thiophosphoryl [,θaiəu'fɔsfə,ril]
- thiophosphoryl的基本解释
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[化] 硫代磷酰
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Adenosine was used as the raw material, dissolved in triethyl phosphate and then esterified with thiophosphoryl chloride under 0~5℃ for 8h without water and oxgen, in alkaline condition provided by 2,6-dimethylpyridine, introducing thiophosphoryl ester to adenosine.Then superfluous triethylamine was added and reacted under 5℃ for 1h to synthesize rough 5'-AMPS.The unpurified product was appled to a DEAE Sephadex A-25 column and eluted with triethylammonium bicarbonate.
用腺苷为起始原料,溶解于磷酸三乙脂中后,在无水无氧环境中及2,6-二甲基吡啶提供的碱性条件下与三氯硫磷以0~5℃下发生酯化反应8h,将硫代磷酸酯引入腺苷,然后再与过量三乙胺在5℃下反应1h,合成粗产品,再用碳酸氢三乙胺作洗脱液,过DEAE Sephadex A-25凝胶柱纯化。
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Diethylthiophosphoryl chloride was synthesized by reacting phosphorus thiochloride with anhydrous alcohol in the presence of NaOH, and then a novel phosphorus-nitrogen- and sulfur-containing flame retardant, 1, 4-di(O,O-diethyl thiophosphoryl imine) benzene, was synthesized via the reaction of diethylthiophosphoryl chloride with p-phenylenediamine.
以三氯硫磷与无水乙醇在NaOH存在下合成了二乙基硫代磷酰氯,然后再与对苯二胺反应合成了新型的含磷、氮、硫的膨胀型阻燃剂:1,4-二(O,O-二乙基硫代磷酰亚胺基)苯。
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thiophosphoryl:硫磷酰
五硫化二磷 thiophosphoric anhydride | 硫磷酰 thiophosphoryl | 三胺化硫磷酰 thiophosphoryl amide
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THIOPHOSPHORYL CHLORIDE:硫代磷酰氯
THIOPHOSGENE 硫光气 6.1 2474 | THIOPHOSPHORYL CHLORIDE 硫代磷酰氯 8 1837 | THIOUREA DIOXIDE 二氧化硫脲 4.2 3341
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THIOPHOSPHORYL CHLORIDE:硫磷酰氯
亚硫酰氯 thionyl chloride | 硫磷酰氯 thiophosphoryl chloride | 钍矿石 thorium ore
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THIOPHOSPHORYL CHLORIDE:三氯化硫磷酰
三溴化硫磷酰 thiophosphoryl bromide | 三氯化硫磷酰 thiophosphoryl chloride | 一氯二溴化硫磷酰 thiophosphoryl dibromide chloride
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thiophosphoryl bromide:三溴化硫磷酰
三胺化硫磷酰 thiophosphoryl amide | 三溴化硫磷酰 thiophosphoryl bromide | 三氯化硫磷酰 thiophosphoryl chloride
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