为.接枝

词组短语

cleft-graft

与为.接枝相关的网络例句 [注：此内容来源于网络，仅供参考]

The effects of different factors on the laser-induced graft polymerization on the PET surface were analyzed, and the mechanisms were discussed. The factors were: 1 Monomers with smaller molecules resulted in better modification than polymeric monomers. Acrylamide monomer was chosen as hydrophilic modifier finally; 2 Higher concentration of the monomer solution favored the graft reaction; 3 With the increasing laser fluence, the surface hydrophilicity of PET films increased at first, then decreased. More laser pulses led to a more hydrophilic surface; 4 Benzophenone as a photosensitizer hindered the graft polymerization; 5 The homopolymer retardant of ammonium iron sulfate hexahydrate in a proper concentration retarded the formation of homopolymers and promotes the graft copolymerization; 6 The solvent of monomer solution also affected the graft reaction. Different solvents functioned in different ways. Ethanol can promote the graft reaction because of the activity of hydrogen in its structure; 7 pH value of the monomer solution affects the polymerization rate, and a lower pH value was favorable to the graft reaction.

这些影响因素的作用分别为：1小分子单体的表面改性效果好，确定以丙烯酰胺为亲水性改性单体；2较高的单体溶液浓度有利于接枝反应；3激光能量密度增大，薄膜表面亲水性先显著增强，后又减弱；激光脉冲次数越多，改性后表面亲水性越强；4光敏剂BP对PET表面接枝聚合反应有阻碍作用；5适当浓度的均聚物抑制剂六水合硫酸铁铵能减少单体均聚物的生成，促进接枝聚合；6单体溶液的溶剂也影响接枝聚合的反应进程，不同溶剂的影响作用原理不同，含较活泼氢的乙醇能促进接枝反应；7溶液pH值影响单体聚合速率，pH值较低有利于接枝反应。

It was found that VAC can be smoothly photografted onto LDPE film with"film combination"system, e. g. conversion percent and grafting efficiency are 70％ and 76％, irrespcetively, with UV intensity of 5400μw/cm〓 and irradiation time of 3min. The reaction orders of polymerization rate to monomer concentration and photoinitiator concentration are about 1 and 0.76, irrespectively, showing that chain transfer reaction takes place with much ease in VAC/LDPE system.

发现利用本文所设计的方法可将VAC快速地接枝在LDPE膜表面，如在光强为5400μw/cm〓，光照3min时，转化率和接枝效率可分别达到70％和76％；聚合反应速率对单体的反应级数约为1，而对光引发剂的反应级数为0.76，说明VAC光接枝聚合中链转移反应占相当大的比例。

This dissertation was designed to study heteto-phase grafting polymerization of vinyl acetate , maleic anhydride and VAC/MAH binary monomer system, irrespectively, with low density polyethylene film as substrate and benzophenone as photoinitiator. The purpose is to develop new and more effective methods to modify the surface and buck properties of polyolefines by studying the grafting mechanism of the system and exploring the characteristics of the grafting process.

本文主要以低密度聚乙烯膜为基体膜，以二苯甲酮为光引发剂，分别对醋酸乙烯酯、马来酸酐以及VAC/MAH的非均相接枝聚合反应进行了系统研究，以探讨相关的接枝反应机理、接枝反应过程以及接枝工艺的可行性，目的在于建立聚烯烃材料本体和表面改性新方法。

The influence of MAH、 AA、 MAA、 AM and GMA on hydrophilicity of PP product surface was studied by reaction extrusion process in the twin screw extruder, where 1,1-bis (tert-butyl peroxy)-3,3,5-trimethylcyclohexane (LQCH335) as the initiator, and St as the graft co-monomer.

