- 更多网络例句与乙酰苯相关的网络例句 [注:此内容来源于网络,仅供参考]
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In this paper, acetanilide used as start material was chlorosulfonated, then reacted with alkylamines with different length of carbon chain to prepare 4 p-acetylaminophenylsulfonylalkylamine.
本文以乙酰苯胺为起始原料,经氯磺化后分别和不同碳链的正烷基胺反应制得4种不同碳链长度的对乙酰氨基苯磺酰烷基胺,将其水解后制得了对氨基苯磺酰正丁胺、对氨基苯磺酰正辛胺、对氨基苯磺酰正十二胺和对氨基苯磺酰正十八胺。
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Finally, reacting II with PhNCO givethe compound 1-(6-nitrobenzimidazol-l-acetyl)-4-phenylsemicarbazide,III in the presence of〓 give the new cyclic compound 2-phenylamino-5-(6-nitrobenzimidazol- 1-methylene)-l,3,4-oxadiazole.
第三部分:以6-硝基苯并咪唑-1-乙酰肼为原料,分别与取代苯甲醛、苯乙酮及乙酰基二茂铁进行缩合反应,合成了10个新的6-硝基苯并咪唑-1-乙酰腙衍生物。
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In our research on study chemical reaction of active methylene compounds and brom-acetophenone. Because of brom-acetophenone is compound that contain carbonyl and halogen ,which will take place electrophilic substitution and nucleophilic addition. When active methylene compounds are ethyl acetoacetate and β-diketone, controlling reaction condition, we have found that mono-substitution's production and di-substitution's. production is isolated; active methylene compounds are acetoacetanilide and acetoacetanilide derivate, pyrrolidin-2-one derivants were obtained by substitution and close-ring reaction .but there is no report about it.
本文是让活泼亚甲基类化合物与溴代苯乙酮发生化学反应,由于溴代苯乙酮是含有羰基的卤代烃结构,它可以发生亲电取代和亲核加成反应,当活泼亚甲基类化合物为乙酰乙酸乙酯和β-二酮时,控制反应条件可以发生单取代和双取代两种产物;当活泼亚甲基类化合物为乙酰乙酰芳胺类化合物来反应时,溴代苯乙酮中的羰基与氨基会发生分子内的关环反应生成吡咯烷-2-酮衍生物,这在以前的研究中是没有发现的。
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Methods Starting from 2-chloro-4-nitrophenol and 2- pyridine hydrochlorid, 3-chloro-4-(pyridin-2-ylmethoxy) aniline was obtained via etherization and reduction. The obtained aniline coupled with N-(4-chloro-3-cyano-7-ethoxyquinolin-6-yl) acetamide to give 4-[3-chloro-4-(2-pyridylmethoxy) phenylamino]-3-cyano-7-ethoxy-6-N-acetylaminoquinoline. And then it was deacetylated, followed by reacting with4- but-2-enoyl chloride to yield the target compound neratinib.
