thienyl ['θaiə,nil]
- thienyl的基本解释
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[化] 噻吩基
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The disorder of the thienyl ring and〓 groups in 11, 12 and the disorder of water in the packing of 14 may be responsible for their triboluminescent activities.Ⅲ. A dinuclear triboluminescent complex,〓(15)(where TTA=2- thenoyltrifluoroacetone, PyO=N-oxide pyridine), was synthesised and its crystal structure and triboluminescence spectrum were determined.
X-射线结构分析表明,四个配合物中的铕原子均呈现出八配位的四方反锥几何构型。11、12及13均为有对称中心结构配合物,11、12中的噻吩环及〓的无序以及配合物14晶胞中水分子的无序可能对它们的摩擦发光活性起了很重要的作用。
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The characteration of 15 will may provide a new pathfor searching new triboluminescent complexes. The triboluminescence maximum of 15is similar to that of its photoluminescence. The disorder of the thienyl rings and 〓groups in 15 may be responsible for its triboluminescent activity.
Eu的距离为4.2137(9)〓。两个桥联O原子与两个Eu构成一平面四边形,∠Eu(1)-O(7)-Eu(1A)和∠O(7)-Eu(1)-O(7A)分别为117.84(14)°和62.18(14)°。15的摩擦发光光谱与其光致发光光谱很类似,表明它们有相同的激发态。15的摩擦发光活性可能与其结构中噻吩环及〓的无序有关。
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The Stille coupling reaction between 8 iodo 9 benzyl 9H purine and RSnBu 3 (R=vinyl,2 thienyl,2 furyl,phenylethynyl and phenyl) was studied using (Ph 3P) 2PdCl 2 as catalyst and DMF as solvent.
采用 (Ph3 P) 2 PdCl2 为催化剂,DMF为溶剂,对 8 碘 9 苄基 9H 嘌呤与有机锡试剂RSnBu3 (R=乙烯基、2 噻吩基、2 呋喃基、苯乙炔基和苯基等)之间的 Stille偶合反应进行了研究,合成出了5种 8位取代的嘌呤衍生物。
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Using thienyl stannane and palladium-catalyzed, 1,4-di(5'-carbaldehyde-thiophen-2'-yl)-2,5-dioctyloxy-benzene was synthesized by four steps, the structure was determined by NMR, IR and elemental analysis.
由于目标产物(5)本身具有多芳环共轭体系,其荧光效应相当强烈,在氯仿溶液中紫外-可见吸收和荧光发射的最大波长分别为413nm和477nm,固态荧光发射波长为504nm
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Eight half-sandwich titanium complexes (S1-S8) with pendant thienyl group were synthesized. These complexes with MAO were tested in ethylene conversion.
合成了8个含有噻吩基的半夹心茂钛络合物(S1-S8),考察了它们在MAO的活化下对乙烯的催化性能。
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thienyl:噻吩基
选自吡嗪基、吡唑基、哒嗪基、吡啶基、嘧啶基、吡咯 基、四唑基、呋喃基、咪唑基、三嗪基、吡喃基、噻唑基、噻吩基(thienyl)、 噻吩基(thiophenyl)、三唑基、唑基、异唑基、噻唑基、二唑基、 吲哚基、喹啉基、异喹啉基、苯并咪唑基及苯并唑基的杂芳基,