- 更多网络例句与丙烷相关的网络例句 [注:此内容来源于网络,仅供参考]
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While the adsorptions of 1-propanol and 1-Br-propane at 100℃ give rise to 1-propoxy species, which mainly converted to propanal at higher temperature. IR spectrum arising from the interaction of propene with the catalyst at 100 ℃ shows the IR bands of allyl alcoholate and isopropoxy species. As the temperature was increased to 150℃, the bands ascribable to the adsorbed acetone and acrolein were observed. Based on these results, it is suggested that isopropoxy species is one of the intermediates for SOP to acrolein over MoPO/SiO〓 catalyst.
2原位IR光谱实验结果表明:200℃时丙烷/O〓混合气在催化剂表面吸附后的IR谱与同温度下异丙醇吸附的IR谱相似,均检测到吸附态丙酮物种和丙烯醛物种的IR谱峰;溴代异丙烷和异丙醇在催化剂表面吸附后均转化为异丙氧基,异丙氧基主要转化为丙烯和丙酮,丙烯进一步转化为丙烯醛;溴代正丙烷和正丙醇在催化剂表面吸附后均转化为正丙氧基,正丙氧基主要转化为丙醛;丙烯在催化剂表面吸附后转化为σ-氧烯丙基和异丙氧基,升温后σ-氧烯丙基转化为丙烯醛而异丙氧基转化为丙酮。
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While the adsorptions of l-propanol and 1-Br-propane at 100 癈 give rise to 1-propoxy species, which mainly converted to propanal at higher temperature. IR spectrum arising from the interaction of propene with the catalyst at 100 癈 shows the IR bands of allyl alcoholate and isopropoxy species. As the temperature was increased to 150 癈, the bands ascribable to the adsorbed acetone and acrolein were observed. Based on these results, it is suggested that isopropoxy species is one of the intermediates for SOP to acrolein over MoPO/SiO2 catalyst.
原位IR光谱实验结果表明:200℃时丙烷/O_2混合气在催化剂表面吸附后的IR谱与同温度下异丙醇吸附的IR谱相似,均检测到吸附态丙酮物种和丙烯醛物种的IR谱峰;溴代异丙烷和异丙醇在催化剂表面吸附后均转化为异丙氧基,异丙氧基主要转化为丙烯和丙酮,丙烯进一步转化为丙烯醛;溴代正丙烷和正丙醇在催化剂表面吸附后均转化为正丙氧基,正丙氧基主要转化为丙醛;丙烯在催化剂表面吸附后转化为σ-氧烯丙基和异丙氧基,升温后σ-氧烯丙基转化为丙烯醛而异丙氧基转化为丙酮。
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Under the above optimum conditions, other trimethylolpropane fatty acid esters, such as trimethylolpropane lauric acid ester, trimethylolpropane myristic acid ester, trimethylolpropane capric acid ester and trimethylolpropane octanoic acid ester were synthesized, and their esterification rates were 80.97%, 87.03%, 80.73% and 81.24%, respectively.
在上述的最优条件下,分别合成三羟甲基丙烷月桂酸酯、三羟甲基丙烷豆蔻酸酯、三羟甲基丙烷癸酸酯、三羟甲基丙烷辛酸酯,其酯化率分别为80.97%、87.03%、80.73%和81.24%。
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The present production situation and market prospects of the main epichlorohydrin downstream products,such as epoxy resin,synthetic glycerol, chlorohydrin rubber ,and so on,are described.
论述了环氧氯丙烷的主要下游产品环氧树脂、合成甘油、氯醇橡胶等的生产现状、市场前景等,指出:我国氯碱行业应该重视这些环氧氯丙烷下游精细化工产品的开发,以促进我国环氧氯丙烷的发展。
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In this paper, initiator is dissolved in 1-bromopropane which is solvent. Then the propene and hydrogen bromide that can be dissolved in 1-bromopropane are inlet in l-bromopropane when initiator is decomposing. The reaction occurs in fluid phase and high-purity 1-bromopropane is synthesized by one step method. In this paper, the material HBr is synthesized with NaBr and sulfuric acid at the presence of hydrobromic acid.