以2-氯-4-硝基苯酚和2-氯甲基吡啶为起始原料,经醚化、硝基还原得到3-氯-4-(吡啶-2-甲氧基)苯胺,3-氯-4-(吡啶-2-甲氧基)苯胺与3-氰基-6-乙酰氨基-7-乙氧基-4-氯喹啉反应得到3-氰基-6-乙酰氨基-4-[3-氯-4-(吡啶-2-甲氧基)苯氨基]-7-乙氧基喹啉,3-氰基-6-乙酰氨基-4-[3-氯-4-(吡啶-2-甲氧基)苯氨基]-7-乙氧基喹啉去乙酰保护基后,与-4-二甲氨基-2-丁烯酰氯经酰化反应得到ner-atinib。
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Mission:"equality and mutual benefit, reputation first, unity and cooperation and friendship between the long-term" supply products: ethylenediamine; diethylamide; triethylamine; Diethylenetriamine; three ethylene diamine; three ethylene amines 40; 40 Five ethylene amines; five ethylene amines 6; caprolactam; DMF; allyl amine; N, N dimethylaniline; propylamine; are butylamine; are TOA; 3 Poly Cyanamide; 1,2 c diamine; ethanolamine; diethanolamine, triethanolamine; potassium iodide, potassium hydroxide, potassium permanganate, toluene, xylene, toluene of chlorine ; Acetone, butanone; acetylacetone; ethyl acetate, butyl acetate; Y-butyrolactone; DMC; acetyl of methyl acetate; Sanfu acetyl acid; Sanfu acetyl B Ethyl; methanol, ethanol, isopropanol; propylene glycol; glycerol; propargyl alcohol; 1.3 propylene glycol; xylitol; acetic acid; have acid; mercaptoacetic acid; vary Bitterness; adipic acid; trifluoroacetic acid; oxalic acid, the amino acid; o-amygdalin acid; DL-Acid; anhydrous piperazine; six non-piperazine, furfural, castor oil, ethylene Aldehyde; glutaraldehyde, multi-POM; isopropyl ether; anisole; tetrahydropyrrole; pure pyridine; 1.2 dichloroethane; methylene chloride, chloroform, carbon tetrachloride; hydrazine hydrate; Nonylphenol;-m-cresol; Se phenol; phenol; the tert-butyl phenol; Titanium Dioxide; iron; full Tangfen; Bisphenol A; azo two different nitrile; sodium azide; sodium carbonate ; Sodium chloride; iron oxide; cuprous chloride; thionyl chloride; D4; sodium bicarbonate; ammonia, potassium chloride; anhydrous sodium sulphite; ammonium persulfate; glycol Dingmi; B Glycol ether; calcium chloride; cyclohexanone; cyclohexane, methyl tertiary butyl ether, potassium carbonate, ferric chloride, potassium nitrate; Linsuansanna; zinc oxide; sodium nitrite; antimony oxide; Tartrate; OP-10; TX-10; tablets base; AES; sodium benzoate, sodium citrate; partial sodium silicate, sodium perborate, a sodium carbonate, sodium benzene; Asia sodium chlorate; Wuluo Care products; urea; hydrochloric acid, sulfuric acid, lactic acid; amino acid, hydrogen peroxide, ammonium bicarbonate