通过在双螺杆挤出机中熔融接枝改性PP，研究了以1，1-二叔丁基过氧化－3，3，5-三甲基环己烷(LQCH335)为引发剂，MAH、AA、MAA、AM和GMA为接枝单体，St为接枝共单体的多单体熔融接枝体系对PP制品表面可涂敷性能的影响，并利用静态水接触角进行表征。

The graft polymerization of acrylonitrile on Crosslinked polyvinyl alcohol microspheres CPVA microspheres was performed by using cerium ammonium sulfate as initiator, and grafted microspheres CPVA-g-PAN were prepared. Subsequently, the grafted PAN was converted into poly via amidoximation reaction with hydroxylamine hydrochloride as reagent, resulting in the functional microspheres CPVA-g-PAO. The chemical structure and physicochemistry characters were adequately characterized with infrared spectrum, scanning electron microscope and determining Zeta potential. The effects of main factors on the amidoximation transform reaction of the grafted PAN were researched with emphasis, and the adsorption property of the functional microspheres CPVA-g-PAO for some biomolecules was examined preliminarily with uric acid as a model biomolecule.

以硫酸铈铵为引发剂，实施了丙烯腈在交联聚乙烯醇微球表面的接枝聚合，制备了接枝微球CPVA-g-PAN，然后以盐酸羟胺为试剂，通过偕胺肟化转变，将接枝的PAN转变为聚偕胺肟，制得了接枝有聚偕胺肟的功能微球CPVA-g-PAO，采用红外光谱法、扫描电子显微镜及Zeta电位测定等法，对功能微球CPVA-g-PAO的化学结构及物理化学特性进行了表征，重点考察了各主要因素对接枝PAN的偕胺肟化转变反应的影响，也以脲酸为模型分子，初探了功能微球CPVA-g-PAO对生物分子的吸附性能。

The tetrabasic graft copolymer was prepared on chloroprene rubber initiated by benzoyl peroxide,with styrene,methyl methacrylate and acrylic acidas graft monomers by tetrabasic graft copolymerization.

以苯乙烯、甲基丙烯酸甲酯、丙烯酸为接枝单体，以过氧化二苯甲酰为引发剂，在氯丁橡胶上进行接枝共聚，制备出CR/St/MMA/AA四元接枝共聚物。

The silk fabric s were ingrafted with acrylamide monomer by the radiation of Co-60γradial and then were coordinated by polysaccharid and citric acid solution in order to improve its capability of withstandingness of crease.

以丙烯酰胺为接枝单体，在Co-60γ射线辐照条件下对真丝织物接枝改性，再用壳聚糖柠檬酸溶液对真丝织物复合整理以改善其抗皱性能。

The analysis results of FTIR , SEM, X-ray Diffraction and TG-DSC proved that,the existence of graft copolymerization between cassava starch and acrylamide was occured;the structures of cassava were destroyed during the copolymerizing; the structures of the copolymer were largely amorphous; within the range of 700℃,the thermal degradation process of the St-g-PAM was divided into three-steps, which was more complex than that of cassava.

FTIR、SEM、X射线衍射、TG-DSC分析结果表明木薯淀粉与丙烯酰胺已发生接枝共聚反应；木薯淀粉在接枝共聚反应中，结构被破坏，接枝共聚物的结构基本上为无定型结构；在700℃温度范围内，木薯淀粉丙烯酰胺接枝共聚物的热降解为三步降解历程，比木薯淀粉复杂。

Two series of polyurethane acrylate grafted acrylic resins (Acr-g-TPU-PETA and Acr-gPPU-PETA) self-emulsifying systems are obtained by grafting -NCO group modified polyurethane acrylates with acrylic copolymer prepared from n-butyl acrylate, styrene,βhydroxyethyl methacrylate and acrylic acid The self-emulsifying systems showed Newtonian fluidity with viscosity closed to that of water, the solid contents were around 30% The T〓 of 15～4℃ for dried film before photocuring favored film formation at room temperature DSC and DMA results showed that PU-PETA is compatible with acrylic resin in the grafted resin The TG and dTG curves for Acr-g-PU-PETA samples were substantially different from the corresponding blends, and the brodened dTG peaks for photocured grafted resin suggest that there might be multiple interactions among chain segments The photocued film of the grafted resins self-emulsifying system exhibited good overall properties with polyurethane acrylate grafts ranging from 30% to 50%, and Acr-g-TPU-PETA series showed better properties than Acr-gPPU-PETA series The adhesion of the photocured film was 1～2 grade, impact strength was 50kg-cm and flexibility was 1mm The Shore hardness and the adhesion of the film decreased markedly if PETA was replaced by HEMA as photoactive group due to the lower C=C double bond content in the grafted resin The polyhydroxy amine-linked thioxanthones photoinitiators can be evenly dispersed in self-emulsifying system without color spot appearing in the dried film The films photocured with IV〓～IV〓 generally exhibited higher Shore hardness, gloss and solventresistance than that cured with Irgacure 2959 and did not induce the rusting of the iron substrate Pigmenting with titanium oxide had no effect on the photocuring The polyhydroxy amine-linked thioxanthone IV〓 and IV〓 can be new candidates for the formulation of titanium oxide pigmented photocurable water-borne coatings for their pale-yellow appearance and slight interference with the color of the coatings WB 4759 with high water-solubility coalesced and separated from the dried resin film, and even induced the rusting of iron substrate.

