oxalamide
- oxalamide的基本解释
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乙二酰胺, 草酰胺
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Studies on Synthesis and Crystal Structure of N, N'-Bis(4-Hydroxy-3-Methoxybenzyl) Oxalamide
篇名 N,N'-双(4-羟基-3-甲氧基苯甲基)草酰胺的合成及晶体结构研究
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DFT Study on Heterobinuclear Cu-Co Complex of N,N'-bis (3-carboxyl Salicyl Aminal Ethylene) Oxalamide
篇名 N,N'-双(3-羧基水杨醛叉缩胺乙基)草酰胺Cu-Co异双核配合物的密度泛函研究
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The new oxalamide bridging ligands N, N'-bis (4-hydroxy-3-methoxy-benzyl) oxalamide (H4LB) was designed and synthesized.
设计合成一种新型对称的草酰胺桥联配体:N,N'-二(4-羟基-3-甲氧基苯甲基)草酰胺配体(H4LB)。
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The structure analysis indicates that the reverse symmetry ligand H4LB molecules are linked into a 2D supermolecular network by two types of hydrogen bonds. One type occurs between the oxalamide oxygen group and the phenol hydroxyl qroup of the nearest molecule with d=2.906(2) and ∠O-H…O=151.8°. The other type is between the oxalamide nitrogen group and the oxalamide oxygen group of anther molecule with d=2.849(2),∠N-H…O=158.7°.
晶体结构研究表明配体H4L为顺式桥联分子,晶体中存在两种氢键,一种是草酰胺基团的O原子与苯环上的酚羟基形成O-H…O氢键[d=2.906(2),∠O-H…O=151.8°];另一种是草酰胺基团的氨基与相邻草酰胺基上的O原子形成N-H…O氢键[d=2.849(2),∠N-H…O=158.7°],通过上述两种氢键将化合物H4LB连接成二维网络结构。
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oxalamide:草酰胺
oxalaldehyde 草醛 | oxalamide 草酰胺 | oxalate 草酸 草酸盐 草酸盐酯 乙二酸盐