公司宗旨:"平等互利,信誉至上,团结合作,友谊长久"乙二胺;二乙胺;三乙胺;二乙烯三胺;三乙烯二胺;三乙烯四胺;四乙烯五胺;五乙烯六胺;己内酰胺;二甲基甲酰胺;烯丙基胺;N,N二甲基苯胺;正丙胺;正丁胺;正辛胺;三聚氰胺;1,2丙二胺;一乙醇胺;二乙醇胺;三乙醇胺;碘化钾;氢氧化钾;高锰酸钾;甲苯;二甲苯;对氯甲苯;丙酮;丁酮;乙酰丙酮;醋酸乙酯;醋酸丁酯;Y-丁内酯;碳酸二甲酯;乙酰乙酸甲酯;三伏乙酰乙酸;三伏乙酰乙酸乙酯;甲醇;无水乙醇;异丙醇;丙二醇;丙三醇;丙炔醇;1.3丙二醇;木糖醇;冰醋酸;己醛酸;巯基乙酸;异辛酸;己二酸;三氟乙酸;乙二酸;对氨基苯乙酸;邻氯苦杏仁酸;DL-扁桃酸;无水哌嗪;六无哌嗪;糠醛;蓖麻油;乙二醛;戊二醛;多聚甲醛;异丙醚;苯甲醚;四氢吡咯;纯吡啶;1.2二氯乙烷;二氯甲烷;三氯甲烷;四氯化碳;水合肼;壬基酚;纯间甲酚;硒酚;苯酚;对叔丁基苯酚;钛白粉;铁粉;全糖粉;双酚A;偶氮二异丁腈;叠氮化钠;碳酸钠;氯化钠;三氧化二铁;氯化亚铜;氯化亚砜;D4;碳酸氢钠;氨水;氯化钾;无水亚硫酸钠;过硫酸铵;乙二醇丁醚;乙二醇乙醚;氯化钙;环己酮;环己烷;甲基叔丁基醚;碳酸钾;三氯化铁;硝酸钾;磷酸三钠;氧化锌;亚硝酸钠;氧化锑;酒石酸;OP-10;TX-10;粒碱;AES;苯甲酸钠;柠檬酸钠;偏硅酸钠;过硼酸钠;过碳酸钠;苯磺酸钠;亚氯酸钠;乌洛托品;尿素;盐酸;硫酸;乳酸;氨基磺酸;双氧水;碳酸氢铵
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In this thesis,the AM1,MNDO,MINDO/3(mainly AM1)and INDO/S-CI semiempirical MO methods were used toinvestigate the excited-state intramolecular protontransfer reactions of salicylic acid derivatives—salicylic acid,methyl salicylate,salicylaldehyde,o-hydroxyaceto-phenone,salicylamide and 3-hydroxy-picolinamide (6 conformers and 2-3 anion species);2-(2'-hydroxy-5' methylphenyl) benzotriazole(4 conformers),2-(2' hydroxyphenyl) benzimidazole (3 conformers and 3anion species),Bis-2,5-(2-benzoxazolyl)hydroquinone(3 conformers),2-(2'-hydroxyphenyl)benzothiazole(2conformers) and 7-azaindole dimer (2 conformers).Theinvestigations were described as follows.Geometry optimization,relative stability andhydrogen bonding energy First,for sylicylic acid derivative molecules,the AM1,MNDO and MINDO/3 methods were used toinvestigate ground-state geometry optimization,energies,relative stabilities and hydrogen-bondingenergies on the five kinds of the molecules(designing 6 conformers and 2-3 anion species).Comparing with experimental data,the optimizedgeometry,the order of stability,the hydrogen-bonding energies and the distances between O-O in O-H..O hydrogen bonds by AM1 method were in agreementwith the experimental data,however,the C-C bondlengths optimized by MNDO and MINDO/3 were longer,C-O and O-H bond lengths were shorter;for C-N bondlengths,the results opitimized by MNDO method werethe same as those by AM1 method,nevertheless the C-Nbond lengths given by MINDO/3 method were muchshorter.For some sylicylic acid derivatives(e.g.methyl salicylate,salicylamide),the order ofstabilities on the conformers given by MNDO andMINDO/3 methods were not in agreement with theexisting conformers deduced by experimental methods,and the hydrogen bonding energies calculated by MNDO.and MINDO/3 methods were smaller.Second,the studyon the other systems found that the optimizedgeometry of the proton-transfered product with INDOmethod could not be obtained,only could theoptimized geometry of reactant be obtained,and thecalculated hydrogen bonding energies were greater.Many results of calculation indicated that the studyon the excited-state intramolecular proton transferreaction system using AM1 method was suitable andreliable.