本论文以1-溴丙烷为溶剂,将引发剂溶于其中,加热到引发剂开始分解时再通入丙烯和HBr,使二者溶解于1-溴丙烷中,在液相中进行反应,实现丙烯"一步法"合成高纯1-溴丙烷利用NaBr与硫酸在氢溴酸存在下反应制备HBr气体,以作为合成1-溴丙烷的原料。
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PECH based PUs showed higher phase separation than that of PPG base PUs owing to that the -Cl groups in PECH reduced the flexibility of molecule chain and hindered the formation of hydrogen bonds between ether groups in soft segments and -NH groups in hard segments. As a result, PECH based PUs have lower free volume content, diffusion coefficient and equilibrium adsorption of CO〓, benzene and ethanol through them than through PPG based PUs.
聚环氧氯丙烷醚聚氨酯的氯基降低了链段柔性,妨碍了软段中醚基与硬段中氨基的氢键作用,导致其相分离程度较聚环氧丙烷醚聚氨酯大,并使CO〓、苯和乙醇蒸汽在聚环氧氯丙烷醚聚氨酯中的渗透系数和扩散系数较聚环氧丙烷醚聚氨酯小,而偏离费克扩散的程度大。
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The optimum conditions were reaction temperature 120°C, reaction time 20h, mole ratio of 5-chloromethyl-2-oxazolidinone and sodium phenolate 1:1. 3,5-Dimethylphenol and epichlorohydrin in sodium hydroxide were condensated to give l,2-epoxy-3-phenoxy propane, then the reation of l,2-epoxy-3-phenoxypropane and the carbamate afforded oxazolidinone in the yields of 69.0%~76.0%. The side reaction had been avoided effectively by the uses of the excessive epichlorohydrin and mixed catalysts.
用3,5-二甲基苯酚和环氧氯丙烷在氢氧化钠存在下缩合生成苯氧基环氧丙烷,然后和氨基甲酸酯反应生成噁唑烷酮,采用过量环氧氯丙烷和使用混合催化剂,有效的避免了副反应的发生,提高了噁唑烷酮的产率,产率69.0%~76.0%。
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This dissertation is mainly focused on the reactivity of methylenecyclopropanes and comprises six parts. 1 The reactions of methylenecyclopropanes with phenylsulfenyl chloride, phenylselenyl chloride and diphenyl diselenide; 2 The coupling reactions of the ring-opening products derivated from methylenecyclopropanes; 3 The palladium-catalyzed ring-enlargement of mono-aryl group substituted methylenecyclopropanes to cyclobutenes. 4 The gold-catalyzed domino ring-opening and ring-closing hydroamination of methylenecyclopropanes with sulfonamides; 5 The Lewis acid-catalyzed reactions of mono-aryl group substituted methylenecyclopropanes with diethyl ketomalonate in the presence of water; 6 The iodobenzene diacetate mediated novel 1,3-dipolar cycloaddition of methylenecyclopropanes, vinylidenecyclopropanes, and methylenecyclobutane with phthalhydrazine.
本论文主要研究了亚甲基环丙烷类化合物的一些化学反应性能,共由以下六部分组成:1、亚甲基环丙烷类化合物与苯硫氯、苯硒氯及二苯基二硒的反应;2、亚甲基环丙烷类化合物开环产物的偶联反应;3、单芳基取代的亚甲基环丙烷类化合物在钯催化剂作用下的扩环反应;4、金化合物催化磺酰胺对亚甲基环丙烷类化合物的串联开环关环氨氢化反应;5、路易斯酸催化亚甲基环丙烷类化合物与丙酮二羧酸二乙酯在有水存在下的反应;6、醋酸碘苯促进的亚甲基环丙烷类化合物、亚乙烯基环丙烷类化合物及亚甲基环丁烷类化合物与邻苯二甲酰肼的新型1,3-偶极环加成反应。
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In this paper, initiator is dissolved in 1-bromopropane which is solvent. Then the propene and hydrogen bromide that can be dissolved in 1-bromopropane are inlet in l-bromopropane when initiator is decomposing. The reaction occurs in fluid phase and high-purity 1-bromopropane is synthesized by one step method. In this paper, the material HBr is synthesized with NaBr and sulfuric acid at the presence of hydrobromic acid.
