parent complex
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In this thesis, a series of complexes based on aromatic multicarboxylic acids have been successfully synthesized in solutions or under hydrothermal conditions. Their structure and properties are investigated.(1) Eight complex compounds have been synthesized and characterized by X-ray single crystal diffractive technology: The eight complexes are listed as following: [Cu242] complex 1 [Cd22(H2O)4]·4H2O complex 2 [Co(H2btc)(H2O)3] complex 3 [Co2(H2O)2]·H2O complex 4 [Ni22(H2O)4] complex 5 [Cu22(H2O)4] complex 6 [Co(H2biim)2(H2O)2](H2btc) complex 7 [Zn(H2biim)2(H2O)2](H2btc) complex 8 The structure of complex 1 is dinuclear complex resulted from weak interactions(0-D chain); complex 2 is 1-D chain stucture result from interactions of water molecules; complex 3、4、5、6 are coordination polymers using hydrothermal synthses, where the first kind ligand is H4btc, the second kind ligand is phen and Co2+、Ni2+、Cu2+ as center ions, respectively. While the coordination enviroment of Co2+ is the same in complex 3, the coordination geometries around the Co atoms in complex 4 are obviously different because of the different reaction conditions. In complex 4, the 1-D chains are connected into 2-D layer through carboxy groups of ligand H4btc. The structures of complex 5、6 are 1-D chain stucture result from interactions of carboxy groups in ligand H4btc. Complex 7、8 are homeomorphy compounds. Either of them are linked to the 3-D chains through intermolecular hydrogen bonds. Each H4btc lose two protons and H2btc2- acts as negative electron balance.
合成了8个结构新颖的配合物,并用X-射线单晶结构分析方法确定了晶体结构,分别为: [Cu242] 配合物1 [Cd22(H2O)4]·4H2O 配合物2 [Co(H2btc)(H2O)3] 配合物3 [Co2(H2O)2]·H2O 配合物4 [Ni22(H2O)4] 配合物5 [Cu22(H2O)4] 配合物6 [Co(H2biim)2(H2O)2](H2btc)配合物7 [Zn(H2biim)2(H2O)2](H2btc)配合物8 配合物1是一个依靠弱作用连接的双核铜结构;配合物2借助水分子形成一维链状结构;配合物3、4、5、6是以H4btc为第一配体、phen为第二配体,通过水热法合成的配合物,其中,Co2+、Ni2+、Cu2+为中心离子;配合物3中的二价钴离子具有相同的配位环境,不同反应条件下得到的配合物4中的二价钴离子存在不同的配位环境,在配合物4中,一维链通过H4btc上的羧基形成一个二维层结构;配合物5、6是借助H4btc上的羧基形成的一维链状结构;配合物7、8属于异质同晶结构,它们的分子通过分子间氢键形成三维网状结构,H4btc上的羧基失去2个质子,作为一个二价负离子起到电荷平衡作用。
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In this paper,fuzzy complex numbers,limits of the sequence of fuzzy complex numbers,the metrical convergence and levelwise convergence,the continuity offuzzy complex functions,the calculus of fuzzy complex functions,theseries whose terms are fuzzy complex numbers,the series whose terms arefuzzy complex functions,the fuzzy complex measure and fuzzy differentialequation are investigated in details.All this may be a foundation forfurther researching fuzzy complex analysis.
本文对模糊复数、模糊复数列的极限、度量收敛与水平收敛、模糊复函数的连续性、模糊复函数的微积分、模糊复数项级数、模糊复函数项级数、模糊复测度及模糊微分方程理论进行了详细的研究,为模糊复分析的进一步研究打下一定基础。
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When the parent of high photosynthetic production rate is used as female parent, the dominancy of the photosynthetic production rate in F1 is over its parent by 8.8 %, otherwise, used as male parent, by 0.9%.
用高光合生产率亲本作母本时,F_1光合生产率优势超亲8.8%,反交F_1光合生产率优势超亲0.9
- 更多网络解释 与parent complex相关的网络解释 [注:此内容来源于网络,仅供参考]
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parent item:父项
parent form 父窗体 | parent item 父项 | parent object 父对象
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Parent Lending Library:家长借书图书馆
Parent Involvement 家长参与 | Parent Lending Library 家长借书图书馆 | Parent Orientation 家长迎新(讲座)
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parent nuclide:母核种
母核 parent nucleus | 母核种 parent nuclide | 母核峰 parent peak