本论文用AM1、MNDO、MINDO/3(主要是AM1)和INDO/S-CI半经验分子轨道方法对水杨酸衍生物系列——水杨酸、水杨酸甲酯、水杨醛、O-羟基乙酰苯酮、水杨酰胺和3-羟基吡啶酰胺(6种异构体和2-3种阴离子);2-(2'-羟基-5'-甲基苯基)苯并三〓唑(4种异构体);2-(2'-羟基苯基)苯并咪唑(3种异构体和3种阴离子);2,5-二间氮杂氧茚氢醌(3种异构体);2-(2'-羟基苯基)间〓杂硫茚(2种异构体)和7-〓吲哚二体(2种异构体)的激发态分子内质子转移反应在以下几个方面进行了较系统的理论研究:几何构型优化和相对稳定性及氢键能首先以水杨酸衍生物系列分子为例,用AM1、MNDO和MINDO/3方法考察了5种分子(每种分子设计6种异构体和2-3种阴离子)的基态几何构型优化,能量、相对稳定性和氢键能计算,通过和实验数据进行比较,AM1方法给出的优化几何构型、稳定性次序、氢键能和O—H。。。O氢键的0—0距离与实验数据吻合最好,MNDO和MINDO/3方法优化的C-C键长偏长,C-O键和O-H键长偏短;对于C-N键长,MNDO和AM1优化结果差别不大,而MINDO/3给出了过短的C-N键长,MNDO和MINDO/3方法给出的有些水杨酸衍生物分子(如水杨酸甲酯和水杨酰胺)异构体的稳定性次序和实验上推测的可存在异构体结果不一致,MNDO和MINDO/3方法给出的氢键能偏低,对其他体系的研究发现INDO方法常常不能得到质子转移产物的优化几何构型,只能得到反应物的优化构型,并且估算的氢键能偏高,大量的计算结果表明AM1方法对本论文研究的激发态分子内质子转移反应体系是适宜和可靠的。
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Universal indicator paper,special indicator paper,ammonium fluoride,ammonium hydrogen difluoride,nbenzyldimethylamine,disinfectant paper,nacetylphenylhydrazine,mcresol purple,bromocresol green,fluorescein,eosin Y,ninhydrin,phenedons,potassium phthalate,pamimobenzene sulphonic acid anhydrous.
广泛试纸,精密试纸,氟化铵,氟化氢铵,N苄基二甲胺,消毒试纸,N乙酰苯肼,间甲酚紫,溴甲酚绿,荧光素,曙红Y,水合茚三酮,菲尼酮S,苯甲酸氢钾,无水对氨基苯磺酸。
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Mission:"equality and mutual benefit, reputation first, unity and cooperation and friendship between the long-term" supply products: ethylenediamine; diethylamide; triethylamine; Diethylenetriamine; three ethylene diamine; three ethylene amines 40; 40 Five ethylene amines; five ethylene amines 6; caprolactam; DMF; allyl amine; N, N dimethylaniline; propylamine; are butylamine; are TOA; 3 Poly Cyanamide; 1,2 c diamine; ethanolamine; diethanolamine, triethanolamine; potassium iodide, potassium hydroxide, potassium permanganate, toluene, xylene, toluene of chlorine ; Acetone, butanone; acetylacetone; ethyl acetate, butyl acetate; Y-butyrolactone; DMC; acetyl of methyl acetate; Sanfu acetyl acid; Sanfu acetyl B Ethyl; methanol, ethanol, isopropanol; propylene glycol; glycerol; propargyl alcohol; 1.3 propylene glycol; xylitol; acetic acid; have acid; mercaptoacetic acid; vary Bitterness; adipic acid; trifluoroacetic acid; oxalic acid, the amino acid; o-amygdalin acid; DL-Acid; anhydrous piperazine; six non-piperazine, furfural, castor oil, ethylene Aldehyde; glutaraldehyde, multi-POM; isopropyl ether; anisole; tetrahydropyrrole; pure pyridine; 1.2 dichloroethane; methylene chloride, chloroform, carbon tetrachloride; hydrazine hydrate; Nonylphenol;-m-cresol; Se phenol; phenol; the tert-butyl phenol; Titanium Dioxide; iron; full Tangfen; Bisphenol A; azo two different