分子光控取向膜的水平;实验证明用自组装多层膜制成的液晶器件亮暗态均匀,静态对比度约为100,达到实用化器件的水平。
- 更多网络解释与二分子的相关的网络解释 [注:此内容来源于网络,仅供参考]
-
diatomic molecule:二原子分子
diatomic 二原子的,双原子的 | diatomic molecule 二原子分子 | diatomic roto 双厚子转动体
-
diatomic:二原子的,双原子的
diathermancy 透热性 | diatomic 二原子的,双原子的 | diatomic molecule 二原子分子
-
dimness:暗淡
dimmish 暗淡 | dimness 暗淡 | dimolecular 双分子 二分子 二分子的
-
isoprene:异戊二烯
而Coenzyme Q10的字源是因为这分子为参与细胞内呼吸传递链的辅酶之一(Coenzyme);Q为醌环(Quinonering)的缩写;而数字10是指这分子的侧链是由10个异戊二烯(Isoprene)所组成(详细结构如右所示).
-
bimaculate:二斑块的
biloculate 二室的 | bimaculate 二斑块的 | bimolecular reaction 双分子反应
-
dimolecular:双分子
dimolecular 二分子的 | dimolecular 双分子 | dimorphicdimorphous 同种二形的
-
dimolecular:二分子的
dimolecular 二分子 | dimolecular 二分子的 | dimolecular 双分子
-
dimolecular:二分子
dimnessduskiness 微暗 | dimolecular 二分子 | dimolecular 二分子的
-
dimolecular:双分子 二分子 二分子的
dimness 暗淡 | dimolecular 双分子 二分子 二分子的 | dimonoecious 同株二型花
-
disulfide bond:二硫键
二硫键(disulfide bond) 又称S-S键. 是2个SH基被氧化而形成的-S-S-形式的硫原子间的键. 在生物化学的领域中,通常系指在肽和蛋白质分子中的半胱氨酸残基中的键. 此键在蛋白质分子的立体结构形成上起着一定的重要作用. 为了确定蛋白质的一级结构,