本论文以1-溴丙烷为溶剂,将引发剂溶于其中,加热到引发剂开始分解时再通入丙烯和HBr,使二者溶解于1-溴丙烷中,在液相中进行反应,实现丙烯&一步法&合成高纯1-溴丙烷利用NaBr与硫酸在氢溴酸存在下反应制备HBr气体,以作为合成1-溴丙烷的原料。
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Its high-capacity and strong-acid-resistance were proved. In the acid condition, the adsorption efficiency to acide green 6B and direct fast yellow RL reached above 90%. Through the adsorption rate curve on adsorption behavior of the three dyes, they were all according with pseudo-secondary adsorption rate curve. The rate constant of adsorption increased with increasing temperature. Through the adsorption isotherm of the three dyes, acide green 6B and direct fast yellow RL were according with Langmuir equation, while disperse blue 56 was according with Freundlich equation. The adsorption behavior was an endothermic process. Entropy was increasing during the adsorption. So raising temperature was in favor of adsorption.
结果表明,甲醛环氧氯丙烷交联壳聚糖对染料具有较强的吸附性能和耐酸性能,在酸性条件下,对酸性绿6B和直接耐晒黄RL的吸附效率达90%以上;拟合甲醛环氧氯丙烷交联壳聚糖对三种染料的吸附速率曲线,发现该吸附行为符合拟二级吸附速率曲线,其吸附速率常数随温度的升高而增大;通过测定不同温度下甲醛环氧氯丙烷交联壳聚糖吸附三种染料的吸附等温线表明,甲醛环氧氯丙烷交联壳聚糖对酸性绿6B和直接耐晒黄RL的吸附符合Langmuir方程,而对分散蓝56的吸附符合Freundlich方程,甲醛环氧氯丙烷交联壳聚糖对染料的吸附是一个吸热过程,吸附后体系熵增加,升温有利于吸附。
- 更多网络解释与丙烷相关的网络解释 [注:此内容来源于网络,仅供参考]
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cyclopropane:环丙烷
根据Rogstam[10]的研究指出,环丙烷(cyclopropane)在许多低温的应用领域,很有可能是相当优良的替代冷媒,未来的发展将取决于环丙烷的使用特性. 冷气机则是另一项主要应用电器,一般使用丙烷作为冷媒,例如瑞典有家冷气制造厂从九十年代中期至今,
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cyclopropane synthesis:环丙烷合成
cyclopousse | (东南亚的)脚踏或机动的三轮车 | cyclopropane synthesis | 环丙烷合成 | cyclopropane | 环丙烷
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Cyclopropane carboxylic acid:环丙烷羧酸
环丙烷甲酰氯Cyclopropane carbonyl chloride364 | 环丙烷羧酸Cyclopropane carboxylic acid364 | 环己胺Cyclohexanamine365
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Cyclopropane carbonyl chloride:环丙烷甲酰氯
环丙胺Cyclopropylamine364 | 环丙烷甲酰氯Cyclopropane carbonyl chloride364 | 环丙烷羧酸Cyclopropane carboxylic acid364
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ECH:环氧氯丙烷
2007-2010年环氧氯丙烷(ECH)产业,2007-2010年环氧氯丙烷工业生产技术发展现状,2007-2010年环氧树脂工业生产技术发展现状,中国聚碳酸酯供应需求及未来形势预测第四章 环氧氯丙烷(ECH)产业 37图表 28 环氧氯丙烷(ECH)两种生产工艺技术优
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POR:环氧丙烷橡胶
(POR)行业下游介绍二、环氧丙烷橡胶(POR)行业下游发展状况分析三、环氧丙烷橡胶(POR)行业下游对环氧丙烷橡胶(POR)行业影响力分析第十二章 环氧丙烷橡胶(POR)重点企业发展分析第十三章 环氧丙烷橡胶(POR)行业投资策略分析第
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propane:丙烷
丙烷-丙烷 (propane) 为一种沸点为 -43.7℉之气体,可由天然气或炼油气中分出,供燃料及工业原料等用. 丁烷-丁烷 (butane) 为一种沸点为 -32℉之气体,亦可由天然气或炼油气中分出,供燃料及工业原料等用. 一般而言,白油 (clean oil) 多指蒸馏油,
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epoxy propane:环氧丙烷
epoxy propane rubber 环氧丙烷橡胶 | epoxy propane 环氧丙烷 | epoxy repair putty 环氧修补腻子
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propanol torch:丙烷喷灯
propane-oxygen flame 丙烷氧火焰 | propanol torch 丙烷喷灯 | propargyl bromide 炔丙基溴
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propylene oxide:环氧丙烷
此种燃料是以低温、高压的方式,将环氧乙烷(EthYlene Oxide)、环氧丙烷(Propylene Oxide)、甲(Methane)、丙烷(Propane)等易挥发碳氢化合物的一种或数种,混合变成液体燃料制成.