nitrile; sodium azide; sodium carbonate ; Sodium chloride; iron oxide; cuprous chloride; thionyl chloride; D4; sodium bicarbonate; ammonia, potassium chloride; anhydrous sodium sulphite; ammonium persulfate; glycol Dingmi; B Glycol ether; calcium chloride; cyclohexanone; cyclohexane, methyl tertiary butyl ether, potassium carbonate, ferric chloride, potassium nitrate; Linsuansanna; zinc oxide; sodium nitrite; antimony oxide; Tartrate; OP-10; TX-10; tablets base; AES; sodium benzoate, sodium citrate; partial sodium silicate, sodium perborate, a sodium carbonate, sodium benzene; Asia sodium chlorate; Wuluo Care products; urea; hydrochloric acid, sulfuric acid, lactic acid; amino acid, hydrogen peroxide, ammonium bicarbonate
公司宗旨:&平等互利,信誉至上,团结合作,友谊长久&乙二胺;二乙胺;三乙胺;二乙烯三胺;三乙烯二胺;三乙烯四胺;四乙烯五胺;五乙烯六胺;己内酰胺;二甲基甲酰胺;烯丙基胺;N,N二甲基苯胺;正丙胺;正丁胺;正辛胺;三聚氰胺;1,2丙二胺;一乙醇胺;二乙醇胺;三乙醇胺;碘化钾;氢氧化钾;高锰酸钾;甲苯;二甲苯;对氯甲苯;丙酮;丁酮;乙酰丙酮;醋酸乙酯;醋酸丁酯;Y-丁内酯;碳酸二甲酯;乙酰乙酸甲酯;三伏乙酰乙酸;三伏乙酰乙酸乙酯;甲醇;无水乙醇;异丙醇;丙二醇;丙三醇;丙炔醇;1.3丙二醇;木糖醇;冰醋酸;己醛酸;巯基乙酸;异辛酸;己二酸;三氟乙酸;乙二酸;对氨基苯乙酸;邻氯苦杏仁酸;DL-扁桃酸;无水哌嗪;六无哌嗪;糠醛;蓖麻油;乙二醛;戊二醛;多聚甲醛;异丙醚;苯甲醚;四氢吡咯;纯吡啶;1.2二氯乙烷;二氯甲烷;三氯甲烷;四氯化碳;水合肼;壬基酚;纯间甲酚;硒酚;苯酚;对叔丁基苯酚;钛白粉;铁粉;全糖粉;双酚A;偶氮二异丁腈;叠氮化钠;碳酸钠;氯化钠;三氧化二铁;氯化亚铜;氯化亚砜;D4;碳酸氢钠;氨水;氯化钾;无水亚硫酸钠;过硫酸铵;乙二醇丁醚;乙二醇乙醚;氯化钙;环己酮;环己烷;甲基叔丁基醚;碳酸钾;三氯化铁;硝酸钾;磷酸三钠;氧化锌;亚硝酸钠;氧化锑;酒石酸;OP-10;TX-10;粒碱;AES;苯甲酸钠;柠檬酸钠;偏硅酸钠;过硼酸钠;过碳酸钠;苯磺酸钠;亚氯酸钠;乌洛托品;尿素;盐酸;硫酸;乳酸;氨基磺酸;双氧水;碳酸氢铵
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The synthesis of alkylcyclohexylbenzoic acid: take the synthesis of ethylcyclohexylbenzoic acid as a typical example. With the AlCl3 as the catalyst, cis+trans acetylcyclohexylbenzene is synthesized from the reaction of acetyl chloride, cyclohexene and benzene.
烷基环己基苯甲酸的合成研究:主要研究了乙基环己基苯甲酸的合成,以乙酰氯、环己烯、苯为原料,三氯化铝为催化剂,合成乙酰基环己基苯,用水合肼、氢氧化钾、一缩二乙二醇经过高温加热还原羰基(Wolff-黄鸣龙还原),将所得到的乙基环己基苯用乙酰氯进行傅克酰基化得到乙基环己基苯乙酮,所得中间体经过处理之后直接得到反式产物,将反式异构体的乙酰基氧化得到反式烷基环己基苯甲酸。
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Guanine can quench the phthalhydrazidylazoacetylacetone's ECL in acid medium, and the linear concentration range of guanine relative to the ECL intensity is from 2.0×10~(-6) to 1.0×10~(-5) mol/L.The mechanism of phthalhydrazidylazoacetylacetone's ECL on the surface of ITO glass has been discussed according the experimental phenomenon.The phenomenon of ITO self-luminescence has also been studied.It has been found that the machanism of phthalhydrazidylazoacetylacetone on the surface of ITO in different medium is dissimilarity. The phenomenon of ITO self-luminescence may be caused by the interaction of the active oxygen element and ITO's surface.
