protecting group

protecting group的基本解释

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保护基

与protecting group相关的网络例句 [注：此内容来源于网络，仅供参考]

In order to resolve these questions, we try to find some new protecting group which could be used in the preparation of such unstable nucleotides analogues.

对于一些寡核苷酸的类似物，由于它们在某些化学环境下的不稳定性而使它们的合成具有一定的困难，为了解决这些问题，人们一直在开发新的保护基，以消除这些副反应的影响，更方便地制备这些化合物。

Constituting dicycle; 2. region selectively reducing six-membered ring ketocarbonyl radical; 3. introducing 7alpha-hydroxy group; 4. Aldol reaction to introduce side chain and obtain 8alpha-hydroxy group; 5. oxidizing the position 7 hydroxy group into ketone; 6. turning the configuration of the position 7 hydroxy group; 7. glycosidating the position 7 hydroxy group; and 8. eliminating protecting group to obtain the target compound.

该方法包括如下步骤：(1)双环的构建；(2)区域选择性还原六元环酮羰基；(3)7α-羟基的引入；(4)Aldol反应引入侧链，同时得到8α-羟基；(5)7位羟基氧化为酮；(6)7位羟基构型的翻转；(7)7位羟基的糖苷化；(8)脱除保护基得到目标化合物。

The E-TOF will also be feasible and practical to assist chemists in screening the optimal reaction condition or evaluating the overall efficiency of different catalytic systems for a specific asymmetric reaction.4.For the first time,we explored chiralγ-hydroxy-α,β-acetylenic esters,which were prepared via asymmetric alkynylation,as key intermediates to the synthesis of chiralγ-butyrolactones. This convergent and enantioselective approach to chiralγ-butyrolactones is practical and easily handled with protecting group free.

这一概念包括反应产率、对映选择性、配体用量以及反应时间四个重要反应参数，不仅适用同一反应不同催化体系的横向综合性评价，而且适用于某一特定反应催化体系的优化过程，有助于研究人员选择最佳的反应条件。4、我们发展了以手性γ-羟基-α，β-炔酸酯为关键中间体完成了手性γ-丁内酯类天然产物的对映立体选择性全合成，该关键中间体能够以我们的催化体系方便的对映选择性合成，之后的官能团转换方法成熟，易于操作，无需进行繁琐的官能团保护和脱保护过程，绿色经济。

与protecting group相关的网络解释 [注：此内容来源于网络，仅供参考]

protecting hood：护盖

protecting group 保护基 | protecting hood 护盖 | protecting housing 保护管