thiolate
- thiolate的基本解释
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n.
硫醇盐, 烃硫基金属
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Syntheses, Crystal Structures of Some Complexes with Mixed Thiolate and Phosphite Ligands and Electrochemi...
本文对一些膦巯混配的过渡金属配合物的合成、结构、反应规律和电化学进行了研究。
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The emulsion preferably contains an oxidatively dimerized form of a mesoionic compound having a thiolate structure, and a silver chloride content of at least 90% by mol.
该乳剂优选含有氧化二聚形式的具有硫醇盐结构的介离子化合物和至少90摩尔%的氯化银。
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The interaction between MT and AA was expressed by infrared spectra, the functional groups of -SH in MT had lone pair electrons, which could formπ-πwith -C=O in AA. The equilibrium binding experiment and Scatchard analysis showed, at least three kinds of binding sites would exist when MT-imprinted polymer formed, the most adsorption capacities were 3.3896mg/g, 0.9362mg/g, 1.6583mg/g respectively; most terminal thiolate sulfurs in MT were polymerized as binding sites in the process of polymerization, which could observed from TEM, binding capability of other thiolate sulfurs was weak since spatial hindrance existed.
采用红外光谱研究了加入金属硫蛋白后功能单体丙烯酸官能团谱峰的变化,结果表明金属硫蛋白分子中的-SH与丙烯酸中的C=O在氯仿溶液中能形成π-π键,由聚合物的吸附特性和Scatchard分析可以得出,金属硫蛋白印迹聚合物至少存在三种结合位点,其高、中、低的最大吸附量分别为3.3896mg/g、0.9362mg/g、1.6583mg/g;通过透射电镜可以观察到,金属硫蛋白在聚合过程中主要以分子两端的巯基作为结合位点,不同位置的巯基受到的空间位阻不同,导致产生了三种不同的结合位点。
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hydroxyl:氢氧基
先前的研究指出,氢氧基(hydroxyl)与咪唑(imidazole)官能基的存在,是酵素具有催化特性的关键. 为了制造仿生材料,加大的Dan Morse等人利用图案化PDMS转印(patterned PDMF stamp)技术,将具有氢氧基端的烷基硫醇(hydroxyl terminated alkane thiolate)转移到金的表面,
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imine complexes:亚胺类配合物
二价汞配合物:Complexes of Hg(11) | 稀土硫化物:organolanthanide thiolate complexes | 亚胺类配合物:imine complexes