鸟嘌呤在弱酸性介质中3-(1-乙酰丙酮偶氮)苯二甲酰肼的电化学发光具有显著的淬灭作用,2.0×10~(-6)~1.0×10~(-5) mol/L浓度范围内,电化学发光强度与鸟嘌呤的浓度成良好的线性关系根据相关试验现象对3-(1-乙酰丙酮偶氮)苯二甲酰肼在氧化铟锡玻璃电极上的电化学发光机理进行了初步探讨,并对氧化铟锡玻璃电极自身发光现象进行了研究,研究发现在不同酸度环境中,3-(1-乙酰丙酮偶氮)苯二甲酰肼在氧化铟锡玻璃电极上电化学发光的机理是显著不同的;ITO自身发光可能是由活性氧系分子与ITO镀膜玻璃电极表面相作用引起的。
- 更多网络解释与乙酰苯相关的网络解释 [注:此内容来源于网络,仅供参考]
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acetophenone photoreduction:乙酰苯光致还原
acetophenone 乙酰苯,苯偶姻,苯乙酮=>アセトフェノン | acetophenone photoreduction 乙酰苯光致还原 | acetophenone-p-phenetidine 苯乙酮缩非那替汀
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chloroacetophenone:氯苯甲基酮 氯乙酰苯 氯乙酰苯
chloroacetonitrile 氯乙腈 | chloroacetophenone 氯苯甲基酮 氯乙酰苯 氯乙酰苯 | chloroacrolein 氯丙烯醛
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CHLOROACETOPHENONE, SOLID:固态氯乙酰苯
CHLOROACETONITRILE 氯乙腈 6.1 2668 | CHLOROACETOPHENONE, SOLID 固态氯乙酰苯 6.1 1697 | CHLOROACETOPHENONE, LIQUID 液态氯乙酰苯 6.1 3416
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CHLOROACETOPHENONE, LIQUID:液态氯乙酰苯
CHLOROACETOPHENONE, SOLID 固态氯乙酰苯 6.1 1697 | CHLOROACETOPHENONE, LIQUID 液态氯乙酰苯 6.1 3416 | CHLOROACETYL CHLORIDE 氯乙酰氯 6.1 1752
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acetylbenzene:乙酰苯;苯乙酮;甲基苯基甲酮
acetylation 乙酰化 | acetylbenzene 乙酰苯;苯乙酮;甲基苯基甲酮 | acetylbenzoylperoxide 乙酰过氧化苯甲酰
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acetylbenzene:乙酰苯
acetylbase乙酰基 | acetylbenzene乙酰苯 | acetylbenzoylperoxide乙酰过氧化苯甲酰
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acetylphenyl salicylate; acetylsalol:柳酸乙酰苯酯;乙酰沙洛
过氧化乙酰基 acetylperoxide | 柳酸乙酰苯酯;乙酰沙洛 acetylphenyl salicylate; acetylsalol | 乙酰磷酸 acetylphosphate
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benzalacetophenone dibromide:亚苄基乙酰苯化二溴
benzalacetone | 苯亚甲基丙酮 | benzalacetophenone dibromide | 亚苄基乙酰苯化二溴 | benzalacetophenone | 亚苄基乙酰苯
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phenacyl chloride:苯甲酰甲基氯,氯乙酰苯
phenacyl bromide 苯甲酰甲基溴 | phenacyl chloride 苯甲酰甲基氯,氯乙酰苯 | phenacyl ester 苯乙酮酯
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phenacyl chloride:苯甲酰甲基氯,氯乙酰苯
phenacyl bromide ==> 苯甲酰甲基溴 | phenacyl chloride ==> 苯甲酰甲基氯,氯乙酰苯 | phenacyl ester ==> 苯乙酮酯