trithiocarbonate [,trai,θaiəu'kɑ:bəneit]
- trithiocarbonate的基本解释
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三硫代碳酸盐[酯], 全硫碳酸盐[酯]
- 更多网络例句与trithiocarbonate相关的网络例句 [注:此内容来源于网络,仅供参考]
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The possible mechanism was discussed. These bowl-shaped aggregates are promising candidates for nano reactor or drug carrier.4 2,7-dimethylene-1,4,6-trioxaspiro[4, 4]nonane with two vinyls was prepared to be used as electron-donor and crosslinker. The ATRP of this crosslinker and excess methylacrylate (used as electron-accpetor) was proved to mainly form homopolymers. With the chain-transfer agent S-1-Dodecyl-S\'-(α,α\'-dimethyl-α-acetic acid)trithiocarbonate, the copolymerization of the spiro hydrocarbon, maleic anhydride and MA by RAFT method produced star PMA.
这些由聚电解质复合物自组装形成的聚集体,在微反应器和药物释放等领域具有潜在的应用前景。4合成了双乙烯基的2,7-二亚甲基-1,4,6-三氧杂螺环烷,作为给电子单体和交联剂,与吸电子单体马来酸酐或过量的丙烯酸甲酯形成电荷转移络合物共同聚合,尝试了用ATRP和RAFT方法一步法合成星形聚合物。
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In addition, environmental induced structure conversion of amphiphilic block copolymer film is also being investigated.3. Acrylic acid was polymerized directly in aqueous phase in the presence of a water-soluble trithiocarbonate as RAFT agent, and well-defined poly with low polydispersity index and high molecular weight was successfully prepared.
与同类文献比较,具有方法简单易操作并在以环境友好的水为介质的条件下反应的优点,且在高的单体和RAFT试剂比例与高转化率的情况下,没有观察到链转移的现象,为进一步合成高分子量的嵌段共聚物提供了潜在的方法。
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Keywords: cyclic trithiocarbonate;RAFT polymerization; multiblock polymer; narrow molecular weight distribution.
中文关键词:环状三硫酯;RAFT聚合;多嵌段聚合物,窄分子量分布
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Firstly, the homopolymerization of acrylamide was carried out in aqueous phase by reversible addition-fragmentation chain transfer radical polymerization using a trithiocarbonate as a chain transfer agent.
整个过程分为两步,首先在水溶液中,通过RAFT控制得到亲水性单体丙烯酰胺的均聚物;然后以得到的均聚物作为水溶性的大分子链转移剂,在水相中条件下参与亲油性单体苯乙烯无皂乳液聚合。
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Dithioester and trithiocarbonate RAFT reagents were synthesizedby different methods, and were used for the polymerization of styrene ormethacrylates, by thermal, thermo-initiator and photo-initiation.
针对这一问题,本文尝试用三种方法合成了结构不同的RAFT试剂,考察了热引发、引发剂引发以及紫外光引发条件下,二硫酯/三硫酯调控的常见单体苯乙烯以及丙烯酸酯的RAFT聚合。
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trithiocarbonate:三硫代碳酸盐
trithioacetone 三聚硫酮 | trithiocarbonate 三硫代碳酸盐 | trithiocarbonicacid 三硫代碳酸
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trithiocarbonate:三硫碳酸盐
trithioaurate 三硫金酸盐 | trithiocarbonate 三硫碳酸盐 | trithionate 三硫磺酸盐
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methyl trithiocarbonate:三硫碳酸甲酯
三甲基乙酸甲酯 methyl trimethylacetate | 三硫碳酸甲酯 methyl trithiocarbonate | 缬草酸甲酯;戊酸甲酯 methyl valerate
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ethylene trithiocarbonate:乙撑三硫代碳酸酯
ethylene thiourea 乙撑硫脲 | ethylene trithiocarbonate 乙撑三硫代碳酸酯 | ethylene tube 乙烯管