以丙烯酸丁酯，甲基丙烯酸-β-羟乙酯，丙烯酸及苯乙烯合成厂丙烯酸共聚树脂，并与含-NCO端基的聚氨酯丙烯酸酯接枝反应，经水性化后，得到两个系列（Acr-g-TPU-PETA和Acr-g-PPU-PETA）各5个不同配比的丙烯酸树脂接枝聚氨酯丙烯酸酯自乳化体系，粘度与水相近，为牛顿流体，固含量30％左右。光固化前干燥涂膜的玻璃化转变温度在-15℃～4℃之间，有利于室温下成膜。DSC及DMA谱表明两种树脂基本相容。Acr-g-PU-PETA的热失重行为明显不同于共混材料，接枝样dTG峰明显宽化，表明接枝样中链段之间的相互作刚有多重性，丙烯酸树脂与聚氨酯之间有一定的相容性。接枝树脂自乳化体系光固化涂层的综合性能以聚氨酯丙烯酸酯成分为50％～30％者相对较好，且以Acr-g-TPU-PETA系列更理想。光固化膜的附着力为1～2级，冲击强度为50kg·cm，柔软性多为1mm。以HEMA代替PETA作为接枝树脂的活性基团，碳—碳双键密度太低，光固化膜交联点太少，硬度和附着力均较差。多羟基胺连硫杂蒽酮光引发剂能均匀分散于树脂自乳化体系和接枝树脂干膜中，不出现色斑，光固化膜肖氏硬度一般高于以Irgacure 2959为光引发剂的光固化膜，光泽度及耐丁酮溶剂性能均有所提高，不会诱导铁基生锈，钛白着色对光固化结果几乎没有影响。本论文所合成的多羟基胺连硫杂蒽酮光引发剂IV〓与IV〓为浅黄色，对光固化涂层的颜色干扰较小，为配制钛白着色光固化水性涂料提供了新的光引发剂。水溶性太强的WB 4759在干膜中易聚结析出，且对所附着的铁基有诱导锈蚀作用。

The grafting copolymerization of 2-Acrylamido-2-methyl propane sulfonic acid onto soybean protein isolate was carried out in 8 mol/L urea aqueous solution with ammonium persulphate as initiator and β-mercaptoethanol as protein unfolding agent.

以亲水2-丙烯酰胺基-2-甲基丙磺酸为接枝单体、过硫酸铵为引发剂、β-巯基乙醇为大豆分离蛋白的变性剂，在8mol/L的尿素溶液中对SPI进行接枝共聚改性。

与为.接枝相关的网络解释 [注：此内容来源于网络，仅供参考]

Calcium Alginate：藻酸钙

文章摘要:笔者以过硫酸钾为引发剂,研究了醋酸乙烯酯(VAc)与海藻酸钙(Calcium alginate)小球的接枝共聚反应;利用FTIR表征了接枝产物;并探讨了单体用量、反应时间和小球粒径对接枝率的影响;5g初始粒径为2.5mm的小球与浓度为3.62mol/L的VAc单体在48℃反应3h,

cleg：马蝇

cleft-graft 为. 接枝 | cleg 马蝇 | cleidoic 隔离的

cleft-graft：为.接枝

cleft 裂缝 | cleft-graft 为. 接枝 | cleg 马蝇