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The transition metal complex has a pentagon ring structure having an amido group connected by a phenylene bridge in which a stable bond is formed in the vicinity of a metal site, and thus, a sterically hindered monomer can easily approach the transition metal complex.
该过渡金属配合物具有由亚苯基桥连接的酰胺基的五边环结构,其中在金属位置附近形成稳定键,因此位阻单体可容易地接近过渡金属配合物。
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Pd(PPh3)4 was more reactive for boronic acids with sterically hindering F atom, and the coupling reactions gave good yields of 90% and 91% without any self-coupling by-product.
Pd(PPh3)4对于含有位阻F原子苯硼酸的偶联反应很具有活性,且没有自偶联产生,产率可达90%及91%。
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The synthesis of sterically hindered peptides containing N-alkylated or 〓disubstituted amino acid residues is being a challenge, which results in difficultcondensation using the usual DCC/HOBt or HOBt-derived coupling reagents.
多肽合成的一个主要难题是富含N-烷基化氨基酸或C〓二烷基化氨基酸的肽链的合成,采用BOP或HBTU等常规缩合剂往往不能得到令人满意的结果。
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However, the reaction speed decreased and more solid green product isolated due to the sterically hindering of ester group.
只是由于酯基的空间位阻效应而使反应速度变慢,析出的固体绿色化合物更多。
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B3The sterically allowed values of φandψare visualized in a Ramachandran plot.
在莱幔图谱上可看见φ与ψ的立体允许值。
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Angiogenesis Sterically Stabilized Liposome:血管生成
水泥稳定粒料:cement stabilized aggregate | 血管生成:Angiogenesis Sterically Stabilized Liposome | 水泥土桩:Cement-stabilized soil pile