tripodal ['traipədəl]
- tripodal的基本解释
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adj.
有三脚的
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Furthermore, the structures of the complexes are strange. The tripodal ligand H〓L〓 form a 2: 2 ring-like binuclear complexes [Eu〓·L〓·6DMF] ·CH〓OH·DMF with Eu〓 in DMF. Two DMF molecules are accommodated in the ring and coordinate with Eu〓.
此外配合物的结构还比较特殊,三足配体H〓L〓与铕的配合物在配位能力较强的溶剂DMF中形成环状的2:2型双核配合物[Eu〓。L〓·6DMF]·CH〓OH·DMF,环状空腔刚好能够把两个配位的DMF溶剂分子包在里面。
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1 To mimic the active centers of tyrosinate iron enzymes whichcontain phenolate donors, new tripodal ligand, N-(2-hydroxybenzyl)-N, N-bis(2-benzimidazolymethyl) aminewhich contain imidazoleand phendate groups were designed and synthesized and its iron com-plexes 〓(2)(where Mim=N-Methylimidazole) and Fe 〓(3) were prepared andcharacterized by various spectroscopic methods.
1.1 为了模拟酪酸铁酶活性中心,设计并合成了含有酚羟基和苯骈咪唑基四齿配体N,N-(2-羟基苯)-N,N-二氨,并合成它的铁配合物:Fe〓、Fe〓〓(2)和Fe〓,并经各种谱学手段表征了这些铁配合物。
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To improve the yield of an Amide-type Tripodal Ligand and investigate its coordination with rare earth ion under mild condition,a series of Amide-type Tripodal Ligands(L1—L4) have been prepared by the reactions of nitrilotriacetic acid and oxalyl chloride with four kinds of amides,respectively.
为了提高酰胺型三脚架型配体的产率,进一步研究其与稀土离子的配位形式及配合物的荧光性能,以氨三乙酸为母体,草酰氯为氯化试剂,与4种胺在较温和的条件下合成了具有三脚架型结构的配体(L1—L4),并考察了实验条件、反应温度、反应体系溶剂、缚酸剂、反应时间及催化剂对反应产率的影响。
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Kinetic spectrophotometric method for the determinationof trace nitrilotriacetic acid;2. To improve the yield of an Amide-type Tripodal Ligand and investigate its coordination with rare earth ion under mild condition,a series of Amide-type Tripodal Ligands(L1—L4) have been prepared by the reactions of nitrilotriacetic acid and oxalyl chloride with four kinds of amides,respectively.
为了提高酰胺型三脚架型配体的产率,进一步研究其与稀土离子的配位形式及配合物的荧光性能,以氨三乙酸为母体,草酰氯为氯化试剂,与4种胺在较温和的条件下合成了具有三脚架型结构的配体(L1—L4),并考察了实验条件、反应温度、反应体系溶剂、缚酸剂、反应时间及催化剂对反应产率的影响。
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The coordination compounds of rare earth with macrocyclic、pyrazolone and tripodal ligand have distinctive structure and properties, and potential applications in exploring new materials, the investigations of analysis and separation of the ions.
稀土穴醚、吡唑啉酮、三脚架化合物具有独特的结构和性质,在新材料的研究、稀土的分析及分离等方面有潜在的应用。
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tripodal:有三脚的
tripod 三脚桌 | tripodal 有三脚的 | tripodic 有三脚的
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tripodal:有三脚的; 三脚架的 (形)
tripod 三脚桌, 三脚架 (名) | tripodal 有三脚的; 三脚架的 (形) | tripped up 绊倒, 使失败, 挑剔