tri-ester
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The nautre of ester bond and sedimentary medium condition control the distribution pattern of organic acid ester in strong reductional environment and water-washed oxidized crude oils. The former features higher contents both of 9, 11-Octadecadienoic acid, methyl ester and Hexadecanoic acid, showing the non-reversible hydrolysis reaction of ester bond in condition of basicity; the later features higher contents of Hexadecanoic acid and Octadeanoic acid, and lower contents of nonsaturated and side-chain acid ester, indicating the reversible hydrolysis reaction of ester bond in acid condition.
酯键的化学性质和沉积环境中介质条件,决定了强还原咸水盐湖相和淡水湖沼相经水洗氧化次生变化的原油有机酸酯的分布特征,前者9,11-十八二烯酸甲酯与正十六烷酸为主,反映酯键在碱性条件的不可逆水解过程,后者以正十六烷酸和正十八烷酸为主,烯酸和支链酸很少,反映酯键的酸性条件的可逆性水解,烯酸经氧化向正十八烷酸,正十六烷酸转化。
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For example, an objective polyester can be produced in a method of producing an ester comprising, a first step wherein a diol is reacted with an ester produced beforehand from a dibasic acid and a monofunctional alcohol, or an ester produced beforehand from a monofunctional alcohol and diol, a second step wherein unreacted ester is separated from the product produced in the first step to obtain another ester, and a third step wherein unreacted ester separated in the second step is recycled to the first step, 0.05-5 millimoles of the catalyst relative to one mole of acid being used in said first step.
例如,可以应用制备酯的方法制备目的聚酯,包括,第一步,使二醇与产生的酯反应,该酯由二元酸和单官能团醇预先制得,或由单官能团醇和二醇预先制得;第二步,将未反应的酯与第一步所制得的产物分离,得到另一种酯;第三步,将第二步中分离出的未反应的酯循环回到第一步中,在第一步中相对于1摩尔酸来说,应用了0.05-5毫摩尔所述的催化剂。
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Except for measuring the yields and comparing the experimental conditions, the article also confirmed the accurate composition of product biodiesel, and results indicated that the biodiesel made by oil and fat mainly consists of Oleicacid methyl ester, Linoleic acid methyl ester, Hexadecanoic acid methyl ester, Octadecanoic acid methyl ester and some other acid methyl ester.
结果表明油脂制的生物柴油主要是油酸甲酯、棕榈酸甲酯、亚油酸甲酯、硬脂酸甲酯和癸酸甲酯的混合脂肪酸甲酯。
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tri-ester:合成
苯氧羧酸:phenoxy carboxylic acid | 合成:tri-ester | 酷胺:ester