phosphinate ['fɔsfəneit]

phosphinate的基本解释

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亚膦酸盐, 亚膦酸酯

与phosphinate相关的网络例句 [注：此内容来源于网络，仅供参考]

On the basis of the reductant hydrogen theory, hydrogenate theory and electrochemisty mechanism, the reaction mechanism of deposits is discussed systematically, with phosphinate, borohydride and borohydride as reductant.

利用已提出的还原氢态理论、氢化物理论以及电化学理论分别以次磷酸盐、硼氢化物以及次磷酸盐与硼氢化物作为复合还原剂条件下，对镀层的反应机制进行了系统的讨论。

Hydroxy-5, 10-dihydrophenophosphazine 10-oxide (1) reacted with SOCl2, and then with MeONa in MeOH to give a methyl phosphinate (2) which can be converted to a dinitro compound 3 (62%) by nitration and the resulting dinitro compound 3 can further be converted to 2, 8-diamino-10-methoxy-5, 10-dihydrophenophosphazine 10-oxide (4, 71%) by hydrogenation over Pd/C (w = 0.05). And the effect of amount of Pd/C (w = 0.05) on the reduction was also studied.

10－羟基－5，10－二氢磷杂吖嗪－10－氧化物（1）经醯氯化、甲基化得到10－甲氧基－5， 10－二氢磷杂吖嗪－10－氧化物（2），2经硝化得到10－甲氧基－2，8－二硝基－5，10－二氢磷杂吖嗪－10－氧化物（3，62%）。3在Pd／C（w = 0.05）存在下，用氢气还原为2，8二氨基－10－甲氧基－5，10－二氢磷杂吖嗪－10－氧化物（4，71%），考察了Pd／C（w = 0.05）用量对氢化还原反应的影响。

The phosphine was quickly oxidized by triplet oxygen to phosphineoxide with a free radical chain reaction at relatively low temperature; while at high temperature, the phosphine react with singlet oxygen through a three member ring intermediate to form phosphineoxide and phosphinate as the product.

在相对较低温度时，膦化物与基态氧发生自由基链反应，膦化物很快被氧化为氧化膦；在相对较高的温度，膦化物与激发态氧直接作用，通过三元环状中间体而最终生成氧化膦和次磷酸酯。

A series of neutral organophosphorus compounds including trialkylphosphates,dialkyl alkylphosphonate,alkyl dialkyI phosphinate,trialkyl phosphine oxide andalkyl esters of phosphorus acid have been separated by reversed phase chromatographyon acetylated paper.

一般中性磷化合物(磷酸三烷基酯、烷基瞵酸二烷基酯、二烷基瞵酸烷基酯、氧化三烷基瞵、亚磷酸二烷基酯及亚磷酸三烷基酯)皆能借乙酰化滤纸为固定相，进行纸上层析分